Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 7Citation - Scopus: 7Comprehensive Thermoeconomic Study of a New Solar Thermosyphon-Assisted Multigeneration System(Elsevier, 2023) Anamaq, Rasoul Najafi; Khani, Leyla; Mohammadpourfard, Mousa; Heris, Saeed Zeinali; Gökçen Akkurt, GüldenNowadays, due to the global energy crisis, limited reservoirs of fossil fuels, and their negative environmental effects, the use of renewable energy sources and multigeneration systems have become good alternatives for conventional thermodynamic systems. One of these resources, whose technology has developed rapidly in recent years, is the use of solar energy for the simultaneous generation of various products. Therefore, in this research, a multigeneration system with several subsystems is introduced. The proposed system includes a solar energy collector to receive thermal energy, two thermal energy storage tanks, an organic Rankine cycle, and a Kalina cycle to generate electricity, a multi-effect distillation unit to produce fresh water, an electrolyzer to produce hydrogen, as well as heat recovery for hot water and hot air generation. In this multigeneration system, the cooling unit is designed with the help of a thermosyphon. The performance of the proposed system is studied from energy, exergy, environmental, and exergoeconomic viewpoints using Aspen HYSYS and EES software. The obtained results show that due to the addition of the thermosyphon unit to the refrigeration system, the exergy efficiency increases from 55.62% to 70.26%. As a result of this combination, the performance of the whole system is improved and the amount of costs are reduced. In addition, the parabolic collector system has the highest exergy destruction ratio, 39%, among the subsystems. Furthermore, the results of the exergoeconomic analysis indicate that the PEM water heater with 33.3% and the ejector with 22.7% own the highest cost destruction rates.Article Citation - WoS: 45Citation - Scopus: 31Highly Efficient Treatment of Petrochemical Spent Caustic Effluent Via Electro-Fenton Process for Cod and Toc Removal: Optimization and Experimental(Springer, 2023) Gholami, Asma; Mousavi, Seyed Borhan; Heris, Saeed Zeinali; Mohammadpourfard, MousaCaustic is commonly used in oil and gas refineries to remove CO2, H2S, organic sulfur, and acidic compounds; however, spent caustic must be treated considering the type of wastewater in refinery and petrochemical units due to their hazardous characteristics. This research aims to reduce the chemical oxygen demand (COD) and the total organic carbon (TOC) from the used caustic effluent of the olefin unit of Ilam Petrochemical Company employing the electro-Fenton method. The affecting parameters, such as H2O2 concentration, reaction time, pH, and current density on the COD and TOC removal rate, were investigated. An experimental design by response surface methodology (RSM) based on the Box–Behnken method with the considered factors was considered to study the setup’s effectiveness and optimize the conditions. The outcomes revealed that by increasing the H2O2 concentration from 11 to 18 mgL, the COD removal efficiency was enhanced from 68 to 93%. On the other hand, by increasing the reaction time after 15 min, the COD and TOC removal efficiency decreased. The same trend was observed by increasing the current density after the optimal value. The optimal conditions were acquired at pH = 4, current density = 20 mAcm2, H2O2 concentration = 18 mgL, and reaction time = 15 min. The promising results confirmed that the electro-Fenton could be an excellent treatment technique in Ilam Petrochemical Unit as a spent caustic treatment. © 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
