Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

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Access Right: Closed AccessInstitution Author: search.filters.institutionAuthor.Kuş, Melih

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  • Article
    Citation - WoS: 2
    Citation - Scopus: 2
    Palladium-Catalysed Regio- and Stereoselective Arylative Substitution of Gamma,delta-Epoxy Esters and Amides by Sodium Tetraaryl Borates
    (Royal Society of Chemistry, 2020) Bilgi, Yasemin; Kuş, Melih; Artok, Levent
    Palladium-catalysed reactions of gamma,delta-epoxy-alpha,beta-unsaturated esters and amides with NaBAr(4)reagents proceeded regio- and stereoselectively, producing allylic homoallyl alcohols with aryl-substituents in the allylic position for a wide range of substrates. AsPh(3)was found to be a competent ligand for the arylation reaction, whereas phosphine ligand/Lewis acidic organoboron combinations favoured the substitution reaction by oxygen nucleophiles (e.g.H2O, ROH).