Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Author: search.filters.author.Kuş, MelihPublisher: search.filters.publisher.Royal Society of Chemistry

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  • Article
    Citation - WoS: 2
    Citation - Scopus: 2
    Palladium-Catalysed Regio- and Stereoselective Arylative Substitution of Gamma,delta-Epoxy Esters and Amides by Sodium Tetraaryl Borates
    (Royal Society of Chemistry, 2020) Bilgi, Yasemin; Kuş, Melih; Kuş, Melih; Artok, Levent; Artok, Levent; 04.01. Department of Chemistry; 04. Faculty of Science; 01. Izmir Institute of Technology
    Palladium-catalysed reactions of gamma,delta-epoxy-alpha,beta-unsaturated esters and amides with NaBAr(4)reagents proceeded regio- and stereoselectively, producing allylic homoallyl alcohols with aryl-substituents in the allylic position for a wide range of substrates. AsPh(3)was found to be a competent ligand for the arylation reaction, whereas phosphine ligand/Lewis acidic organoboron combinations favoured the substitution reaction by oxygen nucleophiles (e.g.H2O, ROH).
  • Article
    Citation - WoS: 15
    Citation - Scopus: 14
    Rhodium Catalysed Chemo- and Stereoselective Arylative and Alkenylative Cyclisation Reactions of Unsymmetric Diynes Containing a Terminal Alkyne Moiety With Organoboronic Acids
    (Royal Society of Chemistry, 2010) Artok, Levent; Kuş, Melih; Artok, Levent; Türkmen, Gülşah; Aksın Artok, Özge; Kuş, Melih; 04.01. Department of Chemistry; 04. Faculty of Science; 01. Izmir Institute of Technology
    Unsymmetric diynes possessing a terminal alkyne moiety reacted with organoboronic acids both chemo- and stereoselectively to afford arylated or alkenylated exocyclic dienes by catalysis from the [Rh(cod)OCH 3] 2 complex. The use of a polar protic solvent, e.g. CH 3OH is required for the success of the process under mild conditions. © 2010 The Royal Society of Chemistry.