Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - Scopus: 6Lithium Extraction From Geothermal Brine Using Γ-Mno2: a Case Study for Tuzla Geothermal Power Plant(Elsevier Ltd, 2024) Toprak, S.; Yılmaz, Selahattin; Öncel, Ç.; Baba, Alper; Yılmaz, S.; Demir, Mustafa Muammer; Baba, A.; Koç, G.A.; Demir, M.M.Geothermal brines contain high concentrations of ions and form a source of various valuable elements. The isolation of the elements from their water systems is a great challenge when the gradual depletion of ores in mining is considered. Attempts have been made for a long time to isolate valuable elements from aqueous mixtures prepared in the laboratory. However, those studies might not reflect the complexity of natural systems and might yield results that deviate significantly from the performance in real field systems. In this study, sorption is used to extract lithium ions from a representative field, Tuzla Geothermal Power Plant (TGPP) Turkey, using a mini-pilot reactor introduced to the reinjection well of the plant. Electrolytic manganese dioxide (γ-MnO2), a relatively inexpensive material widely used as the cathode material in lithium-ion batteries, was employed as a sorbent material for lithium. The sorption/desorption performance of the novel γ-MnO2 was investigated under various conditions. Sorption is performed at 360K and 2 bars. The maximum sorption performance was obtained at 1 h in Tuzla GPP. The desorption experiments were performed in acidic solutions. The concentration of Li+ in the desorption solution was found to be 25 mg/L on average when 10 g of γ-MnO2 was dispersed into 30 mL of the acidic aqueous solution. The first desorption solution was used consecutively for collecting more Li+ ions through the desorption of fresh brine-treated powder samples (cumulative desorption). By repeating this process four times consecutively, 230 mg/L of Li+ was obtained in the desorption solution. Moreover, the reusability of the γ-MnO2 sorbent was examined. The sorbent powder showed almost 40% performance efficiency compared to virgin powder under the conditions employed in this study. The use of electrolytic γ-MnO2 sorbent for lithium adsorption was found to be a promising process for practical use in the separation of lithium from geothermal brines. © 2024Article Citation - WoS: 2Citation - Scopus: 3Evaluation of the Source and Mechanisms of Groundwater Recharge for the Southern Sections of the Western Afar Rift Margin and Associated Rift Floor(Elsevier, 2024) Gidafie, Dereje; Nedaw, Dessie; Azagegn, Tilahun; Abebe, Bekele; Baba, AlperStudy area: Southern Sections of Western Afar rift margin and associated rift floor. Study focus: The purpose of this study is to identify the source and mechanisms of groundwater recharge based on geological, hydrochemical, and environmental isotope studies. New hydrogeological insights: The investigation illustrate that the columnar jointed basalt was extended from the plateau to the rift margin. In addition, transverse structures trending NW-SE and NE-SW connect the plateau to the rift margin and the marginal grabens to the rift floor. The hydrochemical interpretations with EC and TDS shows that the groundwater from the plateau has evolved from Ca-dominated and slightly mineralized to Na-dominated and highly mineralized to the rift floor. Isotopically, the deep groundwater systems are depleted in the entire physiography in contrast to the shallow groundwater systems. Radon measurements are higher at the outlets of the marginal grabens and between the rift margin and the rift floor, suggesting groundwater feeds the river. A comprehensive analysis of the aforementioned results suggests that the deep circulating groundwater is recharged in the plateau and escarpment and chemically altered with increasing depth and along its preferential flow path into the rift floor. Therefore, the plateau area is the main source of recharge for the western Afar rift margin and associated rift floor, due to the presence of preferential pathways, mainly the columnar jointed basalts and crossstructures.Article A Methodology Providing New Insights Into the Flow Patterns of Karst Aquifers: an Example From Sw Türkiye(Springer Heidelberg, 2024) Maramathas, Athanasios; Katsanou, Konstantina; Sagir, Cagdas; Baba, Alper; Lambrakis, NikolaosThis paper presents a new and innovative methodology for the investigation of karst systems using spring discharge. The behaviour of springs in phase space is investigated by plotting the measurements of spring discharge versus the measurements of the water level at the spring's outlet. Such a diagram reveals new features of the function of the karst system and the discharge pattern of the spring that are not captured by common research methods. The application of this method to the Azmak Spring in southwestern T & uuml;rkiye revealed the existence of five distinct discharge subsystems that operate alternately and never simultaneously. They have a specific connection between them, while the transition from one to another is not random but follows a pattern. An attempt was made to interpret these features using concepts from percolation theory.Article Citation - Scopus: 3Evaluation of Gis-Based Spatial Interpolation Methods for Groundwater Level: a Case Study of Türkiye(Tubitak Scientific & Technological Research Council Turkey, 2024) Kırçiçek, Nilüfer Tirol; Baba, Alper; Koçbay, Ayhan; Toklu, Murat MertGroundwater is a valuable and universally distributed resource on Earth. Understanding the spatial and temporal dynamics of groundwater is of utmost importance for effective management. Normally, groundwater levels are recorded at arbitrary points, but groundwater modeling requires interpolating the measured values at specific grid nodes. This study aims to dentify and evaluate the geographical variations of groundwater levels in Türkiye using three geostatistical interpolation techniques. Data from 355 groundwater wells from 1970 to 2019 were used for this purpose. In addition, an investigation of changes in annual average temperature and precipitation was conducted for two different time periods: 1985–2000 and 2001–2016. The results show an increase in the annual average temperature in Türkiye by 0.82 °C during the reference period (1985–2000). Despite regional differences in the precipitation regime, the average annual precipitation in Türkiye has not changed significantly overall. Especially in the Meriç-Ergene, Konya Closed (Konya Kapalı), and Euphrates-Tigris basins, a significant decrease in groundwater levels was observed, even though this decrease is less than 100 m in some wells. After a comprehensive analysis of all these data, possible explanations for the changes in groundwater levels were considered.Article Citation - WoS: 4Citation - Scopus: 6A Sustainable Clean Energy Source for Mitigating Co<sub>2</Sub> Emissions: Numerical Simulation of Hamit Granitoid, Central Anatolian Massif(Springer Heidelberg, 2024) Ayzit, Tolga; Singh, Mrityunjay; Chandrasekharam, Dornadula; Baba, AlperT & uuml;rkiye relies on coal-fired power plants for approximately 18 GW of annual electricity generation, with significantly higher CO2 emissions compared to geothermal power plants. On the other hand, geothermal energy resources, such as Enhanced Geothermal Systems (EGS) and hydrothermal systems, offer low CO2 emissions and baseload power, making them attractive clean energy sources. Radiogenic granitoid, with high heat generation capacity, is a potential and cleaner energy source using EGS. The Anatolian plateau hosts numerous tectonic zones with plutonic rocks containing high concentrations of radioactive elements, such as the Central Anatolian Massif. This study evaluates the power generation capacity of the Hamit granitoid (HG) and presents a thermo-hydraulic-mechanical (THM) model for a closed-loop geothermal well for harnessing heat from this granitoid. A sensitivity analysis based on fluid injection rates and wellbore length emphasizes the importance of fluid resident time for effective heat extraction. Closed-loop systems pose fewer geomechanical risks than fractured systems and can be developed through site selection, system design, and monitoring. Geothermal wellbore casing material must withstand high temperatures, corrosive environments, and should have low thermal conductivity. The HG exhibits the highest heat generation capacity among Anatolian granitoid intrusions and offers potential for sustainable energy development through EGS, thereby reducing CO2 emissions.Article Citation - WoS: 7Citation - Scopus: 8Lithium Extraction From Aqueous Systems by Λ-mno<sub>2</Sub>-deposited Pu Electrospun Mats(Amer Chemical Soc, 2023) Akgun, Berk; Baba, Alper; Demir, Mustafa M.There has been a strong increase in demand for lithium, so the extraction of lithium from natural water resources has become a remarkable remedy to reduce the harmful environmental impact of conventional lithium extraction processes. One of the most effective methods of separating lithium from natural water sources is adsorption using lithium ion sieves as adsorbents. However, the powdered nature of the adsorbents makes them challenging to process. In this study, flexible and free-standing polyurethane (PU) electrospun mats associated with lambda-MnO2 particles were fabricated to extract lithium from aqueous systems. Bead-free and smooth nanofibers were electrospun from a volumetric mixture of DMF:THF (1:2) at 30 wt % of PU solution. lambda-MnO2 powder was deposited on the electrospun mat by vacuum-assisted deposition. The lithium extraction performance of the mats was found to be 21% using single-layer filtration and increased to 77% with multistage filtration. Moreover, using the optimized conditions, lithium extraction achieved up to 14% in a spiked brine sample taken from Lake Tuz (Central Anatolia, Turkey), where the Mg2+/Li+ ratio is higher than 85.Article Citation - Scopus: 3A Brief Overview on Geothermal Scaling(General Directorate of Mineral Research and Exploration (MTA), 2023) Isık, Tuğba; Baba, Alper; Chandrasekharam, Dornadula; Demir, Mustafa M.; Isık, Tuğba; Baba, Alper; Demir, Mustafa MuammerHot spring waters are rich in terms of minerals. Since there are dramatic changes in thermodynamic parameters in geothermal power plants, such as a decrease in temperature and pressure, severe precipitation occurs throughout the system components in an uncontrolled manner. There are three main chemistries in deposits: carbonates (mainly calcium carbonates), silicates (metal silicates), and sulphides (antimony sulphide-stibnite). Energy harvesting is remarkably reduced out of the insulating nature of the deposit. Various actions need to be taken to mitigate this undesirable issue of scaling in geothermal systems. Geothermal systems are in fact quite complex, and the composition of brine and, accordingly, the chemistry of the deposit are not identical. Therefore, each system should be studied individually, and a tailor-made remedy should be developed. In this overview, the types of deposits in terms of chemistry and the actions (pH modification or antiscalant dosing) that should be taken to reduce scaling are mentioned, and potential chemistries of antiscalants are given.Article Citation - WoS: 6Citation - Scopus: 8The Potential, Utilization and Development of Geothermal Energy in Türkiye(Maden Tetkik ve Arama Genel Mudurlugu-mta, 2023) Sener, Mehmet Furkan; Uzelli, Taygun; Akkus, Ibrahim; Mertoglu, Orhan; Baba, AlperGeothermal energy is a natural resource that can be utilized directly or by converting to other types of energy. Considering the diversity of the geological structure of Turkiye, the geothermal systems have developed depending on young tectonic and volcanic active rock. Western and Central Anatolia are especially rich in geothermal resources. The geothermal well with the hottest well-bottom temperature was drilled in Central Anatolia, and the well-bottom temperature was measured as 341 degrees C at a depth of 3845 meters. In 2022, Turkiye's electricity generation capacity and the total installed direct heat use reached 1663 MWe and 5113 MWt, respectively. Considering Anatolia's Curie depth and heat flux, the probable thickness of the batholith can be regarded as 10 km. For example, the total granitoid area of Western Anatolia is 4221 km2 and at least 2% of this granitoid can provide approximately 8x107 MWh of electricity by Enhanced Deep Geothermal Systems (EDGS). When all granites in Turkiye are considered, it is expected that the future capacity of Turkiye will be much higher with drilling research and development studies and the discovery of new fields. This capacity will exceed 100.000 MWt levels in the medium term, especially with the addition of EDGSs.