Environmental Engineering / Çevre Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4321
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Article Citation - WoS: 3Citation - Scopus: 4Enhancing Biogas Production From Chicken Manure Through Vacuum Stripping of Digestate(Springer Heidelberg, 2023) Sengur, Ozlem; Akgul, Deniz; Bayrakdar, Alper; Calli, BarisThe vacuum stripping's combined ammonia removal and disintegration effect on chicken manure digestate was evaluated for the first time at different pH values (8.5, 9.5, and 10.5) and temperatures (30, 50, and 70 degrees C). In this way, the potential increase in biogas production by recirculating the vacuum-stripped digestate to the anaerobic digester was determined. Experimental results showed that increasing pH and temperature significantly increase TAN removal, but pH is more effective. A significant portion of the ammonia was removed in the first 30 min. Therefore, a second set of stripping tests was performed for 30 min and at 70 degrees C and pH 10.5. After 30-min tests, a biomethane potential (BMP) assay was performed using the vacuum-stripped digestate to determine how vacuum stripping affects biomethane production. Despite having the lowest disintegration efficiency, the highest biomethane potential (56.2 +/- 29.7 mL CH4/gVS) was obtained with the digestate, which was subjected to vacuum stripping at 70 celcius without pH adjustment, and 48.7% more methane was produced than the control set. The lower residual biomethane potential in vacuum-stripped digestate at pH 9.5 and 10.5 was attributed to Na+ inhibition resulting from high NaOH consumption for pH adjustment.Article Citation - WoS: 19Citation - Scopus: 18An Appraisal of the Local-Scale Spatio-Temporal Variations of Drought Based on the Integrated Grace/Grace-fo Observations and Fine-Resolution Fldas Model(Wiley, 2023) Khorrami, Behnam; Ali, Shoaib; Gündüz, OrhanThe gravity recovery and climate experiment (GRACE) observations have so far been utilized to detect and trace the variations of hydrological extremes worldwide. However, applying the coarse resolution GRACE estimates for local-scale analysis remains a big challenge. In this study, a new version of the fine resolution (1 km) Famine early warning systems network Land Data Assimilation System (FLDAS) model data was integrated into a machine learning model along with the GRACE data to evaluate the subbasin-scale variations of water storage, and drought. With a correlation of 0.99 and a root mean square error (RMSE) of 3.93mm of its results, the downscaling model turned out to be very successful in modelling the finer resolution variations of TWSA. The water storage deficit (WSD) and Water Storage Deficit Index (WSDI) were used to determine the episodes and severity of drought events. Accordingly, two severe droughts (January 2008 to March 2009 and September 2019 to December 2020) were discerned in the Kizilirmak Basin (KB) located in Central Turkiye. The characterization of droughts was evaluated based on WSDI, scPDSI, and model-based drought indices of the soil moisture storage percentile (SMSP) and groundwater storage percentile (GWSP). The results indicated discrepancies in the drought classes based on different indices. However, the WSDI turned out to be more correlated with GWSP, suggesting its high ability to monitor groundwater droughts as well.Article Citation - WoS: 1Citation - Scopus: 1Exposure To Fumes of a Vegetable Margarine for Frying: Respiratory Effects in an Experimental Model(American Chemical Society, 2023) Cimrin, Arif H.; Alpaydin, Aylin Ozgen; Ozbal, Seda; Toprak, Melis; Yılmaz, Osman; Uluorman, Funda; Ergur, Bekir Uğur; Gürel, Duygu; Sofuoğlu, Sait CemilDeep frying is one of the strongest emission sources into indoor air. A vegetable margarine has recently been used in commercial kitchens. This study investigated the respiratory effects of exposure to its fumes in an experimental model. A setup with glass chambers was constructed. A chamber housed a fryer. The fumes were transported to the other chamber where 24 Wistar albino rats were placed in four randomized groups: acute, subacute, chronic, and control for the exposure durations. PM10 concentration in the exposure chamber was monitored to ensure occupational levels were obtained. Sacrification was performed 24 h after exposure. Lung, trachea, and nasal concha specimens were evaluated by two blinded histologists under a light microscope with hematoxylin–eosin. Mild mononuclear cell infiltration, alveolar capillary membrane thickening, alveolar edema, and diffuse alveolar damage, along with diffuse hemorrhage, edema, and vascular congestion in the interstitium were observed in the acute and subacute groups, and were overexpressed in the chronic group, whereas normal lung histology was observed in the control group. The results indicate that exposure to fumes of vegetable margarine for frying in commercial kitchens may cause pulmonary inflammation that becomes severe as the duration of the exposure increases.Review Citation - WoS: 41Citation - Scopus: 42Review on the Parameters of Recycling Ndfeb Magnets Via a Hydrogenation Process(American Chemical Society, 2023) Habibzadeh, Alireza; Küçüker, Mehmet Ali; Gökelma, MertolRegarding the restrictions recently imposed by China on the export of rare-earth elements (REEs), the world may face a serious challenge in supplying some REEs such as neodymium and dysprosium soon. Recycling secondary sources is strongly recommended to mitigate the supply risk of REEs. Hydrogen processing of magnetic scrap (HPMS) as one of the best approaches for magnet-to-magnet recycling is thoroughly reviewed in this study in terms of parameters and properties. The processes of hydrogen decrepitation (HD) and hydrogenation-disproportio-nation-desorption-recombination (HDDR) are two common methods for HPMS. Employing a hydrogenation process can shorten the production route of new magnets from the discarded magnets compared to other recycling routes such as the hydrometallurgical route. However, determining the optimal pressure and temperature for the process is challenging due to the sensitivity to the initial chemical composition and the interaction of temperature and pressure. Pressure, temperature, initial chemical composition, gas flow rate, particle size distribution, grain size, and oxygen content are the effective parameters for the final magnetic properties. All these influencing parameters are discussed in detail in this review. The recovery rate of magnetic properties has been the concern of most research in this field and can be achieved up to 90% by employing a low hydrogenation temperature and pressure and using additives such as REE hydrides after hydrogenation and before sintering.Article Citation - WoS: 16Citation - Scopus: 20Development of an Emission Estimation Method With Satellite Observations for Significant Forest Fires and Comparison With Global Fire Emission Inventories: Application To Catastrophic Fires of Summer 2021 Over the Eastern Mediterranean(Elsevier, 2023) Bilgiç, Efem; Tuna Tuygun, Gizem; Gündüz, OrhanIn the past few decades, forest fires have increased in number and severity, especially in the Mediterranean regions of Turkiye and Greece, where significant fires caused damage to thousands of hectares of land as well as wildlife. The main objective of the present study is to develop an emission estimation method with satellite-based burned area data from significant forest fire events in the Eastern Mediterranean in July-August 2021. In the first stage of this study, pre-fire and post-fire images of the study area acquired by the Sentinel-2 satellite were processed to calculate the normalized burn rate difference index (dNBR). Then, CORINE Land Cover (CLC) data were used for detecting land cover classes in the burned areas. Atmospheric emissions of NOx, CO, SO2, total suspended particulate matter (TSP), particulate matter with diameters that are equal to or smaller than 2.5 & mu;m (PM2.5), and black carbon (BC) were estimated using the EMEP/EEA Tier 2 -technology-specific approach method, in which burned area maps were retrieved using Sentinel-2 imageries and later combined with land cover type and burning efficiency to estimate the quantity of burning biomass emissions. Emission factors were then used to estimate the fires' trace gas and aerosol emissions. The results showed that the highest burned areas were found in the western Mediterranean region in Turkiye and Central Greece (⁓50,000 ha). The atmospheric emissions from these fires were calculated to be similar in both countries. Furthermore, emission amounts were compared with three different global fire emission inventories including GFAS, GFED, and FINN. The emissions obtained from the GFAS database were the highest emissions of the four emission estimation approaches and our estimated emissions were close to the GFAS. Emissions calculated from the other two databases (FINN and GFED) mostly provided underestimated emissions. The emission uncertainties in this study mainly originated from assumptions regarding the inclusion of burned area efficiency in emission calculations, the landcover dataset, and the emission factors used. Overall, this study is considered a new approach to emission calculations using Sentinel-2 data. This research provides further insight into the use of Sentinel-2 data in emission calculation applications at the local to regional scales.Article Citation - WoS: 31Citation - Scopus: 34Model-Coupled Grace-Based Analysis of Hydrological Dynamics of Drying Lake Urmia and Its Basin(Wiley, 2023) Khorrami, Behnam; Ali, Shoaib; Şahin, Onur Güngör; Gündüz, OrhanLake Urmia basin (LUB), in northwestern Iran, is under the influence of extreme degradation due to a number of natural and anthropogenic factors. The existence of the Lake is critical for the microclimate of the region as well as the quality of human life and wildlife, which necessitates an up-to-date and holistic analysis of its hydrological dynamics. In this premise, satellite-based terrestrial water storage (TWS) received from the Gravity Recovery and Climate Experiment (GRACE) mission was coupled with hydrometeorological modelling and assessment tools to analyse the hydrological status of the lake and its basin. As a new gap-filling approach, the Seasonal-Trend decomposition using Locally estimated scatterplot smoothing (LOESS) (STL) decomposition technique was proposed in this study to reconstruct the missing TWS data. Integrating satellite precipitation data with the Catchment Land Surface Model (CLSM) and WaterGAP model outputs, the hydrological status of the lake was investigated. The STL-based TWS turned out to concord well with the simulated TWS from the CLSM indicating the acceptable performance of the proposed technique. The findings revealed that the LUB had undergone an alarming hydrological situation from 2003 to 2021 with a total loss of 10 and 7.56km3 from its TWS and groundwater storage (GWS), respectively. The water level time series also indicated that the water level of the lake had diminished with an annual rate of -70 +/- 21cm/year corresponding to a total water level depletion of about 13.35 +/- 3.9m during the 2003-2021 period. The GRACE-derived TWS and GWS also agreed well with the CLSM simulations. Assessment of the extreme events of the LUB suggested that the basin suffered from a severe dry event in 2008 resulting in the depletion of its water storage and water level. It was also found that from 2003 onward, a critical hydrological setting had dominated the LUB with a negative hydrological balance of -0.96km3.Article Citation - WoS: 3Citation - Scopus: 6Halogenated By-Products in Chlorinated Indoor Swimming Pools: a Long-Term Monitoring and Empirical Modeling Study(Amer Chemical Soc, 2023) Genişoğlu, Mesut; Minaz, Mert; Tanacan, Ertaç; Sofuoğlu, Sait Cemil; Kaplan-Bekaroğlu, Şehnaz Şule; Kanan, Amer; Ateş, NurayMonitoring the disinfection process and swimming pool water quality is essential for the prevention of microbial infections and associated diseases. However, carcinogenic and chronic-toxic disinfection by-products (DBPs) are formed with reactions between disinfectants and organic/inorganic matters. DBP precursors in swimming pools originate from anthropogenic sources (body secretions, personal care products, pharmaceuticals, etc.) or chemicals used in pools. Temporal (48 weeks) water quality trends of trihalomethanes (THMs), haloacetic acids (HAAs), haloacetonitriles (HANs), and halonitromethanes (HNMs) in two swimming pools (SP-A and SP-B) and precursor-DBP relationships were investigated in this study. Weekly samples were taken from swimming pools, and several physical/chemical water quality parameters, absorbable organic halides (AOX), and DBPs were determined. THMs and HAAs were the most detected DBP groups in pool water. While chloroform was determined to be the dominant THM compound, dichloroacetic acid and trichloroacetic acid were the dominant HAA compounds. The average AOX concentrations were measured to be 304 and 746 mu g/L as Cl- in SP-A and SP-B, respectively. Although the amount of AOX from unknown chlorinated by-products in SP-A did not vary temporally, a significant increase in unknown DBP concentrations in SP-B was observed over time. AOX concentrations of chlorinated pool waters were determined to be an important parameter that can be used to estimate DBP concentrations.Article Citation - WoS: 12Citation - Scopus: 14Identifying Geogenic and Anthropogenic Aluminum Pollution on Different Spatial Distributions and Removal of Natural Waters and Soil in Çanakkale, Turkey(Amer Chemical Soc, 2023) Hızlı, Sezin; Koraoğlu, Aybike Gül; Gören, Ayşegül Yağmur; Kobya, MehmetThe Canakkale-Kirazli region (Turkey) is enriched with minerals, especially aluminum (Al), which dangerously get transported into aquatic media due to several mining and geological activities in recent years. In this study, Al and other potentially toxic metals (PTMs) including B, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Si, and Zn, in both water and soil samples, were measured for quality determination. Selected metals were also analyzed by the enrichment factor (EF), the geoaccumulation index (I-geo), the contamination factor (CF), and the pollution load index (PLI) to evaluate both water and soil pollution geogenically or anthropogenically. Also, the metals were clustered to support the pollution source with Pearson's correlation, principal component analysis (PCA), and hierarchical cluster analysis (HCA). Forty-five natural water samples and 12 soil samples were collected spatially. To perform pollution assessment, two fundamental treatment processes to remove Al pollution from the sample including the highest Al concentration (38.38 mg/L) in water were applied: (1) precipitation with pH adjustment and (2) removal with ion exchange. The pH values of water samples were changed in the range of 3-9 to test the dissolution of Al. The results demonstrated that the study area was mostly under the influence of geogenic aluminum pollution.Article Citation - WoS: 10Citation - Scopus: 12Novel Hybrid Adsorption-Electrodialysis (aded) System for Removal of Boron From Geothermal Brine(American Chemical Society, 2022) Altınbaş, Bekir Fırat; Orak, Ceren; Ökten, Hatice Eser; Yüksel, AslıA novel hybrid adsorption-electrodialysis (AdED) system to remove environmentally harmful boron from geothermal brine was designed and effective operating parameters such as pH, voltage, and flow rate were studied. A cellulose-based adsorbent was synthesized from glycidyl methacrylate (GMA) grafted cellulose and modified with a boron selective n-methyl-d-glucamine (NMDG) group and characterized with SEM-EDX, FT-IR, and TGA analyses. Batch adsorption studies revealed that cellulose-based adsorbent showed a remarkable boron removal capacity (19.29 mg/g), a wide stable operating pH range (2-10), and an adsorption process that followed the Freundlich isotherm (R2= 0.95) and pseudo-second-order kinetics (R2= 0.99). In the hybrid AdED system, the optimum operating parameters for boron removal were found to be a pH of 10, a voltage of 10 V, a flow rate of 100 mL/min, and an adsorbent dosage of 4 g/L. The presence of the adsorbent in the hybrid system increased boron removal from real geothermal brine (containing 199 ppm boron) from 7.2% to 73.3%. The results indicate that the designed AdED system performs better than bare electrodialysis for boron removal from ion-rich real geothermal brine while utilizing environmentally friendly cellulose-based adsorbent.Article Citation - WoS: 13Citation - Scopus: 13Countrywide Spatial Variation of Potentially Toxic Element Contamination in Soils of Turkey and Assessment of Population Health Risks for Nondietary Ingestion(American Chemical Society, 2022) Gören, Ayşegül Yağmur; Genişoğlu, Mesut; Kazancı, Yiğithan; Sofuoğlu, Sait CemilCountrywide surface soil concentrations of potentially toxic elements (PTEs) in Turkey were reviewed in the Web of Science database. A total of 93 papers were investigated to compose a PTE dataset for determining spatial variations and estimating exposure and health risks. Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn were selected as PTEs in surface soil. A compiled PTE concentration dataset was used to estimate chronic toxic risks (CTRs) and carcinogenic risks (CRs) according to the deterministic and probabilistic approaches. While the CTR and CR levels of age and sex groups were estimated using a deterministic approach, population risks were estimated using a probabilistic approach. CTR and CR levels in lower age groups and female sex groups were estimated to be higher than those in higher age groups and associated male sex groups. The average CTR levels of the nondietary ingestion of As-containing soil in <11 year age groups were near/just above the threshold level, while As-associated average CR levels of adults and other age groups were estimated to be in the acceptable risk range (10-6 < CR < 10-5) and low priority risk range (10-5 < CR < 10-4), respectively. As-, Cr(VI)-, and Pb-associated upper-bound CR levels of the Turkish population were simulated to be 5.14 × 10-4, 6.23 × 10-5, and 2.34 × 10-6, respectively. Health risk models show the significance of As in both chronic toxic and carcinogenic effects.