Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Author: search.filters.author.Polat, NahitDepartment: search.filters.department.İzmir Institute of Technology

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Now showing 1 - 3 of 3
  • Article
    Selective Growth of Fapbbr3 Nanocrystals With Precisely Tailored Optical Properties for Advanced Optoelectronic Applications
    (Amer Chemical Soc, 2025) Guvenc, C. Meric; Polat, Nahit; Arica, Tugce A.; Balci, Sinan
    Understanding the evolution of semiconductor nanocrystals (NCs) during their colloidal synthesis is essential for achieving improved control over their physical and chemical properties. The fast reaction kinetics and concurrent nucleation and growth periods of lead halide perovskite NCs pose significant challenges in controlling the synthesis. Here, we present the room-temperature colloidal synthesis of FAPbBr3 NCs with physically decoupled nucleation and growth periods by using the common oleylamine and oleic acid ligand pair for lead halide perovskite NCs. Importantly, in this method, the nucleation and growth phases are entirely decoupled by halting the reaction at a metastable state, where the FAPbBr3 nuclei are formed. Subsequently, preformed FAPbBr3 nuclei are selectively grown by increasing supersaturation. This is achieved by reducing the monomer solubility through the injection of oleic acid into the solution. Notably, two-dimensional perovskite nanostructures form as intermediate products during the synthesis. Furthermore, the size of the FAPbBr3 NCs is tuned from 5.7 to 13.5 nm by controlling the injected oleic acid amount. Photoluminescence quantum yields of the FAPbBr3 perovskite NCs synthesized by using this method reached up to 95%. These findings demonstrate a robust strategy for the controlled synthesis of FAPbBr3 perovskite NCs, providing precisely tailored optical properties for advanced applications such as solar cells, photodetectors, and light-emitting diodes.
  • Article
    Citation - WoS: 2
    Citation - Scopus: 2
    Temperature-Dependent Spectral Properties of Hexagonal Boron Nitride Color Centers
    (Amer Chemical Soc, 2025) Ari, Ozan; Polat, Nahit; Firat, Volkan; Cakir, Ozgur; Ates, Serkan
    Color centers in hexagonal boron nitride (hBN) are emerging as a mature platform for single-photon sources in quantum technology applications. In this study, we investigate the temperature-dependent spectral properties of a single defect in hBN to understand the dominant dephasing mechanisms due to phonons. We observe a sharp zero-phonon line (ZPL) emission accompanied by Stokes and anti-Stokes optical phonon sidebands assisted by the Raman-active low-energy (approximate to 6.5 meV) interlayer shear mode of hBN. The shape of the spectral lines around the ZPL is measured down to 78 K, at which the line width of the ZPL is measured as 211 mu eV. Using a quadratic electron-phonon interaction, the temperature-dependent broadening and the lineshift of the ZPL are found to follow a temperature dependence of T + T 5 and T + T 3, respectively. Furthermore, the temperature-dependent line shape around the ZPL at low-temperature conditions is modeled with a linear electron-phonon coupling theory, which results in a 0 K Debye-Waller factor of the ZPL emission as 0.59. Our results provide insights into the underlying mechanisms of electron-phonon coupling in hBN, which is critical to enhance their potential for applications in quantum technologies.
  • Article
    Citation - WoS: 5
    Citation - Scopus: 5
    Light-Induced, Liquid Crystal-Templated Fabrication of Large-Area Pure Nanoporous Gold Films With High-Density Plasmonic Cavities
    (Amer Chemical Soc, 2024) Orhan, Ozan Baran; Polat, Nahit; Demir, Seren; Balci, Fadime Mert; Balci, Sinan
    Nanoporous gold (NPG) films are three-dimensional gold (Au) frameworks characterized by a uniform distribution of nanoscale irregular pores. Typically produced via a dealloying process, where the less noble silver (Ag) is selectively etched out, NPG films offer a large surface area, excellent chemical stability, remarkable catalytic activity, unique optical properties, and biocompatibility. These attributes make them invaluable for applications in catalysis, plasmonics, biosensors, and nanophotonics. However, the presence of residual Ag from the dealloying process can limit their performance in certain applications. In this study, we report a novel method for the fabrication of ultrapure, large-area NPG films (several cm2) using a light-induced and liquid crystal-templated method. A hexagonal lyotropic liquid crystal containing a strong acid and a nonionic surfactant is combined with an aqueous solution of HAuCl4, followed by the photochemical synthesis of gold nanoparticles (NPs) within the liquid crystal. After calcination of the Au NP-containing liquid crystal film at high temperature, pure NPG films are produced. We demonstrate surface-enhanced Raman spectroscopy (SERS) of Rhodamine 6G (R6G) molecules adsorbed on the NPG films and detect extremely low concentrations (below 10-6 M) of R6G. Additionally, we thoroughly investigated the formation and optical properties of the NPG films. The results reveal that the ultrapure NPG films contain high-density plasmonic nanocavities, where substantial electromagnetic fields are generated, leading to significant enhancement of optical processes at nanoscale dimensions.