Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Comprehensive 4E Analysis, Multi-Objective Optimization, and Feasibility Study of Five Natural Gas Liquefaction Processes With a Case Study for Iran(Elsevier Sci Ltd, 2026) Basmenj, Farhad Rahmdel; Tabriz, Zahra Hajimohammadi; Aghdasinia, Hassan; Mohammadpourfard, MousaNatural gas (NG) is increasingly vital as a cleaner energy source due to its lower carbon emissions compared to other fossil fuels. Liquefaction facilitates efficient long-distance transportation. While numerous studies address NG liquefaction's technical aspects, holistic research remains limited. This study presents a comprehensive evaluation of five conventional natural gas (NG) liquefaction processes (including SMR-Linde, SMR-APCI, C3MRLinde, DMR-APCI, and MFC-Linde) through a 4E framework: energy, exergy, exergoeconomic, and exergoenvironmental analyses. Addressing limitations in prior research, it incorporates environmental considerations and introduces production volume-independent metrics to ensure equitable comparisons. Multi-objective optimization, based on exergoeconomic and exergoenvironmental criteria, is employed to identify Pareto-optimal operating conditions. To accelerate this complex process, neural networks are utilized. The study concludes with a feasibility assessment of large-scale LNG production in Iran, offering practical insights for optimizing process selection and enhancing the economic and environmental viability of LNG technologies. Simulations show that the MFC-Linde cycle as the most efficient regarding specific energy consumption (0.2563 kWh/kgLNG), coefficient of performance (3.184), and exergy efficiency (52.32 %). It also demonstrates the lowest unit exergy cost (3.67$/GJ) and exergy unit environmental impact (5271.86mPts/GJ). Multi-objective optimization, considering both exergetic-economic and exergetic-environmental criteria, using neural networks and genetic algorithms in MATLAB identifies Pareto-optimal conditions for all processes. For the MFCLinde, as the most efficient process, optimal operating conditions in the exergetic-economic trade off scenario are: Exergy efficiency of process = 51.45% and Exergy cost rate of LNG = 82, 162.15$/h; at Pressure of NG feed = 5, 925.32kPa, Pressure drop in valve = 5, 831.99kPa, and NG side temperature in heat exchanger = -168.34 degrees C. Finally, a feasibility study for large-scale LNG (Liquefied Natural Gas) production in Iran shows promising results, with a return on investment of 32.24 %/year and a payback period of 2.34 years, indicating the project's potential success in regions with abundant NG reserves.Article Citation - WoS: 1Citation - Scopus: 1High-Performance Polyether Sulfone (PES) Membranes Modified With Sunflower Seed Shell-Derived Activated Carbon (SSAC)@zif-11 Nanoparticles for Enhanced Antibiotic Removal and Antifouling Properties(Elsevier, 2025) Alafi, Narges Mortazazad; Barzegar, Behrad; Habibi, Rezvan; Aghdasinia, Hassan; Altinkaya, Sacide Alsoy; Barzegar, B.This study investigates the impact of incorporating a novel composite filler on the antibiotic removal efficiency and protein fouling resistance of polyether sulfone (PES) membranes. The filler was synthesized from activated carbon derived from sunflower seed shells (SSAC) and modified with zeolitic imidazolate framework-11 (ZIF-11). The adsorption capacities of the composite for two model antibiotics, tetracycline (TC) and rifampicin (RP), were evaluated. Mixed matrix membranes were fabricated using the phase inversion method with varying SSAC@ZIF11 contents (0.2-1 wt%). The membrane containing 0.8 wt% SSAC@ZIF-11 exhibited improved structural and surface characteristics, including increased porosity, larger pore size, smoother morphology, and enhanced hydrophilicity, as reflected by a reduction in contact angle from 60.72 degrees to 46.45 degrees. At this optimal loading, the pure water flux increased significantly from 10.52 to 39.1 L/m2h. Moreover, the modified membrane demonstrated outstanding removal efficiencies for TC (99.12 %) and RP (89.9 %), alongside excellent antifouling performance, as indicated by a flux recovery ratio increase from 42.85 % to 99.74 %. These results confirm the potential of SSAC@ZIF-11 as an effective nanofiller for developing high-performance PES membranes in advanced water purification applications.Article Citation - WoS: 4Citation - Scopus: 5Enhanced Performance and Anti-Fouling Properties of Polyether Sulfone (pes) Membranes Modified With Pistachio Shell-Derived Activated Carbon (psac)@zif-8&zif To Remove Dye Contaminants(Elsevier, 2024) Shakeri, Neda; Barzegar, Behrad; Habibi, Rezvan; Aghdasinia, Hassan; Altinkaya, Sacide AlsoyThis study aims to improve the properties of polyether sulfone (PES) membranes by using an innovative composite filler. Pistachio shell-derived activated carbon (PSAC) was initially synthesized via chemical activation, followed by surface modification with ZIF-8 and ZIF-67. Subsequently, modified membranes with varying weight percentages of this composite were fabricated using the phase inversion method. The PSAC@ZIF-8&ZIF-67/PES membranes were characterized through FESEM, AFM, pore size, zeta potential, porosity, and water contact angle analyses. The incorporation of the composite in the membranes was confirmed through ATR-FTIR, XRD, and EDS mapping analyses. The finding indicated that adding 0.6 wt% of nanoparticles improved membrane hydrophilicity, increased surface charge, and enhanced porosity. Additionally, the mixed membranes exhibited reduced sedimentation and higher dye removal than unmodified membranes. The optimum amount of composite is determined as 0.6 wt%. At this condition, pure water flux (PWF) increased dramatically from 22.56 L/m2h to 96.26 L/m2h. The mixed matrix membrane demonstrated superior efficiency in removing malachite green (MG) (97 %) and crystal violet (CV) dyes (93 %) and achieved the highest recovery ratio of 61.9 %, indicating a more remarkable membrane ability to combat fouling. The developed membrane demonstrated enhanced hydrophilicity, dye removal efficiency, and antifouling properties, making it promising for environmental applications.Article Citation - WoS: 10Citation - Scopus: 12Bimetallic Mof@cds Nanorod Composite for Highly Efficient Piezo-Photocatalytic Co2 Methanation Under Visible Light(Elsevier Sci Ltd, 2024) Farshchi, Mahdi Ebrahimi; Asgharizadeh, Kimia; Jalili, Hadi; Nejatbakhsh, Siyamak; Azimi, Babak; Aghdasinia, Hassan; Mohammadpourfard, MousaCO2 methanation is leading progress in both dwindling the emitted greenhouse gas and taking advantage of CO2 conversion to a worthwhile fuel. Various types of catalysts have gained researchers' attention. On the other hand, those catalysts chiefly suffer from being uneconomical, owning laborious processes, and having low efficiency. Particularly in the photocatalytic process, electron-hole recombination, charge separation efficiency, and the photocorrosion are the most remarkable obstacles in the path of gaining high efficiency. To conquer the aforementioned hindrances, Cu/Zr-MOF@CdS had been designed in order to not only do elevate CH4 selectivity but also increase CO2 conversion by altering the electron transfer mechanism. Doping Cu in Zr-MOF structure restrains C-C coupling and ameliorates the viability of protonation of *CO to *HCO during methane production. CdS and Zr-MOF both grant piezoelectricity trait to the catalyst in a way that by merging it with the photocatalytic process the mechanism of process converted from type (II) scheme to Z-scheme, culminating in thwarting recombination and increase of charge separation efficiency. The photocatalytic process achieved 23.6 mu mol. g- 1. h- 1 CH4 reaction rate and 80 % CO2 conversion, hereafter applying the piezo-photocatalytic process, these two factors reached 52.2 mu mol. g- 1. h- 1 and 99 %, respectively. This work unveils the viable reaction routes along with their several quotas in piezo-photocatalytic CO2 methanation process by scrutinizing the intricate mechanisms via in-situ analyses.