Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article A Novel ORC-PEM Integrated System for Sustainable Hydrogen Production from Low-Grade Waste Heat in Oil Refineries(Elsevier, 2025) Nazerifard, Reza; Mohammadpourfard, Mousa; Zarghami, RezaThis study presents an integrated multi-generation system for sustainable hydrogen production by harnessing low-grade waste heat from the overhead stream of the NHT unit's stripper column in an oil refinery. The proposed system integrates an ORC with a PEM electrolyzer, forming a novel energy solution that efficiently converts waste heat into clean hydrogen through electricity generation. A detailed model of the proposed system is developed, enabling a comprehensive assessment of its performance from thermodynamic, economic, and environmental viewpoints. At the same time, key operational parameters are optimized using the RSM-BBD method to minimize the hydrogen production cost, thereby enhancing the system's economic viability and practical implementation. The results demonstrated that the system achieves a yearly hydrogen production of 304.53 tons under optimized conditions, for 2.36 $/kg. The integrated system's overall energy and exergy efficiencies are calculated at 8.62 % and 33.43 %, respectively, demonstrating its high thermodynamic performance. Additionally, the system mitigates 3047 tons of CO2 annually by displacing conventional hydrogen production methods.Article Reversibility and Entropy in Bubbling Fluidized Beds: A Recurrence-Based Analysis(Elsevier, 2026) Zarghami, Reza; Mohammadpourfard, Mousa; Akkurt, Gulden GokcenNonlinear time series analysis techniques were applied to characterize bubbling fluidization. The delay method was used to reconstruct the state space attractor and analyze the reconstructed state space. The experiments were carried out in a laboratory-scale fluidized bed, operated under ambient conditions and with various sizes of particles, settled bed heights, measurement heights, and superficial gas velocities. The reversibility of the gas-solid fluidized bed hydrodynamics was investigated using pressure fluctuations by recurrence plot analysis. The anti-diagonal lines of the recurrence plot (RP) were regarded as a measure of reversibility. It was shown that the reversibility versus gas velocity has a concave shape in the bubbling regime. The highest reversibility occurs at velocities remarkably lower than the turbulent transition velocity. In addition, reversibility increases as the size of the particles increases. The Kolmogorov entropy was also estimated to confirm the reversibility analysis in the state space domain. In addition, the average cycle frequency and wideband energy in the frequency domain were also used to clarify the results in the state domain. It was found that a minimum in average cycle frequency, wideband energy, and entropy with an increase in the velocity corresponds to the transition between macro-structures and finer structures of the fluidization system. This minimum was primarily found in the macro-structures of the bubbling fluidization system. These findings can provide a practical tool for the optimal design and operation of the fluidized bed.Article Citation - WoS: 6Citation - Scopus: 7A Comprehensive Study on Doxorubicin-Loaded Aspartic Acid-Coated Magnetic Fe<sub>3</Sub>o<sub>4< Nanoparticles: Synthesis, Characterization and in Vitro Anticancer Investigations(Elsevier, 2024) Jafari, Nahideh; Mohammadpourfard, Mousa; Hamishehkar, HamedMagnetic Fe3O4 nanoparticles (MNPs) hold significant potential across various scientific fields due to their notable properties. For biomedical applications, MNPs must be biocompatible, stable, and possess high magnetic potential. Aspartic acid (ASP) as a coating agent not only provides biocompatibility, stability, and high magnetic potential but also offers the potential for absorbing various drugs for targeted delivery due to its carboxyl and amino functional groups. So, in this study, we synthesized ASP-coated MNPs (ASP-MNPs) through a one-step co-precipitation method and loaded doxorubicin (DOX) onto these nanoparticles to create DOX-ASP-MNPs for targeted drug delivery. Characterization of the nanoparticle confirmed the crystal structure, spherical morphology, and improved size distribution of ASP-MNPs (8.53 +/- 2.56 nm) compared to uncoated MNPs (7.05 +/- 1.89 nm), as analyzed by XRD, FESEM, and TEM. FT-IR and zeta potential assessments (ZP = -6.3 mV for MNPs, ZP = -31.1 mV for ASP-MNPs) verified successful ASP binding, DOX loading, and nanoparticle stability. VSM analysis indicated a slight decrease in saturation magnetism after coating (51.1 emu/g) compared to MNPs (57.4 emu/g). In vitro release studies demonstrated a higher release rate (83 %) of DOX-ASP-MNPs at pH 5.2, indicating their suitability for cancerous cells. Cytotoxicity assays on A-549 cancer cell lines showed a dose-dependent response. DAPI staining revealed that free DOX caused more DNA damage. Cellular uptake studies indicated a time-dependent uptake of DOX-ASP-MNPs, higher at 3 h compared to 1 h, though lower than free DOX uptake due to different uptake pathways. Apoptosis assays over 72 h showed similar apoptotic rates for DOX-ASP-MNPs and free DOX. These findings suggest that ASP-MNPs possess enhanced physicochemical properties and effective drug delivery capabilities, making them a promising candidate for different biomedical applications, particularly targeted cancer therapy.Article Citation - WoS: 22Citation - Scopus: 24Design, Evaluation, and Optimization of an Integrated Proton Exchange Membrane and Double Flash Geothermal Based Organic Rankine Cycle Multi-Generation System Fed by a Biomass-Fueled Gasifier(Elsevier, 2024) Taheri, Muhammad Hadi; Seker, Utku; Akkurt, Gulden Gokcen; Mohammadpourfard, MousaThis study introduces an innovative approach by formulating and evaluating a synergistic biomass-geothermal structure, emphasizing optimized inter-component connections. The research stands out for its thorough analysis of parameter impacts on the system and variables, addressing an unexplored aspect in integrated energy systems. The multi-generation systems are the integration of a combined gasification gas turbine cycle, double flash geothermal cycle, and proton exchange membrane cycle for the generating power and hydrogen. The overall system and its subsystems are studied to explore how the performance of thermodynamics and the total cost rate are influenced by operating parameters. The best operational conditions for both subsystems and the overall system have been determined by analyzing the impact of operating parameters on the thermodynamic behavior and environmental impact through parametric studies. The findings indicate while Sabalan's current efficiency is 16.26 %, the system energy efficiency reached 24.89 % when coupled with other renewable source. To enhance the system's efficiency, a genetics algorithm was utilized to simultaneously optimize the total cost of exergy destruction and investment cost. The outcome of the multi-objective optimization revealed that the exergy efficiency of optimal point for the system is 29.8 % and a total investment cost is 6 (M$/year).Article Citation - WoS: 8Citation - Scopus: 11Design, Thermodynamic and Economic Evaluation, and Optimization of Gasoline Production From Refinery Furnaces Flue Gas(Elsevier, 2023) Nazerifard, Reza; Mohammadpourfard, Mousa; Heris, Saeed ZeinaliIn this paper, the conversion of refinery furnaces’ flue gas into gasoline through the MTG process is investigated. This approach not only reduces greenhouse gas emissions, but also produces a high-value product, providing economic incentives to adopt this technology. The proposed integrated system comprises an organic Rankine cycle, an amine-based carbon capture unit, a methanol synthesis unit, and an MTG unit. In this study, we evaluated the technical and economic aspects of this conversion process, including the thermodynamic and cost analysis, to assess its viability as a sustainable solution for mitigating CO2 emissions from refineries. Also, using response surface methodology combined with the Box-Behnken design, the proposed integrated system was optimized to minimize the gasoline production cost. The thermodynamic assessment concludes that the energy and exergy efficiencies of the overall system are 73.12% and 85.24%, respectively. The proposed system yields an annual gasoline production rate of >184 million liters. The estimated total capital investment for the proposed system is 172.16 M$, which the methanol synthesis unit with a share of 48.65% is the most expensive one. The results give a gasoline production cost of 1.58 $/kg or 4.28 $/gal for the optimized case. Also, hydrogen has the highest contribution in the production cost, so with a 20% decrease in the price of hydrogen, the production cost of gasoline decreases by 18.71%. With this rate of technological improvement, reductions in the price of hydrogen seem inevitable in not-so-distant years, which makes the proposed system of converting refinery furnaces’ flue gas into gasoline became desirable. © 2023 Elsevier LtdArticle Citation - WoS: 103Citation - Scopus: 113Preparation and Characterizations of Tio2/Zno Nanohybrid and Its Application in Photocatalytic Degradation of Tetracycline in Wastewater(Elsevier, 2023) Zeinali Heris, Saeed; Etemadi, Martin; Mousavi, Seyed Borhan; Mohammadpourfard, Mousa; Ramavandi, BahmanThe photodegradation of tetracycline antibiotics (TC) in an aqueous solution, using the TiO2 nanoparticles, ZnO microparticles, and TiO2/ZnO composite under the UV lamp in a continuous reactor, was performed. The effects of different parameters, such as the initial TC concentration, medium pH, ratio of each photocatalyst, and the flow rate were comprehensively studied. SEM, EDX, and XRD characterization techniques were employed to study the morphology and structure features of the prepared composite. The results revealed that a more significant amount of TC is not easily removed from wastewater. Furthermore, by increasing the pH of the medium to 11, the efficiency of TC degradation was increased, while the amount of removal remained stable at higher pH values. As the flow rate increased up to 190 mL/min, the removal efficiency increased; however, at higher flow rates, lower efficiency was obtained. Moreover, using multivariate analysis and response surface methodology (RSM), a model for removing TC and the effect of experimental parameters on removal efficiency was proposed. The optimal conditions using the RSM method were found to be the reduction efficiency of 78.94 % in pH = 11 (flow rate of 132 mL/min, and TiO2 concentration of 323 mg) and reduction efficiency of 75.89% in pH = 9 (flow rate of 143.19 mL/min and TiO2 concentration of 312.73 mg). © 2023 Elsevier B.V.Article Citation - WoS: 7Citation - Scopus: 7Comprehensive Thermoeconomic Study of a New Solar Thermosyphon-Assisted Multigeneration System(Elsevier, 2023) Anamaq, Rasoul Najafi; Khani, Leyla; Mohammadpourfard, Mousa; Heris, Saeed Zeinali; Gökçen Akkurt, GüldenNowadays, due to the global energy crisis, limited reservoirs of fossil fuels, and their negative environmental effects, the use of renewable energy sources and multigeneration systems have become good alternatives for conventional thermodynamic systems. One of these resources, whose technology has developed rapidly in recent years, is the use of solar energy for the simultaneous generation of various products. Therefore, in this research, a multigeneration system with several subsystems is introduced. The proposed system includes a solar energy collector to receive thermal energy, two thermal energy storage tanks, an organic Rankine cycle, and a Kalina cycle to generate electricity, a multi-effect distillation unit to produce fresh water, an electrolyzer to produce hydrogen, as well as heat recovery for hot water and hot air generation. In this multigeneration system, the cooling unit is designed with the help of a thermosyphon. The performance of the proposed system is studied from energy, exergy, environmental, and exergoeconomic viewpoints using Aspen HYSYS and EES software. The obtained results show that due to the addition of the thermosyphon unit to the refrigeration system, the exergy efficiency increases from 55.62% to 70.26%. As a result of this combination, the performance of the whole system is improved and the amount of costs are reduced. In addition, the parabolic collector system has the highest exergy destruction ratio, 39%, among the subsystems. Furthermore, the results of the exergoeconomic analysis indicate that the PEM water heater with 33.3% and the ejector with 22.7% own the highest cost destruction rates.Article Citation - WoS: 49Citation - Scopus: 51Energy, Exergy, Exergoeconomic, and Exergoenvironmental (4e) Analysis of a New Bio-Waste Driven Multigeneration System for Power, Heating, Hydrogen, and Freshwater Production: Modeling and a Case Study in Izmir(Elsevier, 2023) Tabriz, Zahra Hajimohammadi; Mohammadpourfard, Mousa; Gökçen Akkurt, Gülden; Heris, Saeed ZeinaliToday, the world is facing numerous challenges such as the increasing demand for energy, fossil fuels reduction, the growth of atmospheric pollutants, and the water crisis. In the present research, a new multigeneration system based on urban sewage bio-waste has been designed and evaluated for power, hydrogen, freshwater, and heating production. This system, which consists of biomass conversion subsystem, hydrogen production unit, Brayton cycle, atmospheric water harvesting unit, steam Rankine cycle, and organic Rankine cycles, has been evaluated from a thermodynamic point of view, and the energy, exergy, exergoeconomic, and exergoenvironmental analyses have been carried out on it. In the current study, the atmospheric water harvesting unit, as an attractive and environmentally friendly technology, is integrated with this Biomass-based multigeneration. A case study has been conducted on this system using the information collected from cigli wastewater treatment plant located In Izmir province, Turkey, and the results indicate that such a system, in addition to receiving sewage sludge from the treatment plant unit as a polluting waste, can produce added value products. The modeling results show that in the base conditions and with a feed rate of 7.52 kg/s, the total power generated by this system is 17750 kW, the hydrogen production rate is 3180 kg/h, the freshwater production rate is more than 18 l/h, and the energy and exergy efficiencies are 35.48% and 40.18%, respectively. According to the exergoeconomic and exergoenvironmental evaluations, the unit cost of total products and the unit emission of carbon dioxide are calculated as 13.05 $/GJ and 0.2327 t/MWh, respectively. Also, the results of parametric studies show that increasing the rate of Biomass improves the overall energy efficiency and production rates and also reduces the unit emission of carbon dioxide, but on the other hand, it causes a decrease in exergy efficiency and an increase in the unit cost of total products.Article Citation - WoS: 26Citation - Scopus: 25Biomass Driven Polygeneration Systems: a Review of Recent Progress and Future Prospects(Elsevier, 2023) Tabriz, Zahra Hajimohammadi; Khani, Leyla; Mohammadpourfard, Mousa; Gökçen Akkurt, GüldenBiomass is the most widely used renewable energy source which is highly appreciated due to its high availability and non-intermittent nature. Considering problems such as reduction of fossil fuels, global warming, and emission of greenhouse gases, lack of attention to the existing situation may cause irreversible damage to the future of the planet. In addition to using renewable energy sources, improving the efficiency of systems will also be helpful. Polygeneration systems play an important role in increasing efficiency and reducing pollution. So, the use of biomass in polygeneration systems seems to be a great approach for sustainable development. Recent studies on biomass-based polygeneration systems have focused on how to use biomass and integrate diverse subsystems to achieve the best performance from energy and exergy viewpoints. The present paper reviews biomass-based systems, and the parameters affecting the performance of these systems. The literature review shows that the high exergy destruction rate in the gasifiers is the most frequent problem among recent articles. In addition, despite the advantages of anaerobic digestion process, the number of studies conducted on the use of this method for biomass conversion is small. In the end, results, limitations, and future outlooks of these systems are discussed.Article Citation - WoS: 20Citation - Scopus: 18Optimization of the Integrated Orc and Carbon Capture Units Coupled To the Refinery Furnace With the Rsm-Bbd Method(Elsevier, 2022) Nazerifard, Reza; Mohammadpourfard, Mousa; Heris, Saeed ZeinaliTo recover waste heat and reduce the CO2 emissions into the atmosphere, an integrated system of organic Rankine cycle and post-combustion carbon capture unit coupled with furnaces of a refinery located in Tabriz, East Azerbaijan, Iran has been presented. To assess the performances of the proposed system, thermodynamic and economic analyses are performed. The organic Rankine cycle was optimized by selecting the suitable working fluid with optimal operating conditions among the primary considered ones through multi-objective optimization. Then, the response surface methodology combined with the Box-Behnken design was employed to evaluate the effects of decision variables and their interaction on the CO2 capture cost and attain the optimal conditions. The results indicate that the R-245fa is the best working fluids among the selected ones. According to the results, the flue gas inlet temperature into the absorber and lean loading are the terms of the model that have a significant impact on the output response. In the optimum setting of the decision variables, the CO2 capture cost equals 81.60 $/tCO2 and 81.90 $/tCO2 for ORC+CC and DCC+CC processes, respectively. Furthermore, due to the absence of a turbine in the DCC+CC system, its equivalent work is 28 % higher than the ORC+CC system. Also, the amine regeneration energy is responsible for 91.47 % and 86.15 % of the variable operating cost of the optimal ORC+CC and optimal DCC+CC, respectively.