Mechanical Engineering / Makina Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4129
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Article Citation - WoS: 171Characteristics of Brick Used as Aggregate in Historic Brick-Lime Mortars and Plasters(Elsevier Ltd., 2006) Böke, Hasan; Akkurt, Sedat; İpekoğlu, Başak; Uğurlu, ElifMortars and plasters composed of a mixture of brick powder and lime have been used since ancient times due to their hydraulic properties. In this study, raw material compositions, basic physical, mineralogical, microstructural and hydraulic properties of some historic Ottoman Bath brick-lime mortars and plasters were determined by XRD, SEM-EDS, AFM, TGA and chemical analyses. The mineralogical and chemical compositions, microstructures, morphologies and pozzolanicities of the brick powders and fragments used as aggregates in the mortars and plasters were examined to find out the relationship between hydraulic properties of the mortars and the bricks. The characteristics of bricks used in the bath domes were also determined to investigate whether the brick aggregates used in mortar and plasters were prepared from these bricks. The results indicated that the mortars and plasters were hydraulic owing to the presence of crushed brick powders that have good pozzolanicity. The brick powders bad high pozzolanicity because they contained high amounts of calcium-poor clay minerals in their raw materials that were fired at low temperatures. On the other hand, bricks used in the domes had poor pozzolanicity with different mineralogical and chemical compositions from bricks used in mortars and plasters. Based on the results of the analysis, it was thought that the bricks manufactured with high amounts of clays were consciously chosen in the preparation of hydraulic mortars and plasters. (C) 2006 Elsevier Ltd. All rights reserved.Article Citation - WoS: 300Citation - Scopus: 343The Use of Recycled Paper Processing Residues in Making Porous Brick With Reduced Thermal Conductivity(Elsevier Ltd., 2009) Sütçü, Mücahit; Akkurt, SedatProduction of porous and light-weight bricks with reduced thermal conductivity and acceptable compressive strength is accomplished. Paper processing residues were used as an additive to an earthenware brick to produce the pores. SEM-EDS, XRD, XRF and TG-DTA analysis of the paper waste and brick raw material were performed. Mixtures containing brick raw materials and the paper waste were prepared at different proportions (up to 30 wt%). The granulated powder mixtures were compressed in a hydraulic press, and the green bodies were dried before firing at 1100 °C. Dilatometric behaviours, drying and firing shrinkages were investigated as well as the loss on ignition, bulk density, apparent porosity, water absorption and thermal conductivity values of the fired samples. Their mechanical and microstructural properties were also investigated. The results obtained showed that the use of paper processing residues decreased the fired density of the bricks down to 1.28 g/cm3. Compressive strengths of the brick samples produced in this study were higher than that required by the standards. Thermal conductivity of the porous brick produced in this study (<0.4 W/m K) showed more than 50% reduction compared to local brick of the same composition (0.8 W/m K). Conversion of this product to a perforated brick may reduce its thermal conductivity to very low values. Successful preliminary tests were conducted on an industrial scale.Article Citation - WoS: 15Citation - Scopus: 17Influence of Crystallographic Orientation on Hydration of Mgo Single Crystals(Elsevier Ltd., 2009) Sütçü, Mücahit; Akkurt, Sedat; Okur, SalihThis study has been performed in order to find out the influence of crystallographic orientation on hydration of MgO single crystal substrates with (1 0 0)-, (1 1 0)-, and (1 1 1)-orientations. The samples were left in a hydration chamber with an 88% relative humidity for 18 h at room temperature. The effect of humidity on the samples was examined by scanning probe microscope (SPM) and scanning electron microscope (SEM) which showed that the degree of hydration was noticeably influenced by the crystallographic orientation. It was found that the MgO with (1 1 1)-orientation has the highest tendency to hydrate than the other orientations. Second most affected sample was (1 1 0) crystal. Loss of MgO on the surface by hydration is most severe when the crystal is oriented in (1 1 1) plane with the maximum hydrate layer thickness of 174 nm after 18 h of exposure.Article Citation - WoS: 3Citation - Scopus: 4Isothermal Corrosion Testing of Frit Furnace Refractories(Elsevier Ltd., 2009) Balıkoğlu, Fatih; Akkurt, SedatIn this paper, the corrosion behaviour of aluminosilicate type refractories in frit melts is studied in an isothermal corrosion test setup. A refractory brick of largely andalusite and sillimanite composition was compared to another refractory brick of mullite and sillimanite composition, both of which were made by different manufacturers for use in different frit furnaces. The industrial frit used for corrosion tests was a commercial product used in a wall tile glaze formulation. Corrosion tests conducted under isothermal conditions provide quantitative and reproducible data about the corrosion performance of refractories. In this study, tests were performed by partially immersing a 15 mm × 15 mm × 115 mm refractory specimen into a frit melt at temperatures between 1404 and 1504 °C. The effects of temperature, duration of exposure and the refractory brick type were investigated using a statistically designed set of experiments. The ANOVA (analysis of variance) table indicated that temperature and test duration were the most important factor effects, as expected. Increasing both temperature and exposure duration led to an increased amount of corrosion as measured by the cross-sectional area loss of the corroded refractory specimen. Postmortem microstructural analysis was also done on the specimens, with extensive amount of ZnO·Al2O3 precipitation observed along the frit-refractory interface, where crystals of mullite and alumina were also found to precipitate. Increasing the amount of exposure time and temperature produced more ZnO·Al2O3 precipitation. As identified by SEM-EDS analysis, mullite crystals were in the needle-like morphology, while alumina crystals were generally cubic. Additional experiments were conducted by rotating the specimens in the melt at 50 rpm of rotational speed. Due to the reduction of boundary layer thickness, more dissolution was observed from the rotated specimens. In all specimens, corrosion was more pronounced in the bond phase than through the large filler grains of mullite and andalusite.Article Citation - WoS: 11Citation - Scopus: 18Ann Model for Prediction of Powder Packing(Elsevier Ltd., 2007) Sütçü, Mücahit; Akkurt, SedatA multilayer feed forward backpropagation (MFFB) learning algorithm was used as an artificial neural network (ANN) tool to predict packing of fused alumina powder mixtures of three different sizes in green state. The data used in model construction were collected by mixing and pressing powders with average particle sizes of 350, 30 and 3 μm and with narrow particle size distributions. The data sets that were composed of green densities of cylindrical pellets were first randomly partitioned into two for training and testing of the ANN models. Based on the training data an ANN model of the packing efficiencies was created with low average error levels (3.36%). Testing of the model was also performed with successfully good average error levels of 3.39%.Article Citation - WoS: 59Citation - Scopus: 71Additive and Intensive Grinding Effects on the Synthesis of Cordierite(Elsevier Ltd., 2006) Yalamaç, Emre; Akkurt, SedatCordierite was mechanochemically synthesized by mixing proper amounts of kaolin, talc and Al(OH)3. Full factorial experiments were planned, conducted, and the results were analyzed by the use of statistical techniques in order to understand the effects of process variables on the amount of synthesized product. The powder products were analyzed by XRD, DTA, and SEM-EDS. As a result of the statistical analysis, temperature was found to be the most important factor. Based on XRD peak intensity measurements, the cordierite mixture was completely amorphized by grinding at 300 rpm for 60 min. Cordierite was successfully produced at temperatures as low as 1150 °C by using the mixture after intensive grinding. The combined effect of magnesium borate additive and grinding on cordierite synthesis was also studied. These factors successfully decreased the synthesis temperature down to 1000 °C.Article Citation - WoS: 36Citation - Scopus: 43Effects of Boron Addition and Intensive Grinding on Synthesis of Anorthite Ceramics(Elsevier Ltd., 2008) Kavalcı, Sedat; Yalamaç, Emre; Akkurt, SedatAnorthite ceramics were synthesized starting from mixtures prepared by using mechanochemical methods with boron oxide addition. The raw materials used in this study were Sivas Kaolin, calcined alumina/Al(OH)3 and calcite. Statistical experimental design techniques (SED) were used in order to determine and analyze the more important process variables for synthesizing anorthite ceramics. Phase characterizations of synthesized powders were performed by XRD using Cu Kα radiation. Microstructural characterization was performed by SEM. The results of screening experimental design clarified that the temperature was the most important process variable. Second most important process variable was grinding speed of starting mixture which was followed by additive amount and additive type. The effect of both additive use and grinding on anorthite synthesis helped decrease the synthesis temperature down to 900 °C. © 2007 Elsevier Ltd and Techna Group S.r.l.Article Doe and Ann Models for Powder Mixture Packing(American Ceramic Society, 2007) Akkurt, Sedat; Romagnoli, Marcello; Sütçü, MücahitDesign of experiments (DOE) and artificial neural network (ANN) techniques were used to study packing of fused alumina powders composed of three different sizes of particles. The first is the mixture design technique that produces a polynomial model of the powder-packing system. While, the ANN technique is extensively used to model complex systems in many fields. The methodological approach used is mixture design, which can be used to study the influences of two or more additives. It is a structured and organized method for determining the relationship between the components and the output of that process. The mixture design approach permits optimization of size distribution to obtain a target value of porosity. Sensitivity analysis involves the use of the developed ANN model to predict outputs (porosity) at varying levels of the input factor effects.Article Citation - WoS: 63Citation - Scopus: 77Artificial Neural Networks Applications in Building Energy Predictions and a Case Study for Tropical Climates(John Wiley and Sons Inc., 2005) Yalçıntaş, Melek; Akkurt, SedatThis study presents artificial neural network (ANN) methods in building energy use predictions. Applications of the ANN methods in energy audits and energy savings predictions due to building retrofits are emphasized. A generalized ANN model that can be applied to any building type with minor modifications would be a very useful tool for building engineers. ANN methods offer faster learning time, simplicity in analysis and adaptability to seasonal climate variations and changes in the building's energy use when compared to other statistical and simulation models. The model herein is presented for predicting chiller plant energy use in tropical climates with small seasonal and daily variations. It was successfully created based on both climatic and chiller data. The average absolute training error for the model was 9.7% while the testing error was 10.0%. This indicates that the model can successfully predict the particular chiller energy consumption in a tropical climate.Article Citation - WoS: 121Citation - Scopus: 136Quantification of Caco3-Caso3·0.5h 2o-Caso4·2h2o Mixtures by Ftir Analysis and Its Ann Model(Elsevier Ltd., 2004) Böke, Hasan; Akkurt, Sedat; Özdemir, Serhan; Göktürk, E. Hale; Caner Saltık, Emine N.A new quantitative analysis method for mixtures of calcium carbonate (CaCO3), calcium sulphite hemihydrate (CaSO 3·1/2H2O) and gypsum (CaSO 4·2H2O) by FTIR spectroscopy is developed. The method involves the FTIR analysis of powder mixtures of several compositions on KBr disc specimens. Intensities of the resulting absorbance peaks for CaCO 3, CaSO3·1/2H2O and CaSO 4·2H2O at 1453, 980, 1146 cm-1 were used as input data for an artificial neural network (ANN) model, the output being the weight percent compositions of the mixtures. The training and testing data were randomly separated from the complete original data set. Testing of the model was done with successfully low-average error levels. The utility of the model is in the potential ability to use FTIR spectrum to predict the proportions of the three substances in unknown mixtures.
