Physics / Fizik
Permanent URI for this collectionhttps://hdl.handle.net/11147/6
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Research Project Üstüniletken MgB2 tellerin üretimi ve karakterizasyonu(TÜBİTAK - Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 2005) Okur, Salih; Özyüzer, Lütfi; Abukay, Doğan; Emirdağ, Mehtap; Tanoğlu, Metin; Eğilmez, MehmetMgB2 alaşımının 39 K lik Tc kritik sıcaklığına sahip bir üstüniletken olduğunun 2001 de keşfedilmesi çok iyi üstüniletken olduğu bilinen NbTi ve NbsSn malzemelerinin yanısıra uygulamaya daha yakın yeni bir üstüniletken malzeme olma ümidini de artırmıştır. O günden bu güne MgB2 üstüniletken tellerin üretilmesi konusunda çok etkileyici bir aşama kaydedilmiştir. Daha yüksek kritik akım yoğunluğuna ulaşmak için gerekli parametrelerin araştırılması konusunda birkaç teknik geliştirilmiştir. Bunların arasında 'tüp içinde toz ' (TIT) adı verilen metot diğerlerine göre daha pratik ve ümit verici gözükmektedir. Bazı metal ve alaşımların TIT işleminde kılıf malzeme olarak kullanılmaya uygun bulunmuştur. Bunlardan demir ve alaşımları kısmen MgB2 özelliğini bozmadığı gibi manyetik ekranlama yaparak dış manyetik alanların kritik akım üzerindeki yan etkilerini azaltarak daha yüksek değerlere ulaşılmıştır. TIT yöntemi ile MgB2 üretimi sırasında iki farklı teknik vardır. Birisinde reaktif MgB2 tozlar kulanılırken diğerinde belli kimyasal oranlarda karıştırılmış reaktif olmayan Mg+2B tozları kullanılmaktadır. Daha sonra bu tozlar reaksiyon yapmayan bir tüp veya kapsül içine kapatılıp 900 ile 1000 °C civarında belirli bir süre tavlanmaktadır. Bu yöntem ile Demir kılıflı MgB2 üstüniletken tellerinden 15 K de 10 A/cm civarında bir Jc kritik akım yoğunluğuna ulaşılmıştır. Bu projede ilk adım olarak borik asitten M&B2 elde edilmiş ve elde edilen MgB2 in yapısını XRD ve SEM EDX mikroskopu ile karakterize edilmiştir. Uygun bir saflığa sahip MgB2 e ulaşıldığında elektriksel ve manyetik özellikleri pellet haline getirilip incelenmiştir, ikinci adımda ise üretilen MgB2 tozlarından üstüniletken MgB2 tel ve teyplerin TIT yöntemi ile üretilmiştir ve Cu, Fe, ve paslanmaz çelik gibi MgB2 ile etkileşmeyen malzemeler kılıf olarak kullanılanarak üretilmeye çalışılmış ve bu üstüniletken MgB2 tellerin özdirenç ve manyetik alana bağlı olarak kritik akım (Jc) karakteristiğinin sıcaklığa bağımlılığı incelenmiştir.Research Project Üstüniletken magnezyum borür (MgB2) tellerinin yüksek akım ve yüksek manyetik alan uygulamaları için geliştirilmesi(2008) Okur, Salih; Tarhan, Enver; Büyükköse, Serkan; Özyüzer, Lütfi; Tanoğlu, Metin; Emirdağ, Mehtap[No Abstract Available]Article Citation - WoS: 12Citation - Scopus: 14Laser Assisted Synthesis of Anisotropic Metal Nanocrystals and Strong Light-Matter Coupling in Decahedral Bimetallic Nanocrystals(Royal Society of Chemistry, 2021) Mert Balcı, Fadime; Sarısözen, Sema; Polat, Nahit; Güvenç, Çetin Meriç; Karadeniz, Uğur; Tertemiz, Necip Ayhan; Balcı, SinanThe advances in colloid chemistry and nanofabrication allowed us to synthesize noble monometallic and bimetallic nanocrystals with tunable optical properties in the visible and near infrared region of the electromagnetic spectrum. In the strong coupling regime, surface plasmon polaritons (SPPs) of metal nanoparticles interact with excitons of quantum dots or organic dyes and plasmon-exciton hybrid states called plexcitons are formed. Until now, various shaped metal nanoparticles such as nanorods, core-shell nanoparticles, hollow nanoparticles, nanoprisms, nanodisks, nanorings, and nanobipyramids have been synthesized to generate plasmon-exciton mixed states. However, in order to boost plasmon-exciton interaction at nanoscale dimensions and expand the application of plexcitonic nanocrystals in a variety of fields such as solar cells, light emitting diodes, and nanolasers, new plexcitonic nanocrystals with outstanding optical and chemical properties remain a key goal and challenge. Here we report laser-assisted synthesis of decahedral shaped noble metal nanocrystals, tuning optical properties of the decahedral shaped nanocrystals by galvanic replacement reactions, colloidal synthesis of bimetallic decahedral shaped plexcitonic nanocrystals, and strong plasmon-plasmon interaction in bimetallic decahedral shaped noble metal nanocrystals near a metal film. We photochemically synthesize decahedral Ag nanoparticles from spherical silver nanoparticles by using a 488 nm laser. The laser assisted synthesis of silver nanoparticles yields decahedral (bicolored) and prism (monocolored) shaped silver nanocrystals. The decahedral shaped nanoparticles were selectively separated from prism shaped nanoparticles by centrifugation. The optical properties of decahedral nanocrystals were tuned by the galvanic replacement reaction between gold ions and silver atoms. Excitons of J-aggregate dyes and SPPs of decahedral bimetallic nanoparticles strongly couple and hence decahedral shaped plexcitonic nanoparticles are prepared. In addition, localized SPPs of decahedral shaped bimetallic nanocrystals interact strongly with the propagating SPPs of a flat silver film and hence new hybrid plasmonic modes (plasmonic nanocavities) are generated. The experimental results are further fully corroborated by theoretical calculations including decahedral shaped plexcitonic nanoparticles and decahedral nanoparticles coupled to flat metal films.Article Citation - WoS: 33Citation - Scopus: 33Characterization of Thin Film Li0.5la0.5ti1-Xalxo3 Electrolyte for All-Solid Li-Ion Batteries(Elsevier, 2018) Ulusoy, Seda; Gülen, Sena; Aygün, Gülnur; Özyüzer, Lütfi; Özdemir, MehtapSince addition of Al in Li0.5La0.5TiO3 has enhanced ionic conductivity in bulk materials, it is important to apply this material on all solid state thin film batteries. Because some of the good ionic conductors such as Lithium Phosphorus Oxynitride (LiPON) are sensitive to oxygen and moisture and their application is limited, so amorphous Li0.5La0.5Ti1−xAlxO3 (LLTAlO) is a most promising candidate because of its stability. In this study, the crystalline LLTAlO targets were prepared changing the amount of x content by conventional solid state reactions. Using these targets, lithium lanthanum titanium oxide (LLTO) thin film electrolytes were deposited on ITO/SLG substrates by radio frequency magnetron sputtering system in Ar atmosphere. The structural and compositional properties of targets and thin films were characterized by SEM, XRD, Raman spectroscopy and XPS. It was found that all targets are crystalline while the thin films are amorphous. To understand the effect of Al doping on ionic conductivity, electrical measurements were done at room temperature by AC impedance spectroscopy forming ITO/LLTAlO/Al structure like capacitor. Highest ionic conductivity result, 0.96 × 10−6 S·cm−1, is obtained from the nominal thin film composition of Li0.5La0.5Ti1−xAlxO3 (x = 0.05) at room temperature measurements. Heat treatment is also conducted to investigate to understand its effect on ionic conductivity and the structure of the thin films. It is found that ionic conductivity enhances with annealing. Also, temperature dependent ionic conductivity measurements from 298 K to 385 K are taken in order to evaluate activation energy for Li-ion conduction.Article Citation - WoS: 67Citation - Scopus: 80Metal Ion Release From Tin Coated Cocrmo Orthopedic Implant Material(Elsevier Ltd., 2006) Türkan, Uğur; Öztürk, Orhan; Eroğlu, Ahmet EminIn this study, a medical grade CoCrMo alloy was coated with TiN by means of physical vapor deposition (PVD) technique at 550 °C for 6 h. The TiN layer microstructure and thickness were studied by X-ray diffraction (XRD) and cross-sectional scanning electron microscopy (SEM). The adhesive strength of the TiN coatings on the CoCrMo substrate was studied by a commercially available Scanning Scratch Tester. Static immersion test was conducted to investigate the effectiveness of TiN coating in preventing the dissolution of metal ions into the simulated body fluid (SBF) from the substrate by atomic absorption spectrometry (AAS) and inductively coupled plasma optical emission spectrometry (ICP-OES). The XRD results showed that the PVD coated TiN films exhibited (111) preferred orientation, while the SEM analysis indicated quite uniform and highly dense TiN coated layer (about 3 μm thick) with a columnar growth mode reaching from substrate to coating surface. The scratch test results showed that the adhesive strength between the TiN film and the CoCrMo substrate was adequate. The AAS and ICP-OES results showed that the presence of the TiN coating prevented the release of cobalt and chromium metal ions from the substrate CoCrMo alloy whereas cobalt was preferentially dissolved from the as-polished material. Calcium phosphate precipitation was observed on the surface of the as-polished material, indicating a degree of bioactivity of the as-polished surface which is absent in the TiN coated substrate alloy.Article Citation - WoS: 82Citation - Scopus: 92Metal Ion Release From Nitrogen Ion Implanted Cocrmo Orthopedic Implant Material(Elsevier Ltd., 2006) Öztürk, Orhan; Türkan, Uğur; Eroğlu, Ahmet EminCoCrMo alloys are used as orthopedic implant materials because of their excellent mechanical and corrosion properties. However, when placed in vivo, these alloys release Co, Cr, Mo ions to host tissues, which may give rise to significant health concerns over time. Nitrogen ion implantation can be used to form protective layers on the surface of CoCrMo orthopedic alloys by modifying the near surface layers of these materials. In this study, medical grade CoCrMo alloy (IS0 5832-12) was ion implanted with 60 keV nitrogen ions to a high dose of 1.9 × 10 18 ions/cm 2 at substrate temperatures of 100, 200 and 400 °C. The N implanted layer microstructures, implanted layer phases, and thicknesses were studied by a combination of Bragg-Brentano (θ/2θ) and grazing incidence (Seeman-Bohlin) X-ray diffraction (XRD and GIXRD) and cross-sectional scanning electron microscopy (SEM). Atomic force microscopy (AFM) was used for roughness analysis of N implanted as well as as-polished surfaces. Static immersion tests were performed to investigate metal ion release into simulated body fluid (SBF) by electrothermal atomic absorption spectrometry (ETAAS) and inductively coupled plasma optical emission spectrometry (ICP-OES). XRD and SEM analyses indicated that the N implanted layers were ∼ 150-450 nm thick and composed of the (Co,Cr,Mo) 2+xN nitride phase and a high N concentration Co-based FCC phase, γ N depending on the substrate temperature. ETAAS analysis results showed that in vitro exposure of the N implanted surfaces resulted in higher levels of cobalt ion release into the simulated body fluid compared to the untreated, polished alloy. The higher Co release from the N implanted specimens is attributed to the nature of the implanted layer phases as well as to the rougher surfaces associated with the N implanted specimens compared to the relatively smooth surface of the untreated material. SEM analysis of N implanted and untreated specimens after immersion tests clearly indicated calcium phosphate formation on the as-polished CoCrMo alloy, indicating a degree of bioactivity of the untreated metal surface which is absent in the N implanted specimens.Article Citation - WoS: 49Citation - Scopus: 51Voc Sensors Based on a Metal Oxide Nanofibrous Membrane/Qcm System Prepared by Electrospinning(Royal Society of Chemistry, 2014) Horzum Polat, Nesrin; Taşçıoğlu, Didem; Özbek, Cebrail; Okur, Salih; Demir, Mustafa MuammerWe report a simple synthetic route to fabricate crystalline ZnO and CeO2/ZnO nanofibrous mats and their sensing characteristics against volatile organic compounds (VOCs) such as benzene, propanol, ethanol, and dichloromethane. Precursor fibers were fabricated by electrospinning of poly(vinyl alcohol) and metal salt(s) at 2.5 kV cm-1 in aqueous solution. The fibers were directly deposited on the crystal surface of a quartz crystal microbalance (QCM). The crystal, which was coated by nanostructured PVA/metal precursor(s) fibers, was subjected to calcination in air at 500 °C for 5 h. The formation of an oxide based nanofiber mat was revealed by scanning electron microscopy and X-ray diffraction. Upon exposure of the nanofiber mats to the VOCs, the compounds adsorbed onto the surface of oxidic fibers. The physisorption of the compounds was confirmed by FTIR and QCM. Both systems showed sensitivity to the VOCs and they hold a broad promise particularly for sensing applications of volatile alcoholic compounds. The introduction of CeO2 into the ZnO structure reduced the sensitivity of ZnO most probably due to the decrement of oxygen vacancies.