Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 65Citation - Scopus: 67Angle Resolved Vibrational Properties of Anisotropic Transition Metal Trichalcogenide Nanosheets(Royal Society of Chemistry, 2017) Kong, Wilson; Bacaksız, Cihan; Chen, Bin; Wu, Kedi; Blei, Mark; Fan, Xi; Shen, Yuxia; Şahin, Hasan; Wright, David; Narang, Deepa S.; Tongay, SefaattinLayered transition metal trichalcogenides (TMTCs) are a new class of anisotropic two-dimensional materials that exhibit quasi-1D behavior. This property stems from their unique highly anisotropic crystal structure where vastly different material properties can be attained from different crystal directions. Here, we employ density functional theory predictions, atomic force microscopy, and angle-resolved Raman spectroscopy to investigate their fundamental vibrational properties which differ significantly from other 2D systems and to establish a method in identifying anisotropy direction of different types of TMTCs. We find that the intensity of certain Raman peaks of TiS3, ZrS3, and HfS3 have strong polarization dependence in such a way that intensity is at its maximum when the polarization direction is parallel to the anisotropic b-axis. This allows us to readily identify the Raman peaks that are representative of the vibrations along the b-axis direction. Interestingly, similar angle resolved studies on the novel TiNbS3 TMTC alloy reveal that determination of anisotropy/crystalline direction is rather difficult possibly due to loss of anisotropy by randomization distribution of quasi-1D MX6 chains by the presence of defects which are commonly found in 2D alloys and also due to the complex Raman tensor of TMTC alloys. Overall, the experimental and theoretical results establish non-destructive methods used to identify the direction of anisotropy in TMTCs and reveal their vibrational characteristics which are necessary to gain insight into potential applications that utilize direction dependent thermal response, optical polarization, and linear dichroism.Article Citation - WoS: 15Citation - Scopus: 14Development of Electrically Conductive and Anisotropic Gel-Coat Systems Using Cnts(Elsevier Ltd., 2013) İnce Yardımcı, Atike; Tanoğlu, Metin; Selamet, YusufElectrical conductivity of an unsaturated thermoset polyester based gel-coat system containing 0.05 wt.% of carbon nanotubes (CNTs) was investigated. The CNTs used were synthesized by chemical vapor deposition method by methane decomposition and Raman characterization showed that they were mostly single walled and high quality. To disperse CNTs in the gel-coat resin, 3-roll milling technique was used. It was found that as the CNTs are added to gel-coat system, resistivity value decreases significantly while neat gel-coat showed a high resistivity. By the application of an AC electrical field during curing process, it was attempted to align CNTs in the gel-coat resin and an electrically anisotropic polymer was obtained. © 2012 Elsevier B.V. All rights reserved.