Physics / Fizik
Permanent URI for this collectionhttps://hdl.handle.net/11147/6
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Article Citation - WoS: 11Citation - Scopus: 13Effect of Cnt Incorporation on Pan/Ppy Nanofibers Synthesized by Electrospinning Method(TÜBİTAK, 2020) İnce Yardımcı, Atike; Selamet, Yusuf; Tanoğlu, Metin; Tanoğlu, Metin; Yılmaz, Selahattin; Yılmaz, Selahattin; Selamet, Yusuf; 03.02. Department of Chemical Engineering; 03.10. Department of Mechanical Engineering; 04.05. Department of Pyhsics; 03. Faculty of Engineering; 04. Faculty of Science; 01. Izmir Institute of TechnologyIn this study, carbon nanotubes (CNTs) added polyacrylonitrile/polypyrrole (PAN/PPy) electrospun nanofibers were produced. Average diameters of the nanofibers were measured as 268 and 153 nm for 10 and 25 wt% of PPy contents, respectively. A relatively higher strain to failure values (23.3%) were observed for the low PPy content. When as-grown CNTs (1 and 4 wt%) were added into the PAN/PPy blends, disordered nanofibers were observed to form within the microstructure. To improve the interfacial properties of CNTs/PAN/PPy composites, CNTs were functionalized with H2SO4/HNO3/HCl solution. The functionalized CNTs were well dispersed within the nanofibers and aligned along the direction of nanofibers. Therefore, beads formation on nanofibers decreased. The impedance of the nanofibers was found to decrease with the PPy content and CNT addition. These nanofibers had a great potential to be used as an electrochemical actuator or a tissue engineering scaffold.Article Citation - WoS: 17Citation - Scopus: 17Monitoring the Doping and Diffusion Characteristics of Mn Dopants in Cesium Lead Halide Perovskites(American Chemical Society, 2018) Güner, Tuğrul; Şahin, Hasan; Akbalı, Barış; Demir, Mustafa Muammer; Özcan, Mehmet; Topçu, Gökhan; Demir, Mustafa Muammer; Şahin, Hasan; 04.04. Department of Photonics; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 04. Faculty of Science; 01. Izmir Institute of TechnologyCesium lead perovskites, in the form of CsPbX3 or Cs4PbX6, have been widely used for various optoelectronic applications due to their exceptionally good optical properties. In this study, the effect of Mn doping on the structural and optical properties of cesium lead halide perovskite crystals are investigated from both experimental and theoretical points of view. It is found that adding MnCl2 during the synthesis not only leads to a Mn-driven structural phase transition from Cs4PbBr6 to CsPbCl3 but also triggers the Br- to Cl- halide exchange. On the other hand, it is observed that, under UV illumination, the color of Mn-doped crystals changes from orange to blue in approximately 195 h. While the intensity of Mn-originated photoluminescence emission exponentially decays in time, the intensity of CsPbCl3-originated emission remains unchanged. In addition, diffusive motion of Mn ions results in both a growing population of MnO2 at the surface and transition of the host into a cesium-rich Cs4PbCl6 phase.Article Citation - WoS: 15Citation - Scopus: 14Development of Electrically Conductive and Anisotropic Gel-Coat Systems Using Cnts(Elsevier Ltd., 2013) İnce Yardımcı, Atike; Tanoğlu, Metin; Selamet, Yusuf; Tanoğlu, Metin; 03.10. Department of Mechanical Engineering; 04.05. Department of Pyhsics; 03. Faculty of Engineering; 04. Faculty of Science; 01. Izmir Institute of TechnologyElectrical conductivity of an unsaturated thermoset polyester based gel-coat system containing 0.05 wt.% of carbon nanotubes (CNTs) was investigated. The CNTs used were synthesized by chemical vapor deposition method by methane decomposition and Raman characterization showed that they were mostly single walled and high quality. To disperse CNTs in the gel-coat resin, 3-roll milling technique was used. It was found that as the CNTs are added to gel-coat system, resistivity value decreases significantly while neat gel-coat showed a high resistivity. By the application of an AC electrical field during curing process, it was attempted to align CNTs in the gel-coat resin and an electrically anisotropic polymer was obtained. © 2012 Elsevier B.V. All rights reserved.Article Citation - WoS: 8Citation - Scopus: 12A Microstructural Study of Surface Hydration on a Magnesia Refractory(Elsevier Ltd., 2010) Sütçü, Mücahit; Akkurt, Sedat; Okur, Salih; Akkurt, Sedat; 04.05. Department of Pyhsics; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 04. Faculty of Science; 01. Izmir Institute of TechnologyHydration of the surface of a periclase refractory was studied in a controlled humidity atmosphere (92% relative humidity) at 26 °C for up to 92 h. The effect of humidity on the specimens was examined using a scanning probe microscope (SPM) and a scanning electron microscope (SEM), which showed that the degree of hydration was noticeably less in the intergranular bond phase compared to the periclase crystallites. The SPM study indicated significant growth of hydrates on the refractory grain surface. Growth rate of the hydrate layer was least on (0 0 1) orientation, higher for the (1 0 3) orientation, and highest for the (1 0 1) oriented grain. The rate of loss of refractory phases by hydration on a (1 0 1) oriented grain was 4.53 nm/h. This material loss may be insignificant for a bulk brick, but is a serious threat for a magnesia castable consisting of fine magnesia powder due to large surface area exposed to humidity or water itself. © 2010 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
