Physics / Fizik
Permanent URI for this collectionhttps://hdl.handle.net/11147/6
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Article Citation - WoS: 22Citation - Scopus: 24Preparation of the Ferrocene-Substituted 1,3-Distal P-Tert Based Qcm Sensors Array and Utilization of Its Gas-Sensing Affinities(Elsevier Ltd., 2014) Sayın, Serkan; Özbek, Cebrail; Okur, Salih; Yılmaz, MustafaThe article describes the synthesis of the new ferrocene-substituted calix[4]arene derivative 4 as sensitive layer, and suggests that the immobilization of it is on a quartz crystal microbalance gold electrode via the drop-casting method in order to produce the calix[4]arene-based QCM sensor. In addition, sensor response of the calix[4]arene-based QCM sensor was investigated towards carbon dioxide (CO2) and carbon monoxide (CO). The sensing and selectivity studies show that the ferrocene-substituted calix[4]arene-based QCM sensor is an effective gas sensor toward both carbon dioxide and carbon monoxide.Conference Object Citation - WoS: 18Citation - Scopus: 21Gas Sensing Properties of Carbon Nanotubes Modified With Calixarene Molecules Measured by Qcm Techniques(Polish Academy of Sciences, 2012) Mermer, Ömer; Okur, Salih; Sümer, F.; Özbek, Cebrail; Sayın, S.; Yılmaz, MustafaThis study focuses on the characterization and optimization of calixarene modified carbon nanotube thin films for gas detection. Calixarene molecules were synthesized individually by considering their functional groups to attract the gas. Calixarene modified carbon nanotube based sensors were fabricated using drop-casting method on a quartz crystal microbalance gold electrode. Carbon monoxide, carbondioxide, oxygen and dry air were used as active gases for adsorption process, while high-purity nitrogen gas was used for desorption process. The selectivity and sensitivity of calixarene modified carbon nanotube are investigated in detail. Our experimental results show that functional calixarene modified carbon nanotube coated quartz crystal microbalance sensors are very sensitive and selective to gas of CO 2 at room temperature operation.Article Citation - WoS: 34Citation - Scopus: 37Humidity Adsorption Kinetics of Water Soluble Calix[4]arene Derivatives Measured Using Qcm Technique(Elsevier Ltd., 2010) Okur, Salih; Kuş, Mahmut; Özel, Faruk; Yılmaz, MustafaWe report on the optimization and characterization of water soluble calix[4]arene derivative as a humidity sensor based on quartz crystal microbalance technique. The moisture adsorption and desorption kinetics of calix[4]arene were investigated. The Langmuir model was used to determine the kinetic parameters such as adsorption, desorption rates and Gibbs free energy between relative humidity between 29% and 78%. Reproducible experimental results were obtained showing that water soluble calix[4]arene films have a great potential for humidity sensing applications at room temperature operations. © 2009 Elsevier B.V. All rights reserved.Article Citation - WoS: 36Citation - Scopus: 30Humidity Adsorption Kinetics of Calix[4]arene Derivatives Measured Using Qcm Technique(Elsevier Ltd., 2010) Okur, Salih; Kuş, Mahmut; Özel, Faruk; Aybek, Vildan; Yılmaz, MustafaThis study focuses on the characterization of sulphonated calix[4]arene derivative films coated on a quartz substrate with a thickness of 40 nm by spin coating method for humidity detection. The humidity adsorption kinetics of the sulphonated calix[4]arene films was investigated by quartz crystal microbalance (QCM) technique. The Langmuir model was used to determine the adsorption rates and Gibbs free energy for various relative humidities between 11% and 97%. Our reproducible experimental results show that suphonated calix[4]arene films have a great potential for humidity sensing applications at room temperature operations. © 2009 Elsevier B.V. All rights reserved.