Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 1Citation - Scopus: 2A Molecularly Imprinted Polymer as Solid Phase Extraction Sorbent for Ketoprofen Determination in Water and Artificial Serum Prior To Hplc(TÜBİTAK - Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 2022) Shahwan, Talal; Gürel Özyurt, Elif; Özyurt, Ömer; Ölçer, Yekta Arya; Eroğlu, Ahmet Emin; Boyacı, EzelKetoprofen (KET) is an active pharmaceutical compound that has pain relieving and antipyretic effects. Its determination in body fluids and environmental waters is important due to widespread use of the compound. In this study, a selective and reliable method has been developed for the determination of ketoprofen in water and artificial serum using molecularly imprinted polymers (MIPs) as a solid phase extraction sorbent prior to HPLC-DAD detection. The MIP was synthesized by copolymerization of methacrylic acid (MAA) and trimethylpropane trimethacrylate (TRIM) in the presence of ketoprofen as the template. For the sake of comparison, nonimprinted polymer (NIP) was also synthesized under the same experimental conditions without the addition of ketoprofen under the same experimental conditions. Critical extraction parameters such as sample pH, shaking time and sorbent amount were optimized and adjusted to 8.0, 24 h, and 10.0 mg, respectively, for a sample volume of 10.0 mL. MIP showed higher selectivity than NIP towards ketoprofen in an artificial matrix containing another pain relieving drug, ibuprofen, and a cardiovascular drug, metoprolol. The proposed method was successfully applied for the detection of ketoprofen in spiked drinking water, tap water, and artificial serum samples, and showed satisfactory results with respective recoveries of 96.8 % (± 0.8), 93.7% (± 0.6), 62.2% (± 0.6), and 69.9% (± 0.6).Article Citation - WoS: 7Citation - Scopus: 8Evaluation of Dissolution Methods in the Presence of High Chloride Content for the Determination of Germanium in Geological Matrices by Hydride Generation Atomic Absorption Spectrometry(Japan Society for Analytical Chemistry, 2001) Abbasi, Husam U.; Eroğlu, Ahmet Emin; Anwari, Mohammad A.; Volkan, MürvetThe sample dissolution is probably the most crucial step in the determination of germanium in geological and metallurgical samples due to formation of volatile germanium compounds during the course of dissolution. It has been stated that this is especially true for the samples having high sulfide and/or chloride content.Article Citation - WoS: 6Citation - Scopus: 8Growth and Uptake of Sodium and Potassium in Broad Bean (vicia Faba L.) Under Salinity Stress(Taylor and Francis Ltd., 2011) Bulut, Fatma; Akıncı, Şener; Eroğlu, Ahmet EminVicia faba L. (broad bean or faba bean), a food crop of worldwide importance, is moderately tolerant of saline conditions, such as are increasingly common in Mediterranean countries and in Turkey. Our objective was to determine the influence of two salinity levels [50 and 100 mM sodium chloride (NaCl)] and two potassium salts, potassium nitrate (KNO3) (N1 and N2) or potassium acetate (CH3COOK) (A1 and A2), on the development of seedlings of two cultivars of broad bean (cvs. Eresen 87 and Filiz 99) grown in pots of perlite under controlled greenhouse conditions. Flame photometer (FP) analysis of tissues from roots, stems, and leaves of 3-month-old seedlings showed significant differences in growth, internodal length, and potassium (K+)/sodium (Na+) ratios. The FP analyses revealed that Na+ was the ion most responsible for inhibition of growth parameters seen in both cultivars and salt treatments. K+ contents were consistently higher in cv. Filiz 99 than in cv. Eresen 87. Possible correlations between these data and the tolerance to salinity of these cultivars are discussed.Article Citation - WoS: 5Citation - Scopus: 7Hydrogeochemistry and Environmental Properties of Geothermal Fields. Case Study: Balçova, Izmir-Turkey(Taylor and Francis Ltd., 2012) Çakın, Ayça; Gökçen Akkurt, Gülden; Eroğlu, Ahmet Emin; Baba, AlperBalcova Geothermal Field hosts the largest geothermal district heating system of Turkey and a number of shallow groundwater wells that are used for irrigation of the agricultural activities. The present study aims to assess the influence of geothermal fluid on groundwater by determining the hydrogeochemical properties of the water resources. A sampling program was conducted for 10 months and samples were collected from geothermal and groundwater wells including re-injected fluid. Trace and major elements, and the types of waters were determined. The results of groundwater analysis showed that the concentrations of some toxic species, such as arsenic, boron, and fluoride, exceeded the limits of drinking water standards set by TSE, EPA, and WHO.Article Citation - WoS: 16Citation - Scopus: 19Application of Experimental Design on Determination of Aluminum Content in Saline Samples by Adsorptive Cathodic Stripping Voltammetry(TUBITAK, 2013) Yılmaz, Sinan; Öztürk, Betül; Özdemir, Durmuş; Eroğlu, Ahmet Emin; Ertaş, Fatma NilAdsorptive cathodic stripping voltammetric determination of aluminum at ng mL-1 levels in salt samples based on the metal complexation with Calcon (1-(2-hydroxynaphthylazo)-2 naphthol-4-sulfonic acid) and the subsequent adsorptive deposition onto a hanging mercury drop electrode was studied. Central composite design was used as a design method. Several chemical and instrumental parameters (pH, ligand concentration, deposition time, deposition potential, and complexing time) were involved in the experimental design. Analytical parameters such as repeatability, linearity, and accuracy were also investigated and the detection limit was found as 0.32 ng mL-1.Article Citation - WoS: 11Citation - Scopus: 15Effects of Humic Acid on Root Development and Nutrient Uptake of Vicia Faba L. (broad Bean) Seedlings Grown Under Aluminum Toxicity(Taylor and Francis Ltd., 2015) Büyükkeskin, Tamer; Akıncı, Şener; Eroğlu, Ahmet EminInteractions of humic acid with development and uptake by seedlings of Vicia faba L., (cv. Eresen 87) grown in conditions of aluminium toxicity have been investigated in pot experiments in a controlled greenhouse environment. The objective of the study was to investigate whether humic acid moderates aluminum toxicity. The seedlings were treated with solutions of aluminum chloride (AlCl3) prepared in Hoagland control nutrient solution (HO) and 50 and100 μM and humic acid + Hoagland (HA) solutions, respectively. The 50 and100 μM HA solutions increased root fresh (RFW) and dry (RDW) weights, where the RFW differed significantly from controls (HO) after statistical evaluation by NCSS (NCSS, Kaysville, Utah) with two-sample T-test range at the 5% level. The results of the current experiment suggested that humic acid had suppressed or counteracted the toxic effect of aluminum (Al3+) on both main and lateral root growth. Humic acid seems to block the effect of Al3+ on nutrient uptake, as tested by atomic absorption spectrophotometry (AAS) and flame photometery (FP). Al3+ content in the roots was significantly decreased by 219% in 50-μM HA and by 49% in 100-μM HA treatments respectively. Potassium (K+), sodium (Na+), and iron (Fe3+) were recorded as the other elements taken up in the greatest amounts among the tested nutrients, in addition to Al3+. Humic acid increased the contents of Na+, K+, manganese (Mn2+), and zinc (Zn2+) significantly in both concentrations of HA treatment compared to controls. The Fe3+ content in the roots decreased, in both treatments of HA, application by 252% and 32% respectively. The reduction in the former was significant.Article Citation - WoS: 21Citation - Scopus: 21Retention of Aqueous Ba2+ Ions by Calcite and Aragonite Over a Wide Range of Concentrations: Characterization of the Uptake Capacity, and Kinetics of Sorption and Precipitate Formation(The Geochemical Society of Japan, 2007) Tunusoğlu, Özge; Shahwan, Talal; Eroğlu, Ahmet EminThe uptake of aqueous Ba2+, ions by abiogenic calcite and aragonite was studied over a wide range of concentration; 1.0 × 101, 5.0 × 101, 1.0 × 102 5.0 × 102, 1.0 × 103, 5.0 × 104, and 1.0 × 104 mg/L. The uptake process was characterized using ICP-AES, XRPD, SEM/EDS, and FTIR techniques. Up to the initial concentration of 5.0 × 102 mg/L, the uptake of Ba2+ ions was fast and obeyed Lagergren's kinetic model. The equilibrium data were adequately described using Freundlich isotherm model. The overgrowth of BaCO3 (witherite) took place at higher concentrations, in a kinetically slow process and enhanced the uptake of Ba2+ ions. Quantitative XRPD was used to evaluate the fractions of precipitated BaCO3 on calcite and aragonite minerals and monitor their variation with time. At all the studied concentrations, aragonite showed higher removal capacity of Ba2+ and faster uptake kinetics than did calcite. The precipitated crystals appeared to predominantly possess olivary-like morphology with an average particle size of 1-2 μm. EDS was used to reveal the elemental quantities of Ba and Ca after BaCO3 formation on calcite and aragonite surfaces. FTIR spectroscopy was employed to analyze the vibrational modes in carbonate mixtures upon incorporation of Ba2+ by sorption and precipitation mechanisms.