Mechanical Engineering / Makina Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4129
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Article Citation - WoS: 14Citation - Scopus: 14Life Cycle Assessment of Hole Transport Free Planar-Mesoscopic Perovskite Solar Cells(American Institute of Physics, 2020) Sarıaltın, Hüseyin; Geyer, Roland; Zafer, CeylanOrgano-metal lead halide perovskite solar cells (PSCs) attract attention due to their low cost and high power conversion efficiency. Some weak points of this technology are short lifetime, instability, and expensive metal electrode deposition. Eliminating the unstable hole transport layer (HTL) and using carbon-based materials as the counter electrode would address both. In this work, we present a cradle-to-gate life cycle assessment of two HTL-free PSC designs, which use solution phase deposition to achieve mesoscopic and planar structures. Environmental impacts of producing 1 m(2) PSCs are converted to impacts per kWh electricity generation assuming 5years of operational lifetime. We find that major impacts come from fluorine doped tin oxide (FTO) glass patterning due to the electricity consumption of FTO patterning and glass cleaning processes. Even though the electricity consumption when manufacturing both PSCs is similar, their different efficiencies make the environmental impacts per kWh of electricity higher for the mesoscopic PSC than for the planar PSC. Energy payback time values of planar PSCs and mesoscopic PSCs are 0.58 and 0.74years, respectively, and these values are shorter than those of commercial first and second generation solar cells. However, the global warming potential (GWP) values of planar and mesoscopic PSCs are 75 and 94g CO2-eq/kWh, respectively, and these values are still higher than those of commercial solar cells. To reach the GWP of commercial cells, the operational lifetime would have to be 8 and 10years for planar and mesoscopic PSCs, respectively.Article Citation - WoS: 23Citation - Scopus: 26Thermal Management of Electric Vehicle Battery Cells With Homogeneous Coolant and Temperature Distribution(American Institute of Physics, 2020) Göçmen, Sinan; Güngör, Şahin; Çetkin, ErdalElectric vehicles play an integral role in eliminating pollution related to transportation, especially if the electricity is generated via renewable sources. However, storing electricity onboard requires many battery cells. If the temperature of the cells is not strictly regulated, their capacity decreases in time, and they may burn or explode due to thermal runaway. Battery thermal management systems emerged for safe operations by keeping the battery cell temperatures under limit values. However, the current solutions do not yield uniform temperature distribution for all the cells in a pack. Here, we document that constant temperature distribution can be achieved with uniform coolant distribution to the channels located between batteries. The design process of the developed battery pack begins with a design used in current packs. Later, how the shape of the distributor channel affects flow uniformity is documented. Then, the design complexity was increased to satisfy the flow uniformity condition, which is essential for temperature uniformity. The design was altered based on a constructal design methodology with an iterative exhaustive search approach. The uncovered constructal design yields a uniform coolant distribution with a maximum of 0.81% flow rate deviation along channels. The developed design is palpable and easy to manufacture relative to the tapered manifold designs. The results also document that the peak temperature difference between the cells decreases from a maximum of 12K to 0.4K. Furthermore, homogenous distribution of air is one of the limiting factors of the development of metal-air batteries. This paper also documents how air can be distributed uniformly to metal-air battery cells in a battery pack.Article Citation - WoS: 37Citation - Scopus: 38Wetting of Chemically Heterogeneous Striped Surfaces: Molecular Dynamics Simulations(American Institute of Physics, 2018) Nguyen, Chinh Thanh; Barışık, Murat; Kim, BoHungUsing molecular dynamics simulations, we thoroughly investigated the wetting behaviors of a chemically heterogeneous striped substrate patterned with two different wetting materials, face-centered cubic gold and face-centered cubic silver. We analyzed the density distributions, normal stress distributions, surface tensions, and contact angles of a water droplet placed on the substrates at different heterogeneities. We found that the density and stress profile of the water droplet near the substrate-water interface were noticeably affected by altering the gold and silver contents in the substrate. Specifically, a greater portion of gold (more wetting) or smaller portion of silver (less wetting) in the substrate composition induced higher densities and higher normal stresses in the vicinity of the substrate surface. Also, it was observed that the surface tensions at liquid-vapor interface and solid-vapor interface were not largely impacted by the change of the substrate composition while the solid-liquid surface tension decreased exponentially with increasing fraction of gold. Most importantly, we found that contact angle of a nanometer-sized water droplet resting on the chemically heterogeneous striped substrate does not show linear dependence on corresponding surface fractions like that predicted by Cassie-Baxter model at the macro-scale. Consequently, we proposed a method for successfully predicting the contact angle by including the critical effects of the substrate heterogeneity on both surface tensions and line tension at the three-phase contact line of the water droplet and the chemically striped substrate.Article Citation - WoS: 44Citation - Scopus: 47Electric Field Controlled Transport of Water in Graphene Nano-Channels(American Institute of Physics, 2017) Çelebi, Alper Tunga; Barışık, Murat; Beşkök, AliMotivated by electrowetting-based flow control in nano-systems, water transport in graphene nano-channels is investigated as a function of the applied electric field. Molecular dynamics simulations are performed for deionized water confined in graphene nano-channels subjected to opposing surface charges, creating an electric field across the channel. Water molecules respond to the electric field by reorientation of their dipoles. Oxygen and hydrogen atoms in water face the anode and cathode, respectively, and hydrogen atoms get closer to the cathode compared to the oxygen atoms near the anode. These effects create asymmetric density distributions that increase with the applied electric field. Force-driven water flows under electric fields exhibit asymmetric velocity profiles and unequal slip lengths. Apparent viscosity of water increases and the slip length decreases with increased electric field, reducing the flow rate. Increasing the electric field above a threshold value freezes water at room temperature.Article Citation - WoS: 24Citation - Scopus: 28Atomic Density Effects on Temperature Characteristics and Thermal Transport at Grain Boundaries Through a Proper Bin Size Selection(American Institute of Physics, 2016) Vo, Truongquoc; Barışık, Murat; Kim, BohungThis study focuses on the proper characterization of temperature profiles across grain boundaries (GBs) in order to calculate the correct interfacial thermal resistance (ITR) and reveal the influence of GB geometries onto thermal transport. The solid-solid interfaces resulting from the orientation difference between the (001), (011), and (111) copper surfaces were investigated. Temperature discontinuities were observed at the boundary of grains due to the phonon mismatch, phonon backscattering, and atomic forces between dissimilar structures at the GBs. We observed that the temperature decreases gradually in the GB area rather than a sharp drop at the interface. As a result, three distinct temperature gradients developed at the GB which were different than the one observed in the bulk solid. This behavior extends a couple molecular diameters into both sides of the interface where we defined a thickness at GB based on the measured temperature profiles for characterization. Results showed dependence on the selection of the bin size used to average the temperature data from the molecular dynamics system. The bin size on the order of the crystal layer spacing was found to present an accurate temperature profile through the GB. We further calculated the GB thickness of various cases by using potential energy (PE) distributions which showed agreement with direct measurements from the temperature profile and validated the proper binning. The variation of grain crystal orientation developed different molecular densities which were characterized by the average atomic surface density (ASD) definition. Our results revealed that the ASD is the primary factor affecting the structural disorders and heat transfer at the solid-solid interfaces. Using a system in which the planes are highly close-packed can enhance the probability of interactions and the degree of overlap between vibrational density of states (VDOS) of atoms forming at interfaces, leading to a reduced ITR. Thus, an accurate understanding of thermal characteristics at the GB can be formulated by selecting a proper bin size.Article Citation - WoS: 36Citation - Scopus: 39The Natural Emergence of Asymmetric Tree-Shaped Pathways for Cooling of a Non-Uniformly Heated Domain(American Institute of Physics, 2015) Çetkin, Erdal; Oliani, AlessandroHere, we show that the peak temperature on a non-uniformly heated domain can be decreased by embedding a high-conductivity insert in it. The trunk of the high-conductivity insert is in contact with a heat sink. The heat is generated non-uniformly throughout the domain or concentrated in a square spot of length scale 0.1 L0, where L0 is the length scale of the non-uniformly heated domain. Peak and average temperatures are affected by the volume fraction of the high-conductivity material and by the shape of the high-conductivity pathways. This paper uncovers how varying the shape of the symmetric and asymmetric high-conductivity trees affects the overall thermal conductance of the heat generating domain. The tree-shaped high-conductivity inserts tend to grow toward where the heat generation is concentrated in order to minimize the peak temperature, i.e., in order to minimize the resistances to the heat flow. This behaviour of high-conductivity trees is alike with the root growth of the plants and trees. They also tend to grow towards sunlight, and their roots tend to grow towards water and nutrients. This paper uncovers the similarity between biological trees and high-conductivity trees, which is that trees should grow asymmetrically when the boundary conditions are non-uniform. We show here even though all the trees have the same objectives (minimum flow resistance), their shape should not be the same because of the variation in boundary conditions. To sum up, this paper shows that there is a high-conductivity tree design corresponding to minimum peak temperature with fixed constraints and conditions. This result is in accord with the constructal law which states that there should be an optimal design for a given set of conditions and constraints, and this design should be morphed in order to ensure minimum flow resistances as conditions and constraints change.