Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
Browse
7 results
Search Results
Article Citation - WoS: 30Citation - Scopus: 31Esterification of Cetyl Alcohol With Palmitic Acid Over Wo3/Zr-sba-15 and Zr-Sba Catalysts(Elsevier Ltd., 2016) Mutlu, Nahide Nuran; Yılmaz, SelahattinTungsten loaded and Zr incorporated SBA-15 catalysts (WO3/Zr-SBA-15 and Zr-SBA-15) were developed for esterification of cetyl alcohol and palmitic acid. The influence of the Zr content, tungsten loading amount, calcination temperature, feed composition and catalyst amount has been studied. Higher tungsten loading decreased the acidity due to formation of WO3 crystals whereas calcination temperature enhanced the acidity by favoring the dispersion of WOx species. Activities of the catalyst changed depending on their amount of Brønsted sites and total number of acid sites. Zr-SBA-15 catalyst which had the highest amount of Brønsted acid sites gave maximum cetyl palmitate yield (63.1%). This catalyst retained its activity up to 3 reuse cycles without significant loss of activity.Article Citation - WoS: 41Citation - Scopus: 42Fructose Dehydration To 5-Hydroxymethylfurfural Over Sulfated Tio2-Sio2, Ti-Sba Zro2, Sio2, and Activated Carbon Catalysts(American Chemical Society, 2015) Kılınç, Emre; Yılmaz, SelahattinDifferent sulfated catalysts including SO4/TiO2-SiO2, SO4/Ti-SBA-15, SO4/ZrO2, SO4/AC, and SO4/SiO2 were tested in fructose dehydration to 5-hydroxymethylfurfural (HMF). Reactions were carried out in dimethyl sulfoxide (DMSO) at 110 °C. Characterization results indicated that no sulfur leaching was observed from SO4/ZrO2, SO4/TiO2-SiO2, and SO4/Ti-SBA-15 catalysts in the reaction tests. The SO4/TiO2-SiO2 catalyst had a high amount of strong acid sites and the highest amount of Bronsted sites. The highest selectivity to HMF at high conversion, that is, 89% selectivity at 77% fructose conversion was obtained over this catalyst. It preserved its activity after four times reuse.Activated carbonCarbonCatalystsDehydrationArticle Citation - WoS: 53Citation - Scopus: 60Supercritical Deposition of Pt on Sno2-Coated Al2o3 Foams: Phase Behaviour and Catalytic Performance(Elsevier Ltd., 2008) Garrido, G. Incera; Patcas, F. C.; Upper, G.; Türk, M.; Yılmaz, Selahattin; Kraushaar-Czarnetzki, B.Deposition and reduction of an organometallic platinum complex from a supercritical Pt(COD)Me2/CO2 solution was carried out to produce Pt/SnO2 catalysts supported on Al2O3 foams for CO oxidation at moderate temperatures. The phase behaviour of the complex in supercritical carbon dioxide was investigated to find the optimum pressure and temperature conditions for the deposition. For the Pt(COD)Me2/CO2 mixture, the melting point decreased with increasing pressure from 378 K at 0.1 MPa to 360 K at 25.6 MPa. Additional investigations showed that the solubility of Pt(COD)Me2 in CO2 increases from 5.9 × 10-4 mol/mol at 11.2 MPa and 313 K to 3.4 × 10-3 mol/mol at 29.6 MPa and 353 K. The supercritical deposition yielded catalysts with highly dispersed platinum nanoparticles of approx. 3 nm having a narrow size distribution and thus, a superior activity towards oxidation of carbon monoxide in comparison to a catalyst prepared by the conventional aqueous impregnation of Pt.Article Citation - WoS: 11Citation - Scopus: 13Liquid-Phase Oxidation of Carvacrol Using Zeolite-Encapsulated Metal Complexes(American Chemical Society, 2006) Güneş, Alev; Bayraktar, Oğuz; Yılmaz, SelahattinWe report here the use of zeolite-encapsulated metal (salpn) complexes as catalysts in the oxidation reaction of the natural compound carvacrol in acetonitrile with hydrogen peroxide as the oxidant. No previous studies on the oxidation of carvacrol in the presence of metal salpn complexes have been reported. By using a general flexible ligand method, Cr(III), Fe(III), Bi(III), Ni(II), and Zn(II) complexes of N,N′-bis(salicylidene)propane1,3-diamine (H2salpn) encapsulated in NaY zeolite were prepared. All catalysts were characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) analyses to confirm the complex encapsulation. The activities of all prepared catalysts for the oxidation of carvacrol and hydrogen peroxide were tested. The performances of all catalysts were compared on the basis of the leaching test results and carvacrol conversions. Thymohydroquinone and benzoquinones were observed as byproducts at high conversions of carvacrol. No product was formed in the absence of a catalyst. Fe(salpn)-NaY catalyst exhibited the highest carvacrol conversion of 27.6% with a yield of 22.0%, followed by Cr(salpn)-NaY catalyst with 23.5% carvacrol conversion and a yield of 17.6%. Other catalysts have shown relatively lower performances in terms of carvacrol conversion and leaching. The Cr(salpn)-NaY catalyst was found to be a more efficient catalyst than others on the basis of leaching and activity tests. With the selected catalyst Cr (salpn)-NaY, the effects of temperature and carvacrol/hydrogen peroxide molar ratio on carvacrol oxidation reactions were investigated. Increasing the temperature from 40 to 60 °C caused an increase in the thymoquinone yield from 6.2% to 16.0%. An increase in carvacrol/hydrogen peroxide molar ratio from 1 to 3 resulted in a decrease in the thymoquinone yield.Article Citation - WoS: 32Citation - Scopus: 35Liquid Phase Transformation of ?-Pinene Over Beta Zeolites Containing Aluminium or Boron, Titanium and Vanadium as Lattice Ions(Elsevier Ltd., 2005) Gündüz, Gönül; Dimitrova, Raina D.; Yılmaz, Selahattin; Dimitrov, LjubomirBeta zeolites with different modules (SiO2/Al2 O3) and containing B, Ti or V in lattice positions were synthesised by different methods and tested as catalysts in liquid phase transformation of α-pinene at 100 °C in a batch reactor. It was established that the hydrogen forms of Beta samples with a SiO2/Al2O3 module of about 55-66 and containing both micro- and mesopores displayed high catalytic activity in liquid phase isomerization of α-pinene. Samples with boron, titanium or vanadium, as lattice ions possess insignificant catalytic activity.Article Citation - WoS: 36Citation - Scopus: 40The Kinetics of Citral Hydrogenation Over Pd Supported on Clinoptilolite Rich Natural Zeolite(Elsevier Ltd., 2005) Yılmaz, Selahattin; Uçar, Şule; Artok, Levent; Güleç, HilalThe liquid phase hydrogenation of citral has been investigated over Pd (2.42%) supported on clinoptilolite rich natural zeolite catalyst for different reaction conditions. The zeolite support did not affect the active metal properties. This was attributed to the large size of Pd particles on the support. High selectivity (90%) to citronellal was obtained at complete conversion of citral. The catalytic activity increased with reaction temperature (80, 100, 120°C) following an Arrhenius behaviour, while selectivity remained constant for a given conversion. Selectivity to citronellal increased from 78 to 90% with increase in the amount of catalyst in the reaction solution (Citral/Pd mole ratio 293, 176 and 105). The spent catalyst regained its fresh activity and selectivity upon regeneration.Article Citation - WoS: 54Citation - Scopus: 62Sic-Particulate Aluminum Composite Foams Produced by Powder Compacts: Foaming and Compression Behavior(Springer Verlag, 2003) Elbir, Semih; Yılmaz, Selahattin; Toksoy, Ahmet Kaan; Güden, Mustafa; Hall, Ian W.The foaming behavior of SiC-particulate (8.6% by volume) aluminum composite powder compacts contained Titanium Hydride blowing agent was investigated by heating above the melting temperature (750°C) in a pre-heated furnace. Aluminum powder compacts were also prepared and foamed using similar compaction and foaming parameters in order to determine the effect of SiC-particulate addition on foaming and compression behavior. The linear expansions of the compacts at various furnace holding times were ex situ determined. Optical and scanning electron microscopy techniques were used to characterize prepared and deformed foams microstructures. The SiC-particulate addition was found to increase the linear expansion and reduce the extent of the liquid metal drainage and cell coarsening of the aluminum compacts. The composite foam samples also showed higher compressive stresses, but a more brittle behavior as compared with aluminum foams.