Physics / Fizik
Permanent URI for this collectionhttps://hdl.handle.net/11147/6
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Book Part Citation - Scopus: 1Thz Sources and Detectors Fabricated From High Temperature Superconductors(Springer, 2021) Demirhan, Yasemin; Türkoğlu, Fulya; Altan, Hakan; Sabah, Cumali; Özyüzer, LütfiHigh temperature superconductors have unique properties that can be useful in the THz region, single crystal constituted from superconducting CuO2-layers could sustain high voltages across the junctions and they are coupled through the intrinsic Josephson Effect this maintains the potential for very intense, coherent radiation which spreads over the THz gap. We investigated various experimental techniques to fabricate THz sources, bolometers and filters for efficient THz emission and detection. Rectangular mesa structures were fabricated on Bi2Sr2CaCu2O8-x (Bi2212) single crystal superconductors using standard e-beam lithography and Ar ion beam etching systems and an emitted power as high as 60 ?W at frequencies up to 0.85 THz was detected from micron sized continuous wave terahertz sources. We also fabricated bolometric microchips for THz detection purpose from Bi2212 single crystals. Bi2212 microchips detected the signals and response time were calculated, our results have clearly shown that Bi2212 single crystals are potential candidates for THz detection. The detection properties and sensitivity of bolometer chips can be further improved by integrating an antenna and filter structures. In order to investigate this we have fabricated metamaterial THz filters based on metals and YBa2Cu3Ox superconducting thin films with metal-mesh shape and a unique fourcross shape pattern. Both a THz time domain spectrometer and a Fourier transform infrared spectrometer (FTIR) were used to investigate the performance of these filters and the results were compared with simulations done with a commercially available electromagnetic simulation software. © Springer Nature B.V. 2021.Book Part Future Applications of Artificially-Synthesized Organic Molecules Containing Transition-Metal Atoms(Elsevier, 2018) Mayda, Selma; Kandemir, Zafer; Bulut, NejatArtificially-synthesized organic molecules which contain transition-metal atoms offer new possibilities for applications in the electronics, pharmaceutical, and chemical industries. Hence, developing an understanding of the electronic properties of this kind of organic molecules is important. With this purpose, here we study the electronic properties of metalloproteins, metalloenzymes, and Ru-based dye molecules as examples for this kind of organic molecules. In particular, we perform combined Hartree-Fock (HF) and quantum Monte Carlo (HF+QMC) calculations, as well as combined density functional theory (DFT) and QMC (DFT+QMC) calculations to study the electronic properties of these molecules. Our results show that new electronic states named as impurity bound states (IBS) form in metalloproteins, metalloenzymes, and Ru-based dye molecules. We show that the electron occupancy of IBS is critically important in determining the low-energy electronic properties of these molecules. In this respect, the IBS may play a central role in developing new applications based on artificially-synthesized organic molecules containing transition-metal atoms. © 2018 Elsevier Inc. All rights reserved.
