Mechanical Engineering / Makina Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4129
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Article Citation - WoS: 39Citation - Scopus: 40Mode-I Fracture Toughness of Carbon Fiber/Epoxy Composites Interleaved by Aramid Nonwoven Veils(Techno Press, 2019) Beylergil, Bertan; Tanoğlu, Metin; Aktaş, EnginIn this study, carbon fiber/epoxy (CF/EP) composites were interleaved with aramid nonwoven veils with an areal weight density of 8.5 g/m(2) to improve their Mode-I fracture toughness. The control and aramid interleaved CF/EP composite laminates were manufactured by VARTM in a [0]4 configuration. Tensile, three-point bending, compression, interlaminar shear, Charpy impact and Mode-I (DCB) fracture toughness values were determined to evaluate the effects of aramid nonwoven fabrics on the mechanical performance of the CF/EP composites. Thermomechanical behavior of the specimens was investigated by Dynamic Mechanical Analysis (DMA). The results showed that the propagation Mode-I fracture toughness values of CF/EP composites can be significantly improved (by about 72%) using aramid nonwoven fabrics. It was found that the main extrinsic toughening mechanism is aramid microfiber bridging acting behind the crack-tip. The incorporation of these nonwovens also increased interlaminar shear and Charpy impact strength by 10 and 16.5%, respectively. Moreover, it was revealed that the damping ability of the composites increased with the incorporation of aramid nonwoven fabrics in the interlaminar region of composites. On the other hand, they caused a reduction in in-plane mechanical properties due to the reduced carbon fiber volume fraction, increased thickness and void formation in the composites.Article Citation - WoS: 97Citation - Scopus: 110Effect of Polyamide-6,6 (pa 66) Nonwoven Veils on the Mechanical Performance of Carbon Fiber/Epoxy Composites(Elsevier Ltd., 2018) Beylergil, Bertan; Tanoğlu, Metin; Aktaş, EnginIn this study, carbon fiber/epoxy (CF/EP) composites were interleaved with polyamide-6,6 (PA 66) nonwoven veils at two different areal weight densities (17 and 50 gsm) to improve their delamination resistance against Mode-I loading. Mode-I fracture toughness (DCB), tensile, open hole tensile (OHT), flexural, compression, short beam shear (ILSS) and Charpy-impact tests were performed on the reference and PA 66 interleaved composite specimens. The DCB test results showed that the initiation and propagation Mode-I fracture toughness values of the composites were significantly improved by 84 and 171% using PA 66-17 gsm veils respectively, as compared to reference laminates. The use of denser PA 66-50 gsm veils in the interlaminar region led to higher improvement in fracture toughness values (349% for initiation and 718% for propagation) due to the higher amount of veil fibers involved in fiber bridging toughening mechanism. The incorporation of PA 66-50 gsm nonwoven veils also increased the ILSS and Charpy impact strength of the composites by 25 and 15%, respectively. On the other hand, the PA 66 veils reduced in-plane mechanical properties of CF/EP composites due to lower carbon fiber volume fraction and increased thickness.Article Citation - WoS: 15Citation - Scopus: 14Development of Electrically Conductive and Anisotropic Gel-Coat Systems Using Cnts(Elsevier Ltd., 2013) İnce Yardımcı, Atike; Tanoğlu, Metin; Selamet, YusufElectrical conductivity of an unsaturated thermoset polyester based gel-coat system containing 0.05 wt.% of carbon nanotubes (CNTs) was investigated. The CNTs used were synthesized by chemical vapor deposition method by methane decomposition and Raman characterization showed that they were mostly single walled and high quality. To disperse CNTs in the gel-coat resin, 3-roll milling technique was used. It was found that as the CNTs are added to gel-coat system, resistivity value decreases significantly while neat gel-coat showed a high resistivity. By the application of an AC electrical field during curing process, it was attempted to align CNTs in the gel-coat resin and an electrically anisotropic polymer was obtained. © 2012 Elsevier B.V. All rights reserved.Article Citation - WoS: 25Citation - Scopus: 25Characterization Investigations During Mechanical Alloying and Sintering of W-20 Vol% Sic Composites(Elsevier Ltd., 2010) Coşkun, Selim; Öveçoğlu, M. Lütfi; Özkal, Burak; Tanoğlu, MetinThe effect of mechanical alloying and the sintering regime on the microstructural and the physical properties of W-SiC composites were investigated. Powder mixtures of W-20 vol.% SiC were mechanically alloyed (MA'd) using a Spex mill for 3 h, 6 h and 24 h. MA'd powders were characterized by Laser Diffraction Particle Size Analyzer, SEM and XRD investigations. MA'd W-20 vol.% SiC powder composites were sintered under inert Ar and reducing H2 gas conditions at 1680 °C and 1770 °C for 1 h. The microstructural and mechanical characterizations of the sintered samples were carried out by scanning electron microscope (SEM) and X-ray diffraction (XRD) and Vickers Hardness analyses. The addition of SiC remarkably increases the hardness of the composites. Hardness is also increased with decreasing grain size and increasing amount of MA. © 2009 Elsevier B.V. All rights reserved.Article Citation - WoS: 23Citation - Scopus: 27Electric Field Effects on Cnts/Vinyl Ester Suspensions and the Resulting Electrical and Thermal Composite Properties(Elsevier Ltd., 2010) Yurdakul, Hilmi; Seyhan, Abdullah Tuğrul; Turan, Servet; Tanoğlu, Metin; Bauhofer, Wolfgang; Schulte, KarlIn this study, electrical conductivity of a vinyl ester based composite containing low content (0.05, 0.1 and 0.3wt.%) of double and multi-walled carbon nanotubes with and without amine functional groups (DWCNTs, MWCNTs, DWCNT-NH2 and MWCNT-NH2) was investigated. The composite with pristine MWCNTs was found to exhibit the highest electrical conductivity. Experiments aimed to induce an aligned conductive network with application of an alternating current (AC) electric field during cure were carried out on the resin suspensions with MWCNTs. Formation of electric anisotropy within the composite was verified. Light microscopy (LM), scanning electron (SEM) and transmission electron microscopy (TEM) were conducted to visualize dispersion state and the extent of alignment of MWCNTs within the polymer cured with and without application of the electric field. To gain a better understanding of electric field induced effects, glass transition temperature (Tg) of the composites was measured via Differential Scanning Calorimetry (DSC). It was determined that at 0.05wt.% loading rate of MWCNTs, the composites, cured with application of the AC electric field, possessed a higher Tg than the composites cured without application of the AC electric field. © 2010 Elsevier Ltd.Article Citation - WoS: 73Citation - Scopus: 92Tensile Mechanical Behavior and Fracture Toughness of Mwcnt and Dwcnt Modified Vinyl-ester/Polyester Hybrid Nanocomposites Produced by 3-Roll Milling(Elsevier Ltd., 2009) Seyhan, Abdullah Tuğrul; Tanoğlu, Metin; Schulte, KarlThis study aims to investigate the tensile mechanical behavior and fracture toughness of vinyl-ester/polyester hybrid nanocomposites containing various types of nanofillers, including multi- and double-walled carbon nanotubes with and without amine functional groups (MWCNTs, DWCNTs, MWCNT-NH2 and DWCNT-NH2). To prepare the resin suspensions, very low contents (0.05, 0.1 and 0.3 wt.%) of carbon nanotubes (CNTs) were dispersed within a specially synthesized styrene-free polyester resin, conducting 3-roll milling technique. The collected resin stuff was subsequently blended with vinyl-ester via mechanical stirring to achieve final suspensions prior to polymerization. Nanocomposites containing MWCNTs and MWCNT-NH2 were found to exhibit higher tensile strength and modulus as well as larger fracture toughness and fracture energy compared to neat hybrid polymer. However, incorporation of similar contents of DWCNTs and DWCNT-NH2 into the hybrid resin did not reflect the same improvement in the corresponding mechanical properties. Furthermore, experimentally measured elastic moduli of the nanocomposites containing DWCNTs, DWCNT-NH2, MWCNTs and MWCNT-NH2 were fitted to Halphin-Tsai model. Regardless of amine functional groups or content of carbon nanotubes, MWCNT modified nanocomposites exhibited better agreement between the predicted and the measured elastic moduli values compared to nanocomposites with DWCNTs. Furthermore, Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) were used to reveal dispersion state of the carbon nanotubes within the hybrid polymer and to examine the CNT induced failure modes that occurred under mechanical loading, respectively. Based on the experimental findings obtained, it was emphasized that the types of CNTs and presence of amine functional groups on the surface of CNTs affects substantially the chemical interactions at the interface, thus tuning the ultimate mechanical performance of the resulting nanocomposites.Article Citation - WoS: 16Citation - Scopus: 17Porous Nanocomposites Prepared From Layered Clay and Pmma [poly(methyl Methacrylate)](Elsevier Ltd., 2007) Tanoğlu, Metin; Ergün, YeldaThe aim of the present work is the preparation of PMMA based porous nanocomposites that contain clay (montmorillonite, MMT) platelets as reinforcements within the cell walls of the porous structure. To render the clay layers organophilic, MMT was surface treated by an ion exchange reaction between interlayer cations of the clay and ammonium ions of a surfactant. Clay/PMMA based porous nanocomposites were prepared by polymerization of water-in-oil emulsions with and without clay addition. The microstructure and compressive mechanical behavior of the nanocomposites were investigated. The results of mechanical tests showed that the porous systems with the addition of 1 wt.% of organoclay (OMMT) exhibited a 90% and 50% increase of collapse stress and elastic modulus values, respectively, as compared to neat porous PMMA.Article Citation - WoS: 78Citation - Scopus: 106Critical Aspects Related To Processing of Carbon Nanotube/Unsaturated Thermoset Polyester Nanocomposites(Elsevier Ltd., 2007) Seyhan, Abdullah Tuğrul; Gojny, Florian H.; Tanoğlu, Metin; Schulte, KarlCarbon nanotubes (CNTs) have outstanding mechanical, thermal and electrical properties. As a result, particular interest has been recently given in exploiting these properties by incorporating carbon nanotubes into some form of matrix. Although unsaturated polyesters with styrene have widespread use in the industrial applications, surprisingly there is no study in the literature about CNT/thermoset polyester nanocomposite systems. In the present paper, we underline some important issues and limitations during the processing of unsaturated polyester resins with different types of carbon nanotubes. In that manner, 3-roll mill and sonication techniques were comparatively evaluated to process nanocomposites made of CNTs with and without amine (NH2) functional groups and polyesters. It was found that styrene evaporation from the polyester resin system was a critical issue for nanocomposite processing. Rheological behaviour of the suspensions containing CNTs and tensile strengths of their resulting nanocomposites were characterized. CNT/polyester suspensions exhibited a shear thinning behaviour, while polyester resin blends act as a Newtonian fluid. It was also found that nanotubes with amine functional groups have better tensile strength, as compared to those with untreated CNTs. Transmission electron microscopy (TEM) was also employed to reveal the degree of dispersion of CNTs in the matrix.Article Citation - WoS: 19Citation - Scopus: 23Silicon Oxycarbide-Based Composites Produced From Pyrolysis of Polysiloxanes With Active Ti Filler(Elsevier Ltd., 2006) Akkaş, Hatice Deniz; Öveçoğlu, M. Lütfi; Tanoğlu, MetinPhenyl (PPS) and methyl (PMS) containing polysiloxanes were pyrolyzed at elevated temperatures (900-1500 °C) under argon atmosphere to investigate the phase developments within the polymers. It was found that pyrolysis of the polymers under inert atmosphere up to 1300 °C leads to amorphous silicon oxycarbide (SiOxCy) ceramics. Conversions at higher temperatures results in the transformations into the crystalline β-SiC phases. Ceramic matrix composites (CMCs) were developed based on the active filler controlled pyrolysis (AFCOP) of polysiloxanes with active Ti filler additions. CMC monoliths were prepared with 60-80 wt.% of active Ti particulates blended into polymer precursors. Green bodies of the composites were made by warm pressing under 15 MPa pressure and ceramics were obtained by pyrolysis at elevated temperatures between 900 and 1500 °C under argon atmosphere. The results showed that due to the incorporation of active Ti fillers, formation of crystalline phases such as TiC, TiSi, and TiO occured within the amorphous matrix due to the reactions between the Ti and the polymer decomposition products. The microstructural and mechanical characterization results of the composites are presented within the paper.Article Citation - WoS: 3Citation - Scopus: 3Thermostable Tensoresistors of Co Doped Gasb-Fega1.3 Eutectic Composites(Elsevier Ltd., 2008) Rahimov, R. N.; Khalilova, A. A.; Arasly, D. H.; Aliyev, M. I.; Tanoğlu, Metin; Özyüzer, LütfiThe microstructure and tensoresistive properties of GaSb-FeGa1.3 eutectic composites doped with 0.1% Co have been investigated. It was found that the Co impurity atoms mainly accumulate in the metallic inclusions. The length of the inclusions in GaSb-FeGa1.3〈Co〉 was measured to be about half of those in undoped GaSb-FeGa1.3 eutectics. The tensometric characteristics of gauges based on GaSb-FeGa1.3〈Co〉 have been found to be more thermostable than undoped samples. © 2008 Elsevier B.V. All rights reserved.
