Mechanical Engineering / Makina Mühendisliği
Permanent URI for this collectionhttps://hdl.handle.net/11147/4129
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Article Citation - WoS: 25Citation - Scopus: 26Lowering the Sintering Temperature of Solid Oxide Fuel Cell Electrolytes by Infiltration(Elsevier Ltd., 2019) Sındıraç, Can; Çakırlar, Seda; Büyükaksoy, Aligül; Akkurt, SedatA dense electrolyte with a relative density of over 95% is vital to prevent gas leakage and thus the achievement of high open circuit voltage in solid oxide fuel cells (SOFCs). The densification process of ceria based electrolyte requires high temperatures heat treatment (i.e. 1400-1500 degrees C). Thus, the minimum co-sintering temperatures of the anode-electrode bilayers are fixed at these values, resulting in coarse anode microstructures and consequently poor performance. The main purpose of this study is to densify gadolinia doped ceria (GDC), a common SOFC electrolyte, at temperatures lower than 1400 degrees C. By this aim, an approach involving the infiltration of polymeric precursors into porous electrolyte scaffolds, a method commonly used for composite SOFC electrodes, is proposed. By infiltrating polymeric precursors of GDC into porous GDC scaffolds, a reduction in the sintering temperature by at least 200 degrees C is achieved with no additives that might affect the electrical properties. Energy dispersive x-ray spectroscopy line scan analyses performed on porous GDC scaffolds infiltrated by a marker solution (polymeric FeOx precursor in this case) reveals a homogeneous infiltrated phase distribution, demonstrating the effectiveness of polymeric precursors.Article Citation - WoS: 11Citation - Scopus: 12Electrical Properties of Gadolinia Doped Ceria Electrolytes Fabricated by Infiltration Aided Sintering(Elsevier Ltd., 2019) Sındıraç, Can; Büyükaksoy, Aligül; Akkurt, SedatCommon solid oxide fuel cell (SOFC) electrolyte materials (e.g., gadolinia doped ceria - GDC) demand temperatures exceeding 1400 degrees C for densification by conventional solid state sintering. It is very desirable to reduce the densification of the SOFC electroltytes to i) avoid microstructural coarsening of the composite anode layers, which are co-sintered with the electolyte layer in the anode supported SOFC fabrication scheme and ii) reduce energy consumption during SOFC manufacturing. We have recently demostrated a novel infiltration-aided sintering route to densify GDC ceramics at 1200 degrees C. In the present work, we present the electrical properties of GDC ceramics fabricated thusly. Comparison of high density (>= 95%) samples fabricated by conventional or infiltration-aided sintering reveal that at 700 degrees C, similar total electrical conductivities are obtained, while at 300 degrees C, specific grain boundary resistivity is smaller in the latter. Bulk (grain) conductivity is higher in porous GDC ceramics (relative density <= 90%) fabricated by infiltration-aided sintering than the conventionally sintered ones with similar porosities. Finally, open circuit voltage of 0.84 V at 700 degrees C, obtained under dilute hydrogen and stagnant air conditions suggests that GDC ceramics densified by infiltration-aided sintering are suitable for use as SOFC electrolytes.Article Citation - WoS: 9Citation - Scopus: 10Microstructural Investigation of the Effect of Electrospraying Parameters on Lscf Films(Elsevier Ltd., 2020) Sındıraç, Can; Akkurt, SedatIntermediate temperature solid oxide fuel cells (IT-SOFC) require an effectively functioning cathode layer whose performance depends largely on their microstructures. Improved electrochemical performance of the cathode layer can be possible by tailoring the microstructure to ensure that both the oxygen reduction reaction (ORR) occurs fast along the triple-phase boundaries (TPB) and the diffusion pathway is short enough for fast ion diffusion through the cathode layer. Electro spray deposition (ESD) method is a low-cost deposition method which allows the optimization of microstructure by changing the spraying parameters. In this study, gadolinium doped ceria (GDC) electrolyte layer is deposited with La1-xSrxCo1-yFeyO3-? (LSCF) derived from polymeric precursor salts, symmetrically. As a solvent couple, 2-butoxyethanol and ethylene glycol are used instead of the conventional solvent couples frequently employed in the literature. The use of the new type of solvents in the precursor solution leads to promising results on modifying the microstructure of the deposited layer. The effect of electrospraying parameters on the cell performance was also studied. Promising results were obtained as measured by impedance spectroscopy when this new solvent couple was employed. © 2020 Hydrogen Energy Publications LLC