Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Department: search.filters.department.İzmir Institute of Technology. Mechanical EngineeringSubject: search.filters.subject.FTIR

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  • Article
    Citation - WoS: 18
    Citation - Scopus: 20
    Thermal Curing Behavior of Mwcnt Modified Vinyl Ester-Polyester Resin Suspensions Prepared With 3-Roll Milling Technique
    (John Wiley and Sons Inc., 2009) Seyhan, Abdullah Tuğrul; De La Vega, Alejandra; Tanoğlu, Metin; Schulte, Karl
    This study aims to investigate the curing behavior of a vinyl ester-polyester resin suspensions containing 0.3 wt % of multiwalled carbon nanotubes with and without amine functional groups (MWCNTs and MWCNT-NH2). For this purpose, various analytical techniques, including Differential Scanning Calorimetry (DSC), Fourier infrared spectroscopy (FTIR), Raman Spectroscopy, and Thermo Gravimetric Analyzer (TGA) were conducted. The resin suspensions with carbon nanotubes (CNTs) were prepared via 3-roll milling technique. DSC measurements showed that resin suspensions containing CNTs exhibited higher heat of cure (Q), besides lower activation energy (Ea) when compared with neat resin. For the sake of simplicity of interpretation, FTIR investigations were performed on neat vinyl ester resin suspensions containing the same amount of CNTs as resin. As a result, the individual fractional conversion rates of styrene and vinyl ester were interestingly found to be altered dependent on MWCNTs and MWCNT-NH2. The findings obtained from RS measurements of the cured samples are highly proportional to those obtained from FTIR measurements. TGA measurements revealed that CNT modified nanocomposites have higher activation energy of degradation (Ed) compared with the cured polymer. The findings obtained revealed that CNTs with and without amine functional groups alter overall thermal curing response of the surrounding matrix resin, which may probably impart distinctive characteristics to mechanical behavior of the corresponding nanocomposites achieved.
  • Article
    Citation - WoS: 10
    Citation - Scopus: 14
    Chemical Characterization of Cretan Clays for the Design of Restoration Mortars
    (Springer Verlag, 2008) Budak, Meral; Maravelaki-Kalaitzaki, Pagona; Kallithrakas-Kontos, Nikolaos
    Three clays and a marly-limestone from the West of Chania, Crete, fired at temperatures ranging from 200 to 1200°C, were characterized by XRD, FTIR, EDXRF and wet chemical analyses. The aim of this study was to assess the pozzolanic and hydraulic properties of these materials for potential use as binders in the design of restoration mortars. The mineralogical composition of the clays is quartz, illite, calcite, plagioclase, kaolinite and hematite. The identification of larnite and gehlenite in the calcined marly-limestone established it as potential cementious binder. Among the clays, one with low amount of calcite and considerable kaolinite content exhibited the best pozzolanic activity upon heating at 600°C. Therefore, it can be considered as an appropriate material for restoration purposes. It is deduced that the pozzolanic activity of fired clays is greatly dependent on the firing temperature and is enhanced in clays containing low calcite and high kaolinite amounts. © 2008 Springer-Verlag.