Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 21Citation - Scopus: 23Lithium: an Energy Transition Element, Its Role in the Future Energy Demand and Carbon Emissions Mitigation Strategy(Elsevier Ltd, 2024) Chandrasekharam,D.; Şener,M.F.; Recepoğlu,Y.K.; Isık,T.; Demir,M.M.; Baba,A.Energy transition elements (Li, Ni, Co, Fe, Cu) are gaining importance due to their ability to provide energy and play an important role as primary energy sources. Because of the energy density and power density, Li-ion batteries have the edge over other batteries. Li is distributed in various rock-forming minerals and brines, and geothermal waters. Though lithium-bearing minerals are spread over a broad geographic region, these minerals are confined to certain countries with substantial economic potential. Li is extensively used in batteries, and battery-driven vehicles are growing exponentially to meet the carbon reduction goal of the Paris agreement in 2015 and signed by more than 50 percent of the countries. Nearly 55 million cars supported by Li batteries are expected to roll out by 2030. While this is the demand, its occurrence and concentration/extraction processes are not keeping pace with this demand. The extraction of Li from its ore is an energy-intensive process involving many fossil fuel-based energies. To recover one ton of Li metal, nearly 5 to 6 tons of CO2 is emitted. The CO2 emissions of 28 kWh LFP, NMC, and LMO batteries vary from 5600 to 2705 kg CO2-eq. The end-of-life emissions of an internal combustion engine (ICE) vehicle are 400 kg CO2/vehicle, while Li Battery supports 500 kg/vehicle. The quantity of Li required for a 24 kWh average capacity leaf battery is about 137 g/kWh. While emissions are associated with the manufacturing of the batteries, emissions are also associated with a way that while they are recharged as the recharging source is fossil fuel-based energy. The best option to meet zero net carbon emissions by 2050, as envisaged by International Energy Agency (IEA), is to recover Li from geothermal brines and use geothermal energy for recharging. While hydrothermal energy sources are site-specific, enhanced geothermal system (EGS) based geothermal energy is not site-specific and is found wherever high radiogenic granites are available. High radiogenic granites are widely distributed, and heat recovered from EGS sources can provide clean energy and heat. Extraction of lithium from geothermal waters and using geothermal energy for recharging the batteries will drastically reduce CO2 emissions. It will drive the world towards Net Zero Emissions (NZE) scenario in the future. This is being practiced in Turkey. Future research should develop technology to recover Li from geothermal fluids with low concentration and support EGS development. © 2024 Elsevier LtdArticle Citation - WoS: 26Citation - Scopus: 25Conceptual Model of the Gülbahçe Geothermal System, Western Anatolia, Turkey: Based on Structural and Hydrogeochemical Data(Elsevier Ltd., 2017) Uzelli, Taygun; Baba, Alper; Mungan, Gamze Gül; Dirik, Ramazan Kadir; Sözbilir, HasanThe Gülbahçe Geothermal Field is located on the eastern margin of the Karaburun Peninsula, about 45 km from the city of İzmir, western Anatolia, Turkey. The stratigraphy of the study area is represented by a Miocene volcano-sedimentary succession, including several sedimentary and volcanic units. These units overlie the basement rocks of the Karaburun Platform and Bornova Flysch Zone which consist of sandstones, shales and carbonate blocks. These rock units are cut and deformed by a series of NW-SE- to NE-SW-trending faults, extending from Sığacık Bay to Gülbahçe Bay. Structural studies suggest that while most of the geothermal systems in western Anatolia are controlled by normal faults, the geothermal system at Gülbahçe is controlled by a strike-slip dominated shear zone, previously named the İzmir-Balıkesir Transfer Zone. Along the fault zone, associations of active fault segments accommodate deep circulation of hydrothermally modified sea water, and thus the resulting negative flower structure is the primary control mechanism for the geothermal system. Hydrogeochemical properties of the field show that surface temperature of fluid ranges from 30 to 34 °C. Geothermal fluids in Gülbahçe have high salinity (EC > 34 mS/cm) and low enthalpy. Piper and Schoeller diagrams indicate that geothermal fluid is in the NaCl facies. Chemical geothermometers suggest that the reservoir temperature is around 53–136 °C. The isotopic data (oxygen-18, deuterium and tritium) suggest that geothermal fluids are formed by local recharge and deep circulation of sea water.Article Citation - WoS: 2Citation - Scopus: 4Use of Electrospun Fiber Mats for the Remediation of Hypersaline Geothermal Brine(Desalination Publications, 2017) Çelik, Aslı; Koç, Gonca; Erdoğan, Emre; Shahwan, Talal; Baba, Alper; Demir, Mustafa MuammerGeothermal brines display high contents of various metal ions that can adversely affect surface and groundwater resources. Nevertheless, it is possible to sequestrate these metals and use some of them in certain engineering applications. The aim of this study was to fabricate electrospun chitosan fiber mats and remove heavy metal cations from geothermal brine of the Tuzla geothermal field (TGF) by employing these mats. TGF is located on the Biga Peninsula in the northwestern part of Turkey. The brine of TGF has high salinity (EC > 91 mS/cm) and high temperature (reservoir temperature is 173°C). The brine is rich in terms of metal cations. For instance, the concentration of lithium ion in geothermal fluid ranges from 17 to 35 mg/L, with little seasonal variations. A horizontal electrospinning setup was employed to obtain a non-woven mat comprising submicron diameter chitosan fibers at 2.0 kV∙cm−1. This material was then utilized as a stable membrane for the removal of metal ions present in the brine through sorption at 25°C overnight. The results showed that the chitosan fiber mats sequestrate various ions in the brine. Under the studied conditions, the material was capable of removing 46%, 44%, 50%, 44%, 40%, 67% and 48% of Li+, Mg2+, Ba2+, Sr2+, Mn2+, Ca2+ and K+ from the geothermal brine, respectively.Article Citation - WoS: 28Citation - Scopus: 30Hydrochemical and Isotopic Composition of Tuzla Geothermal Field (canakkale-Turkey) and Its Environmental Impacts(Taylor and Francis Ltd., 2009) Baba, Alper; Yüce, Galip; Deniz, Ozan; Yasin, DidemTuzla is an active geothermal area located in northwestern Turkey, 80 km south of the city of Canakkale and 5 km from the Aegean Coast. Geothermal brine, deriving from this area, contains an abundance of NaCl and a water temperature of 173°C (T1 well at 814 m depth) is typically encountered. The aim of this study was to determine the hydrogeochemical properties of the geothermal brine using both chemical and isotopic data, and to investigate the origin of the geothermal brine in the Tuzla area and the environmental impacts of Tuzla Geothermal Field (TGF). Both geothermal brine and shallow groundwater in the area are of meteoric origin. Isotope results indicate that the hot saline waters (brine) in the Tuzla geothermal field originate from connate water along faults. As the saline water rises to the surface, it mixes with shallow groundwaters in various ratios. In addition, the high sodium (Na) and chloride (Cl) content in the Tuzla Stream, fed from the Tuzla geothermal brine during the dry season, cause an increase in sodium and chloride concentrations in the shallow groundwaters by infiltration into the aquifer. Moreover, salt accumulation on the surface is observed due to the uncontrolled artesian flow of geothermal brine, which adversely affects the salinity of shallow groundwater.Article Citation - WoS: 30Citation - Scopus: 36Hydrogeological Properties of Hyper-Saline Geothermal Brine and Application of Inhibiting Siliceous Scale Via Ph Modification(Elsevier Ltd., 2015) Baba, Alper; Demir, Mustafa Muammer; Koç, Gonca A.; Tuğcu, CelalScaling is a major obstacle in harnessing of geothermal energy from the geothermal resources. This paper presents a case study for inhibition of metal silicate scaling using formic acid, harvesting more energy in particular case of Tuzla Geothermal Field (TGF), located on Biga Peninsula, in the northwestern of Turkey. TGF is 5. km far from Aegean Sea and 80. km south of Çanakkale. Geothermal fluid of TGF has high salinity (EC. > 91. mS/cm) and medium temperature (reservoir temperature is 173. °C). The acidification of high-salinity brine to mitigate silicate scaling is examined. Results of the study showed that a compromise between scaling and corrosion is achieved by reducing pH of brine to <6 using 55. ppm formic acid.Article Citation - WoS: 35Citation - Scopus: 45Types of the Scaling in Hyper Saline Geothermal System in Northwest Turkey(Elsevier Ltd., 2014) Demir, Mustafa Muammer; Baba, Alper; Atilla, Vedat; İnanlı, MustafaTuzla is an active geothermal area located in northwestern Turkey, 80km south of the city of Canakkale and 5km from the Aegean Coast. The geothermal brine from this area, which is dominated by NaCl, has a typical temperature of 173°C. Rapid withdrawal of fluid to ambient surface conditions during sampling causes precipitation of various compounds known as scaling. Scaling is one of the important problems in Tuzla geothermal system that reduces the efficiency of the geothermal power plant and causes economical loss. The aim of this study was to determine the type of scaling as a first step towards preventing its formation. The scales formed in the geothermal system were divided into two groups according to location: the ones that formed in downhole and the ones that accumulated along the surface pipeline. Both scales were examined in terms of their elemental composition, structure and morphology using XRF, XRD, and SEM, respectively. The former was found to be mainly composed of PbS (Galena) and CaCO3 (aragonite or calcite). In contrast, the latter was heterogeneous in nature and consisted of mainly saponite like amorphous structure along with submicrometer-sized amorphous silica particles, layered double magnesium and iron hydroxide, and NaCl.