Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 7Citation - Scopus: 7Investigating the Effects of Pa66 Electrospun Nanofibers Layered Within an Adhesive Composite Joint Fabricated Under Autoclave Curing(American Chemical Society, 2023) Esenoğlu, Gözde; Tanoğlu, Metin; Barışık, Murat; İplikçi, Hande; Yeke, Melisa; Nuhoğlu, Kaan; Türkdoğan, Ceren; Martin, Seçkin; Aktaş, Engin; Dehneliler, Serkan; Gürbüz, Ahmet Ayberk; İriş, Mehmet ErdemEnhancing the performance of adhesively joined composite components is crucial for various industrial applications. In this study, polyamide 66 (PA66) nanofibers produced by electrospinning were coated on unidirectional carbon/epoxy prepregs to increase the bond strength of the composites. Carbon/epoxy prepregs with/without PA66 nanofiber coating on the bonding region were fabricated using the autoclave, which is often used in the aerospace industry. The single lap shear Charpy impact energy and Mode-I fracture toughness tests were employed to examine the effects of PA66 nanofibers on the mechanical properties of the joint region. Scanning electron microscopy (SEM) was used to investigate the nanofiber morphology and fracture modes. The thermal characteristics of Polyamide 66 nanofibers were explored by using differential scanning calorimetry (DSC). We observed that the electrospun PA66 nanofiber coating on the prepreg surfaces substantially improves the joint strength. Results revealed that the single lap shear and Charpy impact strength values of the composite joint are increased by about 79 and 24%, respectively, by coating PA66 nanofibers onto the joining region. The results also showed that by coating PA66 nanofibers, the Mode-I fracture toughness value was improved by about 107% while the glass transition temperature remained constant.Article Citation - WoS: 5Citation - Scopus: 6Active Heat Transfer Enhancement by Interface-Localized Liquid Dielectrophoresis Using Interdigitated Electrodes(Elsevier, 2022) Yenigün, Onur; Barışık, MuratWe introduced an active heat transfer control between graphene and water using interdigitated electrodes (IDEs). Oppositely charged co-planer electrodes embedded on a graphene surface created a non-uniform electric field. Resulted interface localized liquid dielectrophoresis (LDEP) perpendicular to surface enhanced the water/graphene coupling and decreased interfacial thermal resistance (ITR) substantially. We correlated the theoretical calculations of average electric field strength near surface with Kapitza values measured at corresponding electrode configurations. We obtained a unified linear variation of Kapitza as a function of average electric strength independent of electrode size and charge. By increasing the electric field strength, we measured up to 96% decrease of Kapitza near electrodes. Since the IDEs generated electric field was only interface localized, it required lower electrode charges than any parallel-plate capacitor systems. We showed that ITR remains effective in heat transfer behavior for systems as big as 100nm such that interface localized electric field can at least increase the heat removal 50% by eliminating the ITR from both graphene/water interfaces of a channel system. By converting hydrophobic few-layer graphene to super-hydrophilic condition with ultra-low Kapitza, current results are important for graphene-based materials considered for the solution of the thermal management problem of current and next generation micro/nano-electronics.Article Citation - WoS: 16Citation - Scopus: 17Thermal and Hydrodynamic Behavior of Forced Convection Gaseous Slip Flow in a Kelvin Cell Metal Foam(Elsevier, 2022) Sabet, Safa; Barışık, Murat; Buonomo, Bernardo; Manca, OronzioPorous metallic foams are a key material in numerous thermal and hydraulic applications. Gas flows in such micro/nanoporous systems deviate from classical continuum descriptions due to nonequilibrium in gas dynamics, and the resulted heat and mass transport show variation by rarefaction. This study performed a wide range of pore-level analysis of convective gas flows in a Kelvin cell model at different porosities and working conditions. Rarefaction effects onto permeability and heat transfer coefficients were calculated through Darcy to Forchheimer flow regimes. Permeability increased up to 60% by increasing rarefaction while this enhancement decreased by increasing porosity. At the same time, rarefaction lessened inertial effects such that Forchheimer coefficients decreased substantially. At high flow velocities, the increase in rarefaction considerably decreased the effect of drag forces. Hence, hydrodynamic enhancement due to rarefaction was found to increase by increasing Reynolds number. On the other hand, positive influence of boundary slip and negative influence of temperature jump developing between gas and solid almost canceled each other for the studied low heat flux region of highly conductive metal foam structures. Hence, Nusselt numbers were found mostly related to Reynolds number independent from rarefaction. We described Nusselt value based on power law model as a function of Reynolds and porosity. Results and the proposed model are important to accurately predict the thermal and hydrodynamic performance of metal foams in the 80 PPI range.Article Citation - WoS: 22Citation - Scopus: 24Size Dependent Influence of Contact Line Pinning on Wetting of Nano-textured/Patterned Silica Surfaces(Royal Society of Chemistry, 2020) Özçelik, H. Gökberk; Satıroğlu, Ezgi; Barışık, MuratWetting behavior on a heterogeneous surface undergoes contact angle hysteresis as the droplet stabilized at a metastable state with a contact angle significantly different from its equilibrium value due to contact line pinning. However, there is a lack of consensus on how to calculate the influence of pinning forces. In general, the pinning effect can be characterized as (i) microscopic behavior when a droplet is pinned and the contact angle increases/decreases as the droplet volume increases/decreases and (ii) macroscopic behavior as the pinning effects decrease and ultimately, disappear with the increase of the droplet size. The current work studied both behaviors using molecular dynamics (MD) simulation with more than 300 different size water droplets on silica surfaces with three different patterns across two different wetting conditions. Results showed that the contact angle increases linearly with increasing droplet volume through the microscopic behavior, while the droplet is pinned on top of a certain number of patterns. When we normalized the droplet size with the corresponding pattern size, we observed a "wetting similarity" that linear microscopic contact angle variations over different size heterogeneities continuously line up. This shows that the pinning force remains constant and the resulting pinning effects are scalable by the size ratio between the droplet and pattern, independent of the size-scale. The slope of these microscopic linear variations decreases with an increase in the droplet size as observed through the macroscopic behavior. We further found a universal behavior in the variation of the corresponding pinning forces, independent of the wetting condition. In macroscopic behavior, pinning effects become negligible and the contact angle reaches the equilibrium value of the corresponding surface when the diameter of the free-standing droplet is approximately equal to 24 times the size of the surface structure. We found that the pinning effect is scalable with the droplet volume, not the size of the droplet base.Article Citation - WoS: 9Citation - Scopus: 13Local Heat Transfer Control Using Liquid Dielectrophoresis at Graphene/Water Interfaces(Elsevier Ltd., 2021) Yenigün, Onur; Barışık, MuratGraphene-based materials are considered for the solution of the thermal management problem of current and next generation micro/nano-electronics with high heat generation densities. However, the hydrophobic nature of few-layer graphene makes passing heat to a fluid very challenging. We introduced an active and local manipulation of heat transfer between graphene and water using an applied, non-uniform electric field. When water undergoes electric field induced orientation polarization and liquid dielectrophoresis, a substantial increase in heat transfer develops due to a decrease in interfacial thermal resistance and increase in thermal conductivity. By using two locally embedded pin and plate electrodes of different sizes, we demonstrated a two-dimensional heat transfer control between two parallel few-layer graphene slabs. We obtained local heat transfer increase up to nine times at pin electrode region with an ultra-low Kapitza resistance through the studied non-uniform electric field strength range creating highly-ordered compressed water in the experimentally measured density limits. With this technique, heat can be (i) distributed from a smaller location to a larger section and/or (ii) collected to a smaller section from a larger region. Current results are important for hot spot cooling and/or heat focusing applications. © 2020Article Citation - WoS: 12Citation - Scopus: 12Numerical Determination of Interfacial Heat Transfer Coefficient for an Aligned Dual Scale Porous Medium(Emerald Group Publishing, 2018) Sabet, Safa; Mobedi, Moghtada; Barışık, Murat; Nakayama, AkiraPurpose Fluid flow and heat transfer in a dual scale porous media is investigated to determine the interfacial convective heat transfer coefficient, numerically. The studied porous media is a periodic dual scale porous media. It consists of the square rods which are permeable in an aligned arrangement. It is aimed to observe the enhancement of heat transfer through the porous media, which is important for thermal designers, by inserting intra-pores into the square rods. A special attention is given to the roles of size and number of intra-pores on the heat transfer enhancement through the dual scale porous media. The role of intra-pores on the pressure drop of air flow through porous media is also investigated by calculation and comparison of the friction coefficient. Design/methodology/approach To calculate the interfacial convective heat transfer coefficient, the governing equations which are continuity, momentum and energy equations are solved to determine velocity, pressure and temperature fields. As the dual scale porous structure is periodic, a representative elementary volume is generated, and the governing equations are numerically solved for the selected representative volume. By using the obtained velocity, pressure and temperature fields and using volume average definition, the volume average of aforementioned parameters is calculated and upscaled. Then, the interfacial convective heat transfer coefficient and the friction coefficient is numerically determined. The interparticle porosity is changed between 0.4 and 0.75, while the intraparticle varies between 0.2 and 0.75 to explore the effect of intra-pore on heat transfer enhancement. Findings The obtained Nusselt number values are compared with corresponding mono-scale porous media, and it is found that heat transfer through a porous medium can be enhanced threefold (without the increase of pressure drop) by inserting intraparticle pores in flow direction. For the porous media with low values of interparticle porosity (i.e. = 0.4), an optimum intraparticle porosity exists for which the highest heat transfer enhancement can be achieved. This value was found around 0.3 when the interparticle porosity was 0.4. Research limitations/implications The results of the study are interesting, especially from heat transfer enhancement point of view. However, further studies are required. For instance, studies should be performed to analyze the rate of the heat transfer enhancement for different shapes and arrangements of particles and a wider range of porosity. The other important parameter influencing heat transfer enhancement is the direction of pores. In the present study, the intraparticle pores are in flow direction; hence, the enhancement rate of heat transfer for different directions of pores must also be investigated. Practical implications The application of dual scale porous media is widely faced in daily life, nature and industry. The flowing of a fluid through a fiber mat, woven fiber bundles, multifilament textile fibers, oil filters and fractured porous media are some examples for the application of the heat and fluid flow through a dual scale porous media. Heat transfer enhancement. Social implications The enhancement of heat transfer is a significant topic that gained the attention of researchers in recent years. The importance of topic increases day-by-day because of further demands for downsizing of thermal equipment and heat recovery devices. The aim of thermal designers is to enhance heat transfer rate in thermal devices and to reduce their volume (and/or weight in some applications) by using lower mechanical power for cooling. Originality/value The present study might be the first study on determination of thermal transport properties of dual scale porous media yielded interesting results such as considerable enhancement of heat transfer by using proper intraparticle channels in a porous medium.Article Citation - WoS: 26Citation - Scopus: 27Internal Surface Electric Charge Characterization of Mesoporous Silica(Nature Publishing Group, 2019) Şen, Tümcan; Barışık, MuratMesoporous silica is an emerging technology to solve problems of existing and to support projected revolutionary applications ranging from targeted drug delivery to artificial kidney. However, one of the major driving mechanisms, electric charging of internal mesoporous surfaces, has not been characterized yet. In the nanoscale confinements of mesoporous structures made of pore throats and pore voids, surface charges diverge from existing theoretical calculations and show local variation due to two occurrences. First, when the size of pore throat becomes comparable with the thickness of ionic layering forming on throats' surfaces, ionic layers from opposite surfaces overlap so that ionic concentration on the surface becomes different than Boltzmann distribution predicts, and there will no longer be an equilibrium of zero electric potential at pore throat centers. Second, when this non zero potential inside throats becomes different than the potential of pore voids, ionic diffusion from void to throat creates axial ionic variation on surfaces. For such a case, we performed a pore level analysis on mesoporous internal surface charge at various porosities and ionic conditions. Pore parameters strongly affected the average internal charge which we characterized as a function of overlap ratio and porosity, first time in literature. Using this, a phenomenological model was developed as an extension of the existing theory to include nano-effects, to predict the average mesoporous internal surface charge as a function of EDL thickness, pore size and porosity.Article Citation - WoS: 21Citation - Scopus: 24Effect of Nano-Film Thickness on Thermal Resistance at Water/Silicon Interface(Elsevier Ltd., 2019) Yenigün, Onur; Barışık, MuratParallel to the developments in micro/nano manufacturing techniques, component sizes in micro/nano electro mechanical systems have been decreasing to nanometer scales. Decrease in lengths in heat transfer direction below the heat carrier phonon length scales reduces thermal conduction in semiconductors. This study shows that such altered phonon spectrums with the decrease of size also reduce the heat transfer at the solid/liquid interfaces and can be correlated with the thermal conductivity of the slab. Using Molecular Dynamics (MD), we measured heat transfer between water and silicon of different thickness between 5 nm and 60 nm. Silicon slabs exhibit a linear temperature profile through the bulk where thermal conductivities measured based on Fourier law decreased by the decreasing slab thickness. We applied a semi-theoretical formulism on variation of conductivity by slab thickness. At the interface of these slabs and water, heat passage is disturbed due to the phonon mismatch of dissimilar materials, which is mostly considered as solid/liquid couple interface properties by the earlier literature. Resistance for phonon passage characterized as Kapitza length (L-K) is measured for different slab thicknesses at different surface wetting conditions varying between hydrophilic to hydrophobic. Increasing surface wetting decreases the L-K while at a certain wetting, decreasing the slab thickness increases the L-K. Once the L-K of different size slabs normalized by its bulk value (assumed to be the L-K of the thickest slab at the corresponding wetting), L-K variation by silicon thickness shows a universal behavior independent of surface wetting. A mathematical model describing the exponential increase of L-K by decreasing thickness was developed and validated by an earlier model. We further developed a correlation between the corresponding changes of L-K and conductivity with respective to their bulk values by analytically combining two models as (L-K/L-K-(Bulk)) = exp (3.94(k(Bulk) - k)/(k x k(Bulk))), using which L-K can be predicted from available thermal conductivities of a certain material. Results are crucial for thermal management of current and future electronics. (C) 2019 Elsevier Ltd. All rights reserved.Article Citation - WoS: 15Citation - Scopus: 16Parametrizing Nonbonded Interactions Between Silica and Water From First Principles(Elsevier, 2020) Özçelik, H. Gökberk; Sözen, Yiğit; Şahin, Hasan; Barışık, MuratSilica has been used in a vast number of micro/nano-fluidic technologies where interactions of water with silica at the molecular level play a key role. In such small systems, an understanding of mass and heat transport or surface wetting relies on accurate calculations of the water-silica interface coupling through atomic interactions. Molecular dynamics (MD) is a convenient tool for such use, but force field parameters for nonbonded interactions are required as an input, which are very limited in literature. These interaction parameters can be predicted by density functional theory, but dispersion forces are not calculated in standard models for electron correlations that additional correction models have been proposed at different levels of sophistications, and still under development. Accordingly, this work employs state of the art quantum chemistry to compute the binding energies. Force field parameters for silica/water van der Waals interactions were calculated, and later tested in MD simulations of water droplet on silica surface. While the standard dispersion corrections overestimated the binding energy, Becke-Johnson model yielded interactions parameters recovering experimentally measured wetting behavior of silica with a water contact angle of approximately 12.4 degrees on the flat and clean silica surface. Results will be useful for the current molecular modelling attempts by providing transferable parameters for simple silica/water van der Waals interactions as an alternative to existing complex surface interaction models.Article Citation - WoS: 59Citation - Scopus: 64Interfacial Thermal Resistance Between the Graphene-Coated Copper and Liquid Water(Elsevier Ltd., 2016) Pham, An T.; Barışık, Murat; Kim, BohungThe thermal coupling at water-solid interfaces is a key factor in controlling thermal resistance and the performance of nanoscale devices. This is especially important across the recently engineered nano-composite structures composed of a graphene-coated-metal surface. In this paper, a series of molecular dynamics simulations were conducted to investigate Kapitza length at the interface of liquid water and nano-composite surfaces of graphene-coated-Cu(1 1 1). We found that Kapitza length gradually increased and converged to the value measured on pure graphite surface with the increase of the number of graphene layers inserted on the Cu surface. Different than the earlier hypothesis on the "transparency of graphene," the Kapitza length at the interface of mono-layer graphene coated Cu and water was found to be 2.5 times larger than the value of bare Cu surface. This drastic change of thermal resistance with the additional of a single graphene is validated by the surface energy calculations indicating that the mono-layer graphene allows only ∼18% van der Waals energy of underneath Cu to transmit. We introduced an "overall interaction strength" value for the nano-composites based the quantitative contribution of pair interaction potentials of each material with water into the total surface energy in each case. Similar to earlier studies, results revealed that Kapitza length shows exponentially variation as a function of the estimated interaction strength of the nano-composite surfaces. The effect of Cu/graphene coupling on thermal behavior between the nano-composite with water was characterized. The Kapitza length was found to decrease significantly with increased Cu/graphene strength in the case of weak coupling, while this behavior becomes negligible with strong coupling of Cu and graphene.