Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

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  • Article
    Citation - Scopus: 7
    High-Pressure Structural Studies and Pressure-Induced Sensitisation of 3,4,5-Trinitro
    (Royal Society of Chemistry, 2023) Atceken, N.; Hemingway, J.; Bull, C.L.; Liu, X.; Michalchuk, A.A.L.; Konar, S.; Morrison, C.A.
    Herein we report the first high-pressure study of the energetic material 3,4,5-trinitro-1H-pyrazole (3,4,5-TNP) using neutron powder diffraction and single-crystal X-ray diffraction. A new high-pressure phase, termed Form II, was first identified through a substantial change in the neutron powder diffraction patterns recorded over the range 4.6-5.3 GPa, and was characterised further by compression of a single crystal to 5.3 GPa in a diamond-anvil cell using X-ray diffraction. 3,4,5-TNP was found to be sensitive to initiation under pressure, as demonstrated by its unexpected and violent decomposition at elevated pressures in successive powder diffraction experiments. Initiation coincided with the sluggish phase transition from Form I to Form II. Using a vibrational up-pumping model, its increased sensitivity under pressure can be explained by pressure-induced mode hardening. These findings have potential implications for the safe handling of 3,4,5-TNP, on the basis that shock- or pressure-loading may lead to significantly increased sensitivity to initiation. © 2023 The Royal Society of Chemistry.
  • Book Part
    Citation - Scopus: 1
    Electrocaloric Ceramics
    (Elsevier, 2023) Alkoy, S.; Okatan, M.B.; Mısırlıoğlu, I.B.; Menşur-Alkoy, E.
    Electrocaloric effect (ECE) is a coupling between thermal and electrical phenomena, specifically it is the change in the entropy of a dielectric material as a result of an electrical stimulus. Electrocaloric materials are currently being investigated as a solid state refrigeration approach for on-chip cooling applications. Among the organic and inorganic electrocaloric material choices, electrocaloric ceramics are at the forefront with their higher electrocaloric coefficients. This article gives a background on the fundamentals of electrocalorics and then discusses the general trends in the literature on the electrocaloric ceramics research. © 2023 Elsevier Inc. All rights reserved