Environmental Engineering / Çevre Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4321
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Article Citation - WoS: 10Citation - Scopus: 12Removal of Arsenate by Electrocoagulation Reactor Using Aluminum Ball Anode Electrodes(IWA Publishing, 2018) Gören, Ayşegül Yağmur; Öncel, Mehmet Salim; Demirbaş, Erhan; Şık, Emrah; Kobya, MehmetThe aim of this research was to remove arsenate (As(V)) from groundwater using an air-injected electrocoagulation (EC) reactor with aluminum (Al) ball anodes. The effects of seven operating variables - initial pH, applied current (i), operating time (t(EC)), initial As(V) concentration (C-o), Al ball anode diameter (d(p)), reactor column height (h), and airflow rate (Q(air)) were investigated with a Box-Behnken statistical experimental design. ANOVA results from the quadratic model equations indicated that the model fitted very well with the experimental data for the responses, which were removal efficiency, operating cost (OC), As(V) adsorption capacity, and effluent concentration (R-2 >= 0.87). The most effective parameters were applied current, operating time, and anode height for As(V) removal efficiency in the EC reactor, while initial pH, Al anode diameter, and air flow rate had limited effect on removal. The model predicted a residual As(V) concentration below 10 mu g/L under the optimum operating conditions (pH 7.03, 0.29 A, 10.5 min, d(p) 7.5 mm, 613.4 mu g/L, h 5.1 cm, and Q(air) 6.4 L/min). The maximum As(V) removal efficiency and minimum OC in the EC process were almost 99% and 0.442 $/m(3), respectively.Article Citation - WoS: 26Citation - Scopus: 34Arsenite Removal From Groundwater in a Batch Electrocoagulation Process: Optimization Through Response Surface Methodology(Taylor & Francis, 2019) Şık, Emrah; Gören, Ayşegül Yağmur; Demirbaş, Erhan; Kobya, Mehmet; Öncel, Mehmet SalimIn this study, influences of seven process variables such as initial pH (pH(i)), applied current (i), operating time (t(EC)), initial As(III) concentration (C-o), diameter of Fe ball anode (d(p)), column height in the electrocoagulation (EC) reactor (h) and airflow rate (Q(air)) for removal of As(III) from groundwater by a new air-fed fixed-bed EC reactor were evaluated with a response surface methodology (RSM). The proposed quadratic model fitted very well with the experimental data for the responses. The removal efficiencies and operating costs were determined to be 99% and 0.01 $/m(3) at the optimum operating conditions (a pH(i) of 8.5, 0.05 A, 4.94 min, d(p) of 9.24 mm, h of 7.49 cm, Q(air) of 9.98 L/min for 50 mu g/L). This study clearly showed that the RSM in the EC process was a very suitable method to optimize the operating conditions at the target value of effluent As(III) concentration (10 mu g/L) while keeping the operating cost to minimal and maximize the removal efficiency.
