Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 5Citation - Scopus: 6Active Heat Transfer Enhancement by Interface-Localized Liquid Dielectrophoresis Using Interdigitated Electrodes(Elsevier, 2022) Yenigün, Onur; Barışık, MuratWe introduced an active heat transfer control between graphene and water using interdigitated electrodes (IDEs). Oppositely charged co-planer electrodes embedded on a graphene surface created a non-uniform electric field. Resulted interface localized liquid dielectrophoresis (LDEP) perpendicular to surface enhanced the water/graphene coupling and decreased interfacial thermal resistance (ITR) substantially. We correlated the theoretical calculations of average electric field strength near surface with Kapitza values measured at corresponding electrode configurations. We obtained a unified linear variation of Kapitza as a function of average electric strength independent of electrode size and charge. By increasing the electric field strength, we measured up to 96% decrease of Kapitza near electrodes. Since the IDEs generated electric field was only interface localized, it required lower electrode charges than any parallel-plate capacitor systems. We showed that ITR remains effective in heat transfer behavior for systems as big as 100nm such that interface localized electric field can at least increase the heat removal 50% by eliminating the ITR from both graphene/water interfaces of a channel system. By converting hydrophobic few-layer graphene to super-hydrophilic condition with ultra-low Kapitza, current results are important for graphene-based materials considered for the solution of the thermal management problem of current and next generation micro/nano-electronics.Article Citation - WoS: 16Citation - Scopus: 17Thermal and Hydrodynamic Behavior of Forced Convection Gaseous Slip Flow in a Kelvin Cell Metal Foam(Elsevier, 2022) Sabet, Safa; Barışık, Murat; Buonomo, Bernardo; Manca, OronzioPorous metallic foams are a key material in numerous thermal and hydraulic applications. Gas flows in such micro/nanoporous systems deviate from classical continuum descriptions due to nonequilibrium in gas dynamics, and the resulted heat and mass transport show variation by rarefaction. This study performed a wide range of pore-level analysis of convective gas flows in a Kelvin cell model at different porosities and working conditions. Rarefaction effects onto permeability and heat transfer coefficients were calculated through Darcy to Forchheimer flow regimes. Permeability increased up to 60% by increasing rarefaction while this enhancement decreased by increasing porosity. At the same time, rarefaction lessened inertial effects such that Forchheimer coefficients decreased substantially. At high flow velocities, the increase in rarefaction considerably decreased the effect of drag forces. Hence, hydrodynamic enhancement due to rarefaction was found to increase by increasing Reynolds number. On the other hand, positive influence of boundary slip and negative influence of temperature jump developing between gas and solid almost canceled each other for the studied low heat flux region of highly conductive metal foam structures. Hence, Nusselt numbers were found mostly related to Reynolds number independent from rarefaction. We described Nusselt value based on power law model as a function of Reynolds and porosity. Results and the proposed model are important to accurately predict the thermal and hydrodynamic performance of metal foams in the 80 PPI range.Article Citation - WoS: 7Citation - Scopus: 8Size and Roughness Dependent Temperature Effects on Surface Charge of Silica Nanoparticles(Elsevier, 2021) Alan, Büşra Öykü; Barışık, MuratSilica nanoparticles (SNP) with different sizes and surface areas are used in numerous micro/nanofluidic applications, while their surface charge properties play a major role in their function. In many of these applications, SNPs also undergo temperature variation. We present that an increase in temperature yields a substantial increase in SNP surface charge depending on nanoparticle size and surface roughness, which cannot be estimated by existing theory. As a continuation of our earlier work characterizing the deviation of SNP surface charging from theoretical predictions due to curvature and EDL overlap effects, this study presents the differentiation from the theory in temperature dependence under various conditions. As we calculate surface chemistry as a function of local ionic conditions (Charge Regulation), temperature variation changed the equilibrium constants of protonation/deprotonation reactions of the SNP surface, in addition to changes occurring in relative permittivity and ionic mobilities. Results show that variation of SNP surface charge by temperature decreases by decreasing particle size and/or increasing roughness size, compare to theoretical flat plate calculations considering similar temperature-dependent properties and charge regulation on the surface. We characterized these deviations by obtaining an electrokinetic similarity between different systems of various size and roughness at various ionic conditions based on the non-dimensional groups of lambda/DP and lambda/DR. Based on these, we devised a phenomenological model as an extension to the flat plate theory to successfully predict the surface charge of SNPs as a function of the particle size, roughness size, and temperature. The current findings are important for the characterization of SNPs through temperature variations and can also be used to adjust the surface charge of SNPs by tuning the temperature.Article Citation - WoS: 16Citation - Scopus: 16Slip Effects on Ionic Current of Viscoelectric Electroviscous Flows Through Different Length Nanofluidic Channels(American Chemical Society, 2020) Şen, Tümcan; Barışık, MuratThe pressure driven slip flow of an electrolyte solution is studied through different nanofluidic channel lengths at varying salt concentrations. The viscous-thickening due to the electrostatic interactions within the electric double layer and the reverse ionic transport due to the streaming potential are developed. The influence of the Navier slip boundary condition is described under both electroviscous and viscoelectric effects with a surface charge regulation (CR) model while the observed behavior is compared and validated with molecular dynamic (MD) calculations from multiple studies. Results show that electroviscous and viscoelectric effects decrease transport. Earlier studies at the no slip boundary presented an increase of ionic current by increasing salt concentration and decreasing channel length. In contrast, our study found that the ionic current occurred almost independent of both salt concentration and channel length, except for very short channels and very low salt concentrations, when electroviscous and viscoelectric effects were considered. In the case of the constant slip length condition, ionic conduction was enhanced, but velocity slip developing on surfaces showed significant variation based on the salt concentration and channel length. This is due to the natural CR behavior enhancing the surface charge and consequential near surface electrohydrodynamics as a result of increase in salt concentration and/or decrease of channel length. Considering that the electroviscous effect alone creates up to 70% lower velocity slips than Poiseuille flow predictions, while further including the viscoelectric effect, results in an almost no-slip condition at high salt concentrations and/or short channels. As a result, the ionic current of a viscoelectric electroviscous slip flow is found to be equal to 1/3 of an electroviscous slip flow and to decrease with a decrease in the channel length.Article Citation - WoS: 32Citation - Scopus: 34Pore Size and Porosity Dependent Zeta Potentials of Mesoporous Silica Nanoparticles(American Chemical Society, 2020) Yakın, Fetiye Esin; Barışık, Murat; Şen, TümcanMesoporous silica nanoparticles (MSNPs) are synthesized in the various forms of porous structures according to an application's needs, while their zeta potentials play a major role in their function. We show that variation in pore size and/or porosity yields a substantial decrease in MSNP zeta potential up to 25% lower than the theoretical zeta potential predictions for a flat surface at the corresponding ionic conditions in moderate pH range. By considering surface chemistry as a function of local ionic conditions (charge regulation), we calculated local zeta potentials around the MSNP which showed variation between pore openings and solid surfaces. Through a systematic study, we evaluated an average three-dimensional zeta potential for MSNPs with various conditions, based on the ratio of the area covered by pore openings to the rest of the MSNP surface area as a function of three-dimensional porosity and pore size. Results show that the high overlap of ionic layers inside the pores creates electric potentials close to zeta potential of the remaining surface, but large pore size and/or high ionic salt concentration yields divergence. We characterized the variation of MSNP zeta potential in terms of porosity (epsilon(3D)), pore size (D-pore), and ionic condition quantified by Debye length (lambda) and obtained unified behavior as a function of the nondimensional group of epsilon(3D)(D-pore/lambda). For epsilon(3D)(D-pore/lambda) < 0.01, MSNP zeta potential remains similar to flat plate predictions, but it decreases by increasing epsilon(3D)(D-pore/lambda) value. The influence of pore entrances on surface zeta potential increases nonlinearly by the increase of porosity and/or decrease of EDL overlap, similar to a change of area to volume ratio. The current findings are important for the understanding and further control of mesoporous particle transport in various promising and groundbreaking applications such as targeted drug delivery.Article Citation - WoS: 22Citation - Scopus: 24Size Dependent Influence of Contact Line Pinning on Wetting of Nano-textured/Patterned Silica Surfaces(Royal Society of Chemistry, 2020) Özçelik, H. Gökberk; Satıroğlu, Ezgi; Barışık, MuratWetting behavior on a heterogeneous surface undergoes contact angle hysteresis as the droplet stabilized at a metastable state with a contact angle significantly different from its equilibrium value due to contact line pinning. However, there is a lack of consensus on how to calculate the influence of pinning forces. In general, the pinning effect can be characterized as (i) microscopic behavior when a droplet is pinned and the contact angle increases/decreases as the droplet volume increases/decreases and (ii) macroscopic behavior as the pinning effects decrease and ultimately, disappear with the increase of the droplet size. The current work studied both behaviors using molecular dynamics (MD) simulation with more than 300 different size water droplets on silica surfaces with three different patterns across two different wetting conditions. Results showed that the contact angle increases linearly with increasing droplet volume through the microscopic behavior, while the droplet is pinned on top of a certain number of patterns. When we normalized the droplet size with the corresponding pattern size, we observed a "wetting similarity" that linear microscopic contact angle variations over different size heterogeneities continuously line up. This shows that the pinning force remains constant and the resulting pinning effects are scalable by the size ratio between the droplet and pattern, independent of the size-scale. The slope of these microscopic linear variations decreases with an increase in the droplet size as observed through the macroscopic behavior. We further found a universal behavior in the variation of the corresponding pinning forces, independent of the wetting condition. In macroscopic behavior, pinning effects become negligible and the contact angle reaches the equilibrium value of the corresponding surface when the diameter of the free-standing droplet is approximately equal to 24 times the size of the surface structure. We found that the pinning effect is scalable with the droplet volume, not the size of the droplet base.Article Citation - WoS: 9Citation - Scopus: 13Local Heat Transfer Control Using Liquid Dielectrophoresis at Graphene/Water Interfaces(Elsevier Ltd., 2021) Yenigün, Onur; Barışık, MuratGraphene-based materials are considered for the solution of the thermal management problem of current and next generation micro/nano-electronics with high heat generation densities. However, the hydrophobic nature of few-layer graphene makes passing heat to a fluid very challenging. We introduced an active and local manipulation of heat transfer between graphene and water using an applied, non-uniform electric field. When water undergoes electric field induced orientation polarization and liquid dielectrophoresis, a substantial increase in heat transfer develops due to a decrease in interfacial thermal resistance and increase in thermal conductivity. By using two locally embedded pin and plate electrodes of different sizes, we demonstrated a two-dimensional heat transfer control between two parallel few-layer graphene slabs. We obtained local heat transfer increase up to nine times at pin electrode region with an ultra-low Kapitza resistance through the studied non-uniform electric field strength range creating highly-ordered compressed water in the experimentally measured density limits. With this technique, heat can be (i) distributed from a smaller location to a larger section and/or (ii) collected to a smaller section from a larger region. Current results are important for hot spot cooling and/or heat focusing applications. © 2020Article Citation - WoS: 17Citation - Scopus: 18Electric Field Controlled Heat Transfer Through Silicon and Nano-Confined Water(Taylor & Francis, 2019) Yenigün, Onur; Barışık, MuratNanoscale heat transfer between two parallel silicon slabs filled with deionized water was studied under varying electric field in heat transfer direction. Two oppositely charged electrodes were embedded into the silicon walls to create a uniform electric field perpendicular to the surface, similar to electrowetting-on-dielectric technologies. Through the electrostatic interactions, (i) surface charge altered the silicon/water interface energy and (ii) electric field created orientation polarization of water by aligning dipoles to the direction of the electric field. We found that the first mechanism can manipulate the interface thermal resistance and the later can change the thermal conductivity of water. By increasing electric field, Kapitza length substantially decreased to 1/5 of its original value due to enhanced water layering, but also the water thermal conductivity lessened slightly since water dynamics were restricted; in this range of electric field, heat transfer was doubled. With a further increase of the electric field, electro-freezing (EF) developed as the aligned water dipoles formed a crystalline structure. During EF (0.53 V/nm), water thermal conductivity increased to 1.5 times of its thermodynamic value while Kapitza did not change; but once the EF is formed, both Kapitza and conductivity remained constant with increasing electric field. Overall, the heat transfer rate increased 2.25 times at 0.53 V/nm after which it remains constant with further increase of the electric field.Article Citation - WoS: 8Citation - Scopus: 8Pore Connectivity Effects on the Internal Surface Electric Charge of Mesoporous Silica(Springer, 2019) Şen, Tümcan; Barışık, MuratNano-scale confinements within mesoporous systems develop overlapping electric double layers (EDL) such that the existing theoretical models cannot predict the electric potential distributions and resulting surface charges. In addition, ionic conditions undergo local variation through connections between the pore voids and pore throats. For the first time in literature, we studied the charging behavior of mesoporous silica in terms of the pore to throat size ratio (R-pt) to characterize the pore connectivity effects, in addition to porosity (epsilon) and pore size (H). Both local and average surface charge densities inside mesoporous silica were examined by varying these parameters systematically. Results showed that the magnitude of surface charge density decreased with increasing EDL overlap and decreasing connectivity effects. We formulized this behavior and developed an extended model to predict mesoporous silica's internal charge as a function of porosity, pore size, and pore to throat size ratio.Article Citation - WoS: 12Citation - Scopus: 12Numerical Determination of Interfacial Heat Transfer Coefficient for an Aligned Dual Scale Porous Medium(Emerald Group Publishing, 2018) Sabet, Safa; Mobedi, Moghtada; Barışık, Murat; Nakayama, AkiraPurpose Fluid flow and heat transfer in a dual scale porous media is investigated to determine the interfacial convective heat transfer coefficient, numerically. The studied porous media is a periodic dual scale porous media. It consists of the square rods which are permeable in an aligned arrangement. It is aimed to observe the enhancement of heat transfer through the porous media, which is important for thermal designers, by inserting intra-pores into the square rods. A special attention is given to the roles of size and number of intra-pores on the heat transfer enhancement through the dual scale porous media. The role of intra-pores on the pressure drop of air flow through porous media is also investigated by calculation and comparison of the friction coefficient. Design/methodology/approach To calculate the interfacial convective heat transfer coefficient, the governing equations which are continuity, momentum and energy equations are solved to determine velocity, pressure and temperature fields. As the dual scale porous structure is periodic, a representative elementary volume is generated, and the governing equations are numerically solved for the selected representative volume. By using the obtained velocity, pressure and temperature fields and using volume average definition, the volume average of aforementioned parameters is calculated and upscaled. Then, the interfacial convective heat transfer coefficient and the friction coefficient is numerically determined. The interparticle porosity is changed between 0.4 and 0.75, while the intraparticle varies between 0.2 and 0.75 to explore the effect of intra-pore on heat transfer enhancement. Findings The obtained Nusselt number values are compared with corresponding mono-scale porous media, and it is found that heat transfer through a porous medium can be enhanced threefold (without the increase of pressure drop) by inserting intraparticle pores in flow direction. For the porous media with low values of interparticle porosity (i.e. = 0.4), an optimum intraparticle porosity exists for which the highest heat transfer enhancement can be achieved. This value was found around 0.3 when the interparticle porosity was 0.4. Research limitations/implications The results of the study are interesting, especially from heat transfer enhancement point of view. However, further studies are required. For instance, studies should be performed to analyze the rate of the heat transfer enhancement for different shapes and arrangements of particles and a wider range of porosity. The other important parameter influencing heat transfer enhancement is the direction of pores. In the present study, the intraparticle pores are in flow direction; hence, the enhancement rate of heat transfer for different directions of pores must also be investigated. Practical implications The application of dual scale porous media is widely faced in daily life, nature and industry. The flowing of a fluid through a fiber mat, woven fiber bundles, multifilament textile fibers, oil filters and fractured porous media are some examples for the application of the heat and fluid flow through a dual scale porous media. Heat transfer enhancement. Social implications The enhancement of heat transfer is a significant topic that gained the attention of researchers in recent years. The importance of topic increases day-by-day because of further demands for downsizing of thermal equipment and heat recovery devices. The aim of thermal designers is to enhance heat transfer rate in thermal devices and to reduce their volume (and/or weight in some applications) by using lower mechanical power for cooling. Originality/value The present study might be the first study on determination of thermal transport properties of dual scale porous media yielded interesting results such as considerable enhancement of heat transfer by using proper intraparticle channels in a porous medium.