Environmental Engineering / Çevre Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4321
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Article Pomza ve Nsdd-pomza ile Sabit Yataklı Kolon Reaktörde Metilen Mavisi Giderimi: Deneysel ve Modelleme Çalışması(2019) Balcı, Esin; Ökten, Hatice Eser; Genişoğlu, Mesut; Recepoğlu, Yaşar Kemal; Gören, Ayşegül YağmurNano sıfır değerlikli demir (nSDD) yüksek renk konsantrasyonlarına sahip tekstil atıksularının arıtımında ekonomik ve çevre dostu bir adsorban olarak ortaya çıkmaktadır. Ancak nSDD partikülleri sulu çözeltilerde elektrostatik etkileşimler sebebiyle kolayca topaklaşmakta ve bu da arıtma veriminin düşmesine neden olmaktadır. Dolayısıyla düşük maliyetli, doğal poröz yapıda ve ortalama 2m2/gr spesifik yüzey alanına sahip pomza, nSDD topaklaşmasını önleyici bir malzeme olarak kullanılabilir. Bu çalışmada sadece pomza ve pomzanSDD (ağırlıkça 9:1) karışımının kullanıldığı kolon reaktörde 25, 50, 75 ve 100 mg/L metilen mavisi konsantrasyonları için arıtma verimleri incelenmiştir. Pomzanın ve pomza-nSDD karışımının 100 mg/L metilen mavisi deneyindeki toplam kapasiteleri sırasıyla 2,8 ve 4,2 mg/g-adsorban olarak bulunmuştur. Özellikle düşük konsantrasyonlarda, pomza-nSDD karışımının arıtma performansını önemli ölçüde arttırdığı görülmüştür. Thomas modeli deneysel verilere uygulanmış ve modelin öngörü gücünün düşük konsantrasyonda yüksekken, yüksek konsantrasyonlarda ortalama olduğu kanısına varılmıştır.Article Citation - WoS: 10Citation - Scopus: 12Novel Hybrid Adsorption-Electrodialysis (aded) System for Removal of Boron From Geothermal Brine(American Chemical Society, 2022) Altınbaş, Bekir Fırat; Orak, Ceren; Ökten, Hatice Eser; Yüksel, AslıA novel hybrid adsorption-electrodialysis (AdED) system to remove environmentally harmful boron from geothermal brine was designed and effective operating parameters such as pH, voltage, and flow rate were studied. A cellulose-based adsorbent was synthesized from glycidyl methacrylate (GMA) grafted cellulose and modified with a boron selective n-methyl-d-glucamine (NMDG) group and characterized with SEM-EDX, FT-IR, and TGA analyses. Batch adsorption studies revealed that cellulose-based adsorbent showed a remarkable boron removal capacity (19.29 mg/g), a wide stable operating pH range (2-10), and an adsorption process that followed the Freundlich isotherm (R2= 0.95) and pseudo-second-order kinetics (R2= 0.99). In the hybrid AdED system, the optimum operating parameters for boron removal were found to be a pH of 10, a voltage of 10 V, a flow rate of 100 mL/min, and an adsorbent dosage of 4 g/L. The presence of the adsorbent in the hybrid system increased boron removal from real geothermal brine (containing 199 ppm boron) from 7.2% to 73.3%. The results indicate that the designed AdED system performs better than bare electrodialysis for boron removal from ion-rich real geothermal brine while utilizing environmentally friendly cellulose-based adsorbent.Article Citation - WoS: 31Citation - Scopus: 35Electrochemical Degradation of Methylene Blue by a Flexible Graphite Electrode: Techno-Economic Evaluation(American Chemical Society, 2022) Gören, Ayşegül Yağmur; Recepoğlu, Yaşar Kemal; Edebali, Özge; Şahin, Çağrı; Genişoğlu, Mesut; Ökten, Hatice EserIn this study, electrochemical removal of methylene blue (MB) from water using commercially available and low-cost flexible graphite was investigated. The operating conditions such as initial dye concentration, initial solution pH, electrolyte dose, electrical potential, and operating time were investigated. The Box-Behnken experimental design (BBD) was used to optimize the system's performance with the minimum number of tests possible, as well as to examine the independent variables' impact on the removal efficiency, energy consumption, operating cost, and effluent MB concentration. The electrical potential and electrolyte dosage both improved the MB removal efficiency, since increased electrical potential facilitated production of oxidizing agents and increase in electrolyte dosage translated into an increase in electrical current transfer. As expected, MB removal efficiency increased with longer operational periods. The combined effects of operating time-electrical potential and electrical potential-electrolyte concentration improved the MB removal efficiency. The maximum removal efficiency (99.9%) and lowest operating cost (0.012 $/m3) were obtained for initial pH 4, initial MB concentration 26.5 mg/L, electrolyte concentration 0.6 g/L, electrical potential 3 V, and operating time 30 min. The reaction kinetics was maximum for pH 5, and as the pH increased the reaction rates decreased. Consequent techno-economic assessment showed that electrochemical removal of MB using low-cost and versatile flexible graphite had a competitive advantage.Article Citation - WoS: 40Citation - Scopus: 47Boron in Geothermal Energy: Sources, Environmental Impacts, and Management in Geothermal Fluid(Elsevier, 2022) Mott, A.; Baba, Alper; Hadi Mosleh, Mojgan; Ökten, Hatice Eser; Babaei, Masoud; Gören, Ayşegül Yağmur; Feng, C.; Recepoğlu, Yaşar Kemal; Uzelli, Taygun; Uytun, Hüseyin; Morata, Diego; Yüksel Özşen, AslıThe problem of hazardous chemicals in geothermal fluid is a critical environmental concern in geothermal energy developments. Boron is among the hazardous contaminants reported to be present at high concentrations in geothermal fluids in various countries. Poor management and inadequate treatment of geothermal fluids can release excessive boron to the environment that has toxic effects on plants, humans, and animals. Despite the importance of boron management in geothermal fluid, limited and fragmented resources exist that provide a comprehensive understanding of its sources, transport and fate, and the treatment strategies in geothermal energy context. This paper presents the first critical review from a systematic and comprehensive review on different aspects of boron in geothermal fluid including its generation, sources, toxicity, ranges and the management approaches and treatment technologies. Our research highlights the origin of boron in geothermal water to be mainly from historical water-rock interactions and magmatic intrusion. Excessive concentrations of boron in geothermal fluids have been reported (over 500 mg/L in some case studies). Our review indicated that possible boron contamination in geothermal sites are mostly due to flawed construction of production/re-injection wells and uncontrolled discharge of geothermal water to surface water. The dominancy of non-ionic H3BO3 species makes the selection of the suitable treatment method for geothermal waters limited. Combining boron selective resins and membrane technologies, hybrid systems have provided effluents suitable for irrigation. However, their high energy consumption and course structure of boron selective resins encourage further research to develop cost-effective and environmentally friendly alternatives.Article Citation - WoS: 13Citation - Scopus: 14Desalination and Detoxification of Textile Wastewater by Novel Photocatalytic Electrolysis Membrane Reactor for Ecosafe Hydroponic Farming(MDPI, 2022) Aydın, Muhammed Iberia; Özaktaç, Damla; Yüzer, Burak; Doğu, Mustafa; İnan, Hatice; Ökten, Hatice Eser; Coşkun, Serdar; Selçuk, HüseyinIn this study, a novel photoelectrocatalytic membrane (PECM) reactor was tested as an option for the desalination, disinfection, and detoxification of biologically treated textile wastewater (BTTWW), with the aim to reuse it in hydroponic farming. The anionic ion exchange (IEX) process was used before PECM treatment to remove toxic residual dyes. The toxicity evaluation for every effluent was carried out using the Vibrio fischeri, Microtox® test protocol. The disinfection effect of the PECM reactor was studied against E. coli. After PECM treatment, the 78.7% toxicity level of the BTTWW was reduced to 14.6%. However, photocatalytic desalination during treatment was found to be slow (2.5 mg L-1 min-1 at 1 V potential). The reactor demonstrated approximately 52% COD and 63% TOC removal efficiency. The effects of wastewater reuse on hydroponic production were comparatively investigated by following the growth of the lettuce plant. A detrimental effect was observed on the lettuce plant by the reuse of BTTWW, while no negative impact was reported using the PECM treated textile wastewater. In addition, all macro/micronutrient elements in the PECM treated textile wastewater were recovered by hydroponic farming, and the PECM treatment may be an eco-safe wastewater reuse method for crop irrigation.Article Noktasal Kaynaklar için Ulusal Hava Kirliliği Emisyon Faktörleri ve Envanterinin Belirlenmesi: Metal Sektörü için Örnek Bir Çalışma(Marmara Üniversitesi, 2021) Özdemir, Hüseyin; Aktaş, Muhammet Ali; Yalçın, İbrahim Ertuğrul; Alyüz, Ümmügülsüm; Ökten, Hatice Eser; Özcan, H. Kurtuluş; Köksal, Canan Esin; Çetintürk Gürtepe, İrde; Demir, Göksel; Ünal, AlperHava kalitesinin korunması için yürütülen çalışmalar ve yasal uygulamalar, günümüzde çevre bilincinin artması ile daha daönemli hale gelmiştir. Yenilenebilir enerji kullanımının yaygınlaştırılması gibi çevre dostu düzenlemeler ile hava kalitesininiyileştirilmesi artık ülke politikalarında yer almaktadır. Hava kalitesinin yükseltilmesine yönelik yasal düzenlemelerinhazırlanmasında mevcut durumun ortaya konması büyük önem taşımaktadır. Atmosfere verilen kirliliğin miktarının doğruolarak tespit edilebilmesi ve illerin temiz hava eylem planlarının hazırlanabilmesi için ulusal ölçekte, kaynaklarına göre havakirleticilerinin emisyon envanterinin hesaplanması, ulusal ve uluslararası sorumluluklar gereği atmosfere verdiğimizemisyonların belirli periyotlarda raporlanması gerekmektedir. Bu nedenle, emisyon envanterinin belirli bir düzen içerisinde,kirlilik kaynaklarına ait veriler ve yerel emisyon faktörleri kullanılarak hazırlanması gerekmektedir. Bu çalışmada, MarmaraBölgesi pilot bölge seçilerek Çevre ve Şehircilik Bakanlığı ile birlikte ülkemizde ilk defa ulusal emisyon envanteri geliştirilmesiprojesi gerçekleştirilmiştir. Bu çalışmadaki noktasal kaynaklar için yapılan kısım bu makalede anlatılmış ve metal sektörüyleilgili elde edilen sonuçlar verilmiştir. Marmara Bölgesi’ndeki metal sektörünün emisyon envanteri hesaplamasında 27 tesisin128 emisyon kaynak bilgisi kullanılmıştır. Ulusal emisyon faktörleriyle yapılan hesaplamalara göre emisyon değerleri; CO için46.849 ton/yıl, SO2 için 7.589 ton/yıl, NOx için 8.906 ton/yıl ve TSP için 1.759 ton/yıl bulunmuştur.Article Phytoremediation of Boron Containing Synthetic Aqueous Solutions and Real Geothermal Water Using Lemna Minor(2021) Ökten, Hatice Eser; Gören, Ayşegül YağmurIn this paper, phytoremediation performance of Lemna minor L. on boron (B) removal from synthetic solution and real geothermal brine was evaluated. Effects of B concentration, initial pH, water height in cell, and initial humic acid concentration were investigated. The maximum removal efficiency was 96.7 % with the experimental run with B concentration of 5 mg L-1, pH 8, and 1.5 cm water depth. Increasing the B concentration from 5 to 30 mg L-1 resulted in a drastic decrease in removal efficiency to 36.6 %, due to the toxic effect of high boron content, which was clearly observed from deterioration of plant’s color and structure. SEM, FTIR, and mass balance analyses revealed that the boron removal mechanism was mainly biosorption. Geothermal water experiments indicated L. minor’s applicability with 59.5% removal efficiency, proving high potential in being used for post-treatment of geothermal waters with high boron content.Article An Experimental Study on Release Mechanism of Iron and Manganese From Sediments To the Water Column in Reservoirs(2021) Vural, Buse; Elçi, Şebnem; Ökten, Hatice EserIron and manganese accumulation in drinking water reservoirs is a challenging issue and should be controlled to prevent their adverse effects on human health. Accumulation of these elements not only clogs pipeline systems but also causes stains on fixtures and laundry. Also, high concentrations of iron and manganese may lead to various health problems when ingested. This study focuses on the release mechanism of iron and manganese from sediments to the water column in reservoirs and investigates methods to prevent this release. Effects of hypoxia, hypolimnetic aeration, alkalinity of water, and thermal stratification on iron and manganese concentrations were investigated through laboratory experiments. Experiments done simulating the water column showed that hypoxia caused more dissolution of ferrous iron when compared with that of manganese. Accordingly, aeration of the water column in hypoxic conditions lead to a significant decrease in ferrous iron concentrations (in our case reaching zero). However, manganese and total iron levels were not affected by the aeration of the water column. Alkalinity level of the water column was observed to have a great effect on the solubility of iron and manganese. Concentrations of total Fe and total Mn measured for acidic (pH = 5) conditions were considerably greater than concentrations measured at neutral conditions. As for alkaline (pH = 11) conditions, the opposite was observed with measured concentrations of total Fe and total Mn being lower than the ones measured for neutral conditions. Thermal stratification had an enhancing effect on the solubility of both iron and manganese ions. While aeration of the stratified water column slightly decreased the concentrations of Total Fe and Mn, it had a greater impact on decreasing $Fe^{2+}$ concentrations.Article Citation - WoS: 33Citation - Scopus: 37Energy Production From Treatment of Industrial Wastewater and Boron Removal in Aqueous Solutions Using Microbial Desalination Cell(Elsevier, 2021) Gören, Ayşegül Yağmur; Ökten, Hatice EserAs a result of a much needed paradigm shift worldwide, treated saline water is being considered as a viable option for replacing freshwater resources in agricultural irrigation. Vastly produced geothermal brine in Turkey may pose a significant environmental risk due to its high ionic strength, specifically due to boron. Boron species, which are generally found uncharged in natural waters, are costly to remove using high-throughput membrane technologies such as reverse osmosis. Recent advances in bioelectrochemical systems (BES) has facilitated development of energetically self-sufficient wastewater treatment and desalination. In this study, removal of boron from synthetic solutions and real geothermal waters, along with simultaneous energy production, using the microbial desalination cell (MDC) were investigated. Optimization studies were conducted by varying boron concentrations (5, 10, and 20 mg L-1), air flow rates (0, 1, and 2 L min(-1)), electrode areas (18, 24, 36, and 72 cm(2)), catholyte solutions, and operating modes. Even though the highest concentration decrease was observed for 20 mg-B L-1, 5 mg-B L-1 concentration experiment gave the closest result to the 2.4 mg-B L-1 limit value asserted by WHO. Effect of electrode surface area was proven to be significant on boron removal efficiency. Employing the optimum conditions acquired with synthetic solutions, boron and COD removal efficiencies from real geothermal brine were 44.3% and 90.6%, respectively. MDC, being in its early levels of technology readiness, produced promising desalination and energy production results in removal of boron from geothermal brine.Article Fotobiyokataliz Yöntemi Kullanılarak Pestisit Giderimi-derleme Çalışması(Niğde Ömer Halisdemir Üniversitesi, 2019) Okçu, Gamze; Ökten, Hatice Eser; Yalçuk, ArdaAromatik yapılı, çevresel koşullarda zorlukla parçalanabilen, kararlı organik kirleticilerin başında gelen pestisitler, atmosfere, su sistemlerine, besin zincirine taşınmakta, asıl kaynaklarından çok uzak noktalarda birikebilmektedir. Konvansiyonel arıtma proseslerinin pestisitlerin gideriminde yetersiz kalmasından dolayı kirletilmiş sulardan uzaklaştırılmaları için yeni arıtım teknolojilerine ihtiyaç duyulmaktadır. Son yıllarda, su sistemlerinden konvansiyonel tekniklerle arıtılamayan kirleticilerin giderilmesinde birleşik fotokatalitik-biyolojik arıtma umut verici bir alternatiftir: Fotokataliz toksik organikleri biyolojik olarak parçalanabilir ürünlere dönüştürürken, biyolojik parçalama ürünlerini verimli şekilde mineralize eder. Ön arıtma sırasında gereksiz kimyasal ve %60 oranında enerji sarfiyatından kaçınmak amacıyla ön arıtma basamağında mineralizasyon yüzdesi minimalize edilerek çalışma maliyeti düşürülür. Literatüre göre yalnız kimyasal prosesle yaklaşık %80 pestisit parçalanması ve %50’den az mineralizasyon gözlemlenebilirken hibrit reaktör sistemiyle tamamen parçalanma ve yaklaşık %90 pestisit mineralizasyonu elde edilebilmektedir. Bu derlemenin amacı, fotobiyokataliz işleminin, bireysel fotokataliz ve/veya biyolojik arıtma yöntemlerine göre pestisit giderim koşulları kapsamında, temellerini, mekanizmalarını ve literatürde yer alan güncel çalışmaları ele almak ve incelemektir.
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