Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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  • Article
    Machine Learning Integrated Solvothermal Liquefaction of Lignocellulosic Biomass to Maximize Bio-Oil Yield
    (Elsevier Sci Ltd, 2025) Ocal, Bulutcem; Sildir, Hasan; Yuksel, Asli
    Accelerating consumption of limited fossil-based for economic growth and simultaneously mitigating greenhouse gas emissions create a dilemma that is waiting to be solved by researchers. In this context, solvothermal liquefaction of lignocellulosic biomass to produce bio-oil is a promising way to obtain green energy. However, maximizing bio-oil is challenging to optimize the operating parameters employing conventional techniques due to the complexity and non-linearity of the process. Lately, machine learning approaches have become powerful tools for addressing complex nonlinear problems by predicting process behavior and regulating operating parameters for optimization by learning from datasets. The current research demonstrates integrating experimental and a developed artificial neural network model to optimize solvothermal liquefaction of pinus brutia, based on temperature, water fraction, and biomass amount in maximizing bio-oil generation for the first time. The highest bio-oil yields were obtained at 31.40 %, 18.68 %, and 39.69 %, respectively, with 4 and 8 g biomass in the presence of water, ethanol, and water/ethanol mixture at 240 degrees C. Under the model conditions, the maximum biooil yield was experimentally verified at 46.20%, which was predicted at 48.8 %. Beyond providing accurate yield predictions, the approach highlights the potential of date-driven modeling to reduce experimental workload and cost while aiding parameter selection to improve efficiency. These outcomes emphasize the importance of machine learning integration into liquefaction process, providing remarkable results for future process design, optimization, and scalability. On the other hand, the study also includes characterization results (ultimate, proximate, FTIR, and GC-MS) of selected products and pinus brutia.
  • Article
    Citation - WoS: 15
    Citation - Scopus: 16
    A Machine Learning Ensemble Approach for Predicting Solar-Sensitive Hybrid Photocatalysts on Hydrogen Evolution
    (IOP Publishing, 2024) Bakır, Rezan; Orak, Ceren; Yuksel, Asli
    Hydrogen, as the lightest and most abundant element in the universe, has emerged as a pivotal player in the quest for sustainable energy solutions. Its remarkable properties, such as high energy density and zero emissions upon combustion, make it a promising candidate for addressing the pressing challenges of climate change and transitioning towards a clean and renewable energy future. In an effort to improve efficiency and reduce experimental costs, we adopted machine learning techniques in this study. Our focus turned to predictive analyses of hydrogen evolution values using three photocatalysts, namely, graphene-supported LaFeO3 (GLFO), graphene-supported LaRuO3 (GLRO), and graphene-supported BiFeO3 (GBFO), examining their correlation with varying levels of pH, catalyst amount, and H2O2 concentration. To achieve this, a diverse range of machine learning models are used, including Random Forest (RF), Decision Tree (DT), Support Vector Machine (SVM), XGBoost, Gradient Boosting, and AdaBoost-each bringing its strengths to the predictive modeling arena. An important step involved combining the most effective models-Random Forests, Gradient Boosting, and XGBoost-into an ensemble model. This collaborative approach aimed to leverage their collective strengths and improve overall predictability. The ensemble model emerged as a powerful tool for understanding photocatalytic hydrogen evolution. Standard metrics were employed to assess the performance of our ensemble prediction model, encompassing R squared, Root Mean Squared Error (RMSE), Mean Squared Error (MSE), and Mean Absolute Error (MAE). The yielded results showcase exceptional accuracy, with R squared values of 96.9%, 99.3%, and 98% for GLFO, GBFO, and GLRO, respectively. Moreover, our model demonstrates minimal error rates across all metrics, underscoring its robust predictive capabilities and highlighting its efficacy in accurately forecasting the intricate relationships between GLFO, GBFO, and GLRO values and their influencing factors.