Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Author: search.filters.author.Gokelma, MertolSubject: search.filters.subject.HPMS

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  • Article
    Citation - WoS: 1
    Effect of Mechanical Pre-Treatment on the Recovery Potential of Rare-Earth Elements and Gold From Discarded Hard Disc Drives
    (Springer, 2024) Habibzadeh, Alireza; Kucuker, Mehmet Ali; Gokelma, Mertol
    The growing demand for rare-earth elements (REEs) and their limited availability have made REEs critical with high supply risk. E-waste, particularly waste electrical and electronic equipment (WEEE), offers a valuable secondary source. This study assesses the impact of mechanical pre-treatment on the recovery of REEs and gold from discarded hard disk drives (HDDs). We compared recovery efficiencies of REEs and Au using separation techniques, particle sizing, and chemical analyses between two pre-treatment methods: shredding and manual disassembly. Shredding, common in electronic waste processing, leads to oxidation and significant loss of critical raw materials (CRMs), while manual disassembly preserves clean, and non-oxidized NdFeB magnets for magnet-to-magnet recycling. Manually disassembled HDDs were directly analyzed to determine recyclable quantities of REEs and gold. Shredded HDDs underwent sieving, density, and magnetic separation, followed by demagnetization and chemical analysis. Results indicate shredding causes a 73.9% loss of REEs and a 43.8% loss of Au compared to manual disassembly, with increased oxidation due to finer particles. These findings suggest that while shredding is adequate for recovering ferrous and aluminum fractions, manual disassembly is essential for maximizing REE recovery.
  • Article
    Citation - WoS: 6
    Citation - Scopus: 6
    Microstructural Investigation of Discarded Ndfeb Magnets After Low-Temperature Hydrogenation
    (Springer, 2024) Habibzadeh, Alireza; Kucuker, Mehmet Ali; Cakir, Oznur; Gokelma, Mertol
    Due to continuously increasing demand and limited resources of rare-earth elements (REEs), new solutions are being sought to overcome the supply risk of REEs. To mitigate the supply risk of REEs, much attention has recently been paid to recycling. Despite the more common recycling methods, including hydrometallurgical and pyrometallurgical processes, hydrogen processing of magnetic scrap (HPMS) is still in the development stage. Magnet-to-magnet recycling via hydrogenation of discarded NdFeB magnets provides a fine powder suitable for the production of new magnets from secondary sources. One of the crucial aspects of HPMS is the degree of recovery of the magnetic properties, as the yield efficiency can easily reach over 95%. The amount, morphology, and distribution of the Nd-rich phase are the key parameters to achieve the excellent performance of the magnet by isolating the matrix grain. Therefore, a better insight into the microstructure of the matrix grains and the Nd-rich phase before and after hydrogenation is essential. In this study, a low-temperature hydrogenation process in the range of room temperature to 400 degrees C was conducted as the first step to recycle NdFeB magnets from discarded hard disk drives (HDDs), and the hydrogenated powder was characterized by electron microscopy and X-ray diffraction. The results show that there are three different morphologies of the Nd-rich phase, which undergo two different transformations through oxidation and hydride formation. While at lower temperatures (below 250 degrees C) the degree of pulverization is higher and the experimental evidence of hydride formation is less clear, at higher temperatures the degree of pulverization decreases. The formation of neodymium hydride at higher temperatures prevents further oxidation of the Nd-rich phase due to its high stability.