IZTECH Research Centers Collection / İYTE Araştırma Merkezleri Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/11147/2636
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Article Citation - WoS: 6Citation - Scopus: 6A Novel Land Surface Temperature Reconstruction Method and Its Application for Downscaling Surface Soil Moisture With Machine Learning(Elsevier, 2024) Güngör, Şahin; Gündüz, OrhanDownscaling of soil moisture data is important for high resolution hydrological modeling. Most downscaling studies in the literature have used spatially discontinuous land surface temperature (LST) maps as the main auxiliary parameter, which limits the creation of continuous soil moisture maps. The number of studies on soil moisture downscaling with machine learning that use gapless LST maps is limited. With this motivation, a hybrid reconstruction method has been proposed in this study to practically obtain continuous LST maps, which are then used to produce high resolution surface soil moisture (SSM) datasets. The proposed method is shown to have high mean performance with R2 and RMSE values of 0.94 and 1.84°K, respectively, for the period between 2019 and 2022. The developed reconstructed LST maps were then used to downscale original 9 km spatial resolution soil moisture datasets of SMAP L3 and SMAP L4 with Random Forest (RF) machine learning algorithm. The RF model were run with four different rainfall datasets, and the MSWEP rainfall dataset was found to produce the best results. The use of antecedent rainfall values as input variables in machine learning models has been shown to improve the performance of the models R2 0.76 to 0.93. The accuracy of the downscaled data was later evaluated for Western Anatolia Basins (WAB) in Türkiye with 31 in-situ stations. The downscaled SMAP L4 had good average statistical indicators R (0.815 ± 0.1), RMSE (0.09 ± 0.047 cm3/cm3), and ubRMSE (0.058 ± 0.025 cm3/cm3). Downscaled SMAP L3 was also validated with in-situ observations with satisfactory R (0.79 ± 0.074), RMSE (0.09 ± 0.043 cm3/cm3), and ubRMSE (0.06 ± 0.026 cm3/cm3) statistics. Furthermore, the performance of the downscaled SMAP L3 was also cross validated with SMAP + Sentinel 1 (L2) dataset between 2019 and 2022. The mean statistics of R (0.761 ± 0.11) and Root Mean Squared Difference (RMSD) (0.05 ± 0.014 cm3/cm3) between downscaled SMAP L3 and L2 data revealed that the new reconstruction method of LST used in the RF model for downscaling of soil moisture performed well to obtain high resolution soil moisture datasets. The proposed technique also overcame the difficulties associated with coastal regions where data was masked for quality considerations, by not only enhancing overall spatial resolution but also filling these data gaps and giving a complete SSM coverage. © 2024 Elsevier B.V.Article Citation - WoS: 4Citation - Scopus: 5Breakthrough Curve Analysis of Phosphorylated Hazelnut Shell Waste in Column Operation for Continuous Harvesting of Lithium From Water(Elsevier, 2024) Recepoğlu, Yaşar Kemal; Arar, Ozguer; Yuksel, AsliIn batch-scale operations, biosorption employing phosphorylated hazelnut shell waste (FHS) revealed excellent lithium removal and recovery efficiency. Scaling up and implementing packed bed column systems necessitates further design and performance optimization. Lithium biosorption via FHS was investigated utilizing a continuous-flow packed-bed column operated under various flow rates and bed heights to remove Li to ultra-low levels and recover it. The Li biosorption capacity of the FHS column was unaffected by the bed height, however, when the flow rate was increased, the capacity of the FHS column decreased. The breakthrough time, exhaustion time, and uptake capacity of the column bed increased with increasing column bed height, whereas they decreased with increasing influent flow rate. At flow rates of 0.25, 0.5, and 1.0 mL/min, bed volumes (BVs, mL solution/mL biosorbent) at the breakthrough point were found to be 477, 369, and 347, respectively, with the required BVs for total saturation point of 941, 911, and 829, while the total capacity was calculated as 22.29, 20.07, and 17.69 mg Li/g sorbent. In the 1.0, 1.5, and 2.0 cm height columns filled with FHS, the breakthrough times were 282, 366, and 433 min, respectively, whereas the periods required for saturation were 781, 897, and 1033 min. The three conventional breakthrough models of the Thomas, Yoon-Nelson, and Modified Dose-Response (MDR) were used to properly estimate the whole breakthrough behavior of the FHS column and the characteristic model parameters. Li's extremely favorable separation utilizing FHS was evidenced by the steep S-shape of the breakthrough curves for both parameters flow rate and bed height. The reusability of FHS was demonstrated by operating the packed bed column in multi-cycle mode, with no appreciable loss in column performance.Book Part Citation - Scopus: 3High Radiogenic Granites of Western Anatolia for Egs: a Review(CRC Press, 2023) Chandrasekharam, Dornadula; Baba, Alper; Ayzit, TolgaTurkey has made remarkable progress in the hydrothermal sector by promoting both electricity generation and direct application. In terms of power generation, this country is the fourth top country in the world. Nearly 1 billion kWh of energy is being utilized to keep 150,000 homes warm in the winter. In addition, Turkey has huge amounts of uptapped energy in its high radiogenic granites in western Anatolia, spread over a cumulative area of 6,910 km2. The radioactive heat generated by these granites varies from 5 to 13 µW/m3. These granite plutons are located over a region with high heat flow values (120 mW/m2) and the Curie temperature isotherm in this region is located at a depth varying from 6 to 12 km. The heat flow values here are 50% higher than the world average. This thermal regime concurs well with the wet granite melting curve at a heat flow of 85 mW/m2. The entire thermal regime indicates a visco-elastic lower crustal layer in this region. Thus, these granites provide excellent sites for initiating Enhanced Geothermal Systems projects in Turkey. Earlier EGS projects in France and Australia gave power estimates of 79×106 kWh of electricity from 1km3 of such granite. With ongoing development in drilling technology, the classical concept of creating a fracture network is being replaced with loop technology that reduces minor seismic risks and also the cost of power. The most important additional advantage Turkey has is the high-temperature regime at shallow depth, unlike other countries where the granites are located at depths >5km. These factors cause the cost of power to fall below 6 euro cents per kWh. Besides the power and heat, the greatest advantage is the reduction in emissions and achieving UN sustainable development goals. A conservative estimate shows that these radiogenic granites of western Anatolia are capable of generating a minimum of 546×109 kWh of power. Energy from these granites can be utilized to generate freshwater using the desalination method. Earlier studies indicate that to produce 1 m3 of desalinated water, ~16 kWh of electrical energy are needed. The cost of fresh water generated using geothermal energy sources will be <1.5 euros per 1m3. Turkey can utilize the energy from granite for water and food security in the future. © 2024 selection and editorial matter, Dornadula Chandrasekharam and Alper Baba.Article Citation - WoS: 6Citation - Scopus: 8The Potential, Utilization and Development of Geothermal Energy in Türkiye(Maden Tetkik ve Arama Genel Mudurlugu-mta, 2023) Sener, Mehmet Furkan; Uzelli, Taygun; Akkus, Ibrahim; Mertoglu, Orhan; Baba, AlperGeothermal energy is a natural resource that can be utilized directly or by converting to other types of energy. Considering the diversity of the geological structure of Turkiye, the geothermal systems have developed depending on young tectonic and volcanic active rock. Western and Central Anatolia are especially rich in geothermal resources. The geothermal well with the hottest well-bottom temperature was drilled in Central Anatolia, and the well-bottom temperature was measured as 341 degrees C at a depth of 3845 meters. In 2022, Turkiye's electricity generation capacity and the total installed direct heat use reached 1663 MWe and 5113 MWt, respectively. Considering Anatolia's Curie depth and heat flux, the probable thickness of the batholith can be regarded as 10 km. For example, the total granitoid area of Western Anatolia is 4221 km2 and at least 2% of this granitoid can provide approximately 8x107 MWh of electricity by Enhanced Deep Geothermal Systems (EDGS). When all granites in Turkiye are considered, it is expected that the future capacity of Turkiye will be much higher with drilling research and development studies and the discovery of new fields. This capacity will exceed 100.000 MWt levels in the medium term, especially with the addition of EDGSs.Article Citation - WoS: 36Citation - Scopus: 40Statistical Downscaling of Grace Twsa Estimates To a 1-Km Spatial Resolution for a Local-Scale Surveillance of Flooding Potential(Elsevier, 2023) Khorrami, Behnam; Pirasteh, Saied; Ali, Shoaib; Şahin, Onur Güngör; Vaheddoost, BabakThe Gravity Recovery and Climate Experiment (GRACE) paved the way for large-scale monitoring of the hydrological extremes. However, local scale analysis is aslo challenging due to the coarse resolution of the GRACE estimates. The feasibility of the downscaled GRACE data for the flood monitoring in the Kizilirmak Basin (KB) in Turkiye is investigated in this study by integrating the GRACE and hydrological model outputs of a random forest approach. Results suggest that the TWSA, over the Asagi Kizilirmak Basin (AKB), is ascending with an annual rate of + 3.51mm/yr; while the Orta Kizilirmak Basin (OKB), Yukari Kizilirmak Basin (YKB), Delice Basin (DB), Develi Kapali Basin (DKB), and Seyfe Kapali Basin (SKB) showed descending trend respectively as -1.15mm/yr, -1.58mm/yr, -1.14mm/yr, -2.34mm/yr, and -1.31mm/yr. The hydrological status of the basin showed that in 2003, 2005, 2010-2013, and 2015-2016 periods the study area was prone to the inundation. Hence, by validating the Flood Potential Index (FPI) rates acquired from the downscaled GRACE data, it was shown that the best correlation coefficient (0.73) between FPI and streamflow (Q) is associated with the SKB. It is also concluded that the downscaled TWSA associated with the fine-resolution models depicts acceptable accuracy in determination of the flood potential at local scales.Article Citation - WoS: 5Citation - Scopus: 5Are Soil and Geology Characteristics Considered in Urban Planning? an Empirical Study in Izmir (turkiye)(MDPI, 2023) Salata, Stefano; Uzelli, TaygunIt is well acknowledged that sustainable soil management can play a crucial role in reducing the vulnerability of urban areas, but are soil characteristics properly evaluated in the decision-making process concerning urbanization? Within this work, we conducted an analysis of the land-use change trends in the city of Izmir (Turkey). We made an extended and detailed analysis of the urbanization processes between 2012 and 2018 in a geographic information system environment (Esri ArcGIS 10.8.1 and ArcGIS Pro 3.0). Then, we superimposed by spatial overlay different soil characteristics: land capability, hydraulic conductibility, soil groups, and fault lines. We discovered that although there is a joint agreement on soil and its geological importance in reducing urban vulnerabilities to flooding, urban heat islands, agricultural production, or earthquakes, there is scarce knowledge of its characteristics to inform land-use planning. This work sheds some light on how newly developed areas are planned without proper consideration of soil properties, following a fuzzy and irrational logic in their distribution. Results encourage the utilization and inclusion of soil knowledge to support the decision-making process concerning urban transformation to achieve more resilient and less vulnerable urban systems.Article Perfluoropentacene Thin Films on Au(1 1 1) Surfaces: Effect of Kinetic Energy and Vibrational Properties(Elsevier, 2022) Yavuz, Adem; Danışman, M. FatihWe studied vibrational properties and the effect of beam kinetic energy on perfluoropentacene (PFP) thin films grown by supersonic molecular beam deposition (SMBD) technique on gold surfaces. Though similar growth mechanism was observed for different beam kinetic energies, in the case of low coverage (less than 1 monolayer) films and for low deposition rates significant differences were observed in the properties of films grown by using helium and argon carrier gasses with the former case resulting in higher average grain size. For multilayer films however there were no significant differences between helium and argon grown films. Vibrational properties were investigated by using Infrared Scattering-type Scanning Nearfield Optical Microscopy (s-SNOM) on clean and m-carborane-1-thiol (M1) coated template-stripped gold (TSAu) substrates. For both substrates thick PFP films (15 nm) had similar spectra whereas there were significant differences in the spectra of thin films (1 nm) due to PFP-substrate interactions. Davydov splitting of the IR modes were observed for both 1 nm and 15 nm films indicating similar molecular arrangements in both type of films.Article Citation - WoS: 8Citation - Scopus: 8Structural Controls and Hydrogeochemical Properties of Geothermal Fields in the Varto(TÜBİTAK Scientific & Technological Research Council Turkey, 2021) Uzelli, Taygun; Sener, Mehmet Furkan; Dolek, Iskender; Baba, Alper; Sozbilir, Hasan; Dirik, Ramazan KadirVarto and the surrounding region have important geothermal fields, developing in strike-slip tectonic setting in East Anatolia, which resulted from the collision of the Arabian and Eurasian plates. The main structural elements in the area are the NE-trending sinistral and NW-trending dextral strike-slip fault segments and N-S trending extension zones. In order to determine fault-controlled geothermal circulation, it is very important to fully characterize the structural elements in these complex environments. The widely distributed volcanic rocks have fracture and crack systems that play an important role in surface infiltration, geothermal fluid, and groundwater circulation. Especially in areas where the fault segments intersect, hot springs outlets and natural resources easily come to the surface. In order to understand the flow paths of geothermal fluid along the faults in these geothermal systems, it is necessary to determine the stress state of the faults and to map the distribution of the structural elements. For this reason, we conducted a detailed study on the Varto Fault Zone, which has important geothermal fields in Eastern Anatolia. We present conceptual models of the geothermal fields in the Varto region that show favorable geothermal activity on the intersecting fault segments, fault bends, step-overs, and accompanying fracture-crack sets. As a result, we emphasize that the planes of strike-slip faults in transtensional areas are more favorable for secondary permeability and enhances the geothermal fluid circulation, and this can be supported by hydrogeochemical data.Article Citation - WoS: 4Citation - Scopus: 15Effects of Seismic Activity on Groundwater Level and Geothermal Systems in İzmir, Western Anatolia, Turkey: the Case Study From October 30, 2020 Samos Earthquake(TÜBİTAK - Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 2021) Uzelli, Taygun; Bilgiç, Esra; Öztürk, Bahadır; Baba, Alper; Sözbilir, Hasan; Tatar, OrhanThe October 30, 2020 Samos earthquake (Mw 6.6) affected the Aegean Sea and environs, caused destruction and loss of life in the city of İzmir located 70 km away from the earthquake epicenter. Before this earthquake, water resources were monitored in the areas of Bayraklı, Gülbahçe, and Seferihisar. For this purpose, 10 groundwater monitoring wells were drilled in the Bayraklı area, where groundwater level, temperature, and electrical conductivity changes were monitored at 1-h intervals in 5 wells. Besides physical parameters such as groundwater levels, temperatures and electrical conductivities, hydrogeochemical cations, and anions measured in the study area. Change in the groundwater levels was observed before, during, and after the Samos earthquake. A trend of rising groundwater level was observed two days before the mainshock, to a height of 10 cm, and the level was maintained till the end of the earthquake. The water levels returned to its original height after about 7 to 10 days of the earthquake. Moreover, electrical conductivity (EC) values were changed because of the interaction with the surrounding rocks and well walls, mixing with different waters during the earthquake shaking. The essential anomalies were observed in the geothermal fields of Gülbahçe and Seferihisar. Due to this earthquake, new geothermal springs emerged along the NE-SW trending Gülbahçe and Tuzla faults, located about 50 to 20 km from the Samos earthquake epicenter, respectively. The new geothermal waters are in Na-Cl composition and similar to other geothermal springs in the region. While the recorded water temperatures in the new geothermal springs vary from 40 to 45 °C in Seferihisar, it was measured between 35 and 40 °C in Gülbahçe. Due to these anomalies, it is found essential to monitor the effect of the earthquake on the physical and chemical characteristics of the groundwater and its usefulness in earthquake predictions.Article Citation - WoS: 4Citation - Scopus: 10Characterization of Sb Scaling and Fluids in Saline Geothermal Power Plants: a Case Study for Germencik Region (büyük Menderes Graben, Turkey)(Pergamon-Elsevier Science Ltd, 2021) Tonkul, Serhat; Baba, Alper; Demir, Mustafa M.; Regenspurg, SimonaTurkey is located on the seismically active Alpine-Himalayan belt. Although tectonic activity causes seismicity in the Anatolian plate, it also constitutes an important geothermal energy resource. Today, geothermal energy production is heavily concentrated in Turkey's Western Anatolia region. Graben systems in this region are very suitable for geothermal resources. The Buyuk Menderes Graben (BMG) is an area of complex geology with active tectonics and high geothermal potential power. Germencik (Aydin) is located in the BMG, where the geothermal waters include mainly Na-Cl-HCO3 water types. This study examined the stibnite scaling formed in the preheater system of the Germencik Geothermal Field (GGF). The formation of the stibnite scaling on the preheater system dramatically reduces the energy harvesting of the GGF. Considering the stibnite scaling in the surface equipment, the optimum reinjection temperature was determined as 95 degrees C to prevent stibnite scaling in the GGF.