Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 4Citation - Scopus: 3Ligand Engineering for Improving the Stability and Optical Properties of Cspbi3 Perovskite Nanocrystals(Elsevier B.V., 2024) Yuce Cakir,H.; Yalcinkaya,Y.; Demir,M.M.Inorganic lead halide perovskite nanocrystals (NCs) have recently become one of the research topics for optoelectronic applications due to their excellent photophysical properties. Despite their notable thermal stability over organic-inorganic halide perovskites, CsPbI3 NCs suffer from the phase instability of α-CsPbI3 phase at room temperature and under ambient conditions. Here, the effects of 4-Hydroxybenzoic acid (4-HBA) as an additive to standard oleic acid – oleylamine pair on the stability and optical properties of CsPbI3 perovskite NCs are discussed. 4-HBA addition into perovskite NC systems causes a compressive strain on perovskite lattice, which leads to the formation of a mixed phase α- and γ-CsPbI3 phases while pristine perovskite has α-CsPbI3 phase. Time-dependent stability of the perovskite NCs was tested under an ethanol (EtOH) medium. After EtOH exposure of the perovskite NCs, CsPbI3 NCs transformed to non-perovskite phase in 1 h while 4-HBA added CsPbI3 NCs still have perovskite phase after 48 h. In addition to the improved optical properties of the perovskite NCs, 4-HBA addition remarkably improves CsPbI3 perovskite stability. © 2024 Elsevier B.V.Conference Object Citation - Scopus: 1Strength Requirements of Permanent Metal Deck Forms Used for Lateral Bracing of Steel Bridge Girders(2006) Eğilmez, Oğuz Özgür; Helwig, T.A.; Herman, R.S.Permanent metal deck forms (PMDF) are often used in steel bridges to support the weight of the wet concrete during deck construction. Although the PMDF also has the potential to provide bracing to steel bridge girders during construction, the stiffness of the PMDF system as a lateral brace is drastically reduced by the eccentric support angle connection detail used to attach the forms to the girders. Laboratory tests have shown that a simple modification to the connection detail can substantially increase the stiffness of these PMDF systems and allow utilization of the PMDF for girder bracing. This paper presents results from a parametrical study conducted to determine stability and strength requirements for PMDF used to provide lateral bracing to steel bridge girders. Detailed FEA models were used to determine the stability bracing strength requirements for the fasteners that are used to connect the PMDF along the sidelaps of the sheets and to the girders. Design expressions are presented as well as an example demonstrating the use of the design equations.Conference Object Citation - Scopus: 2Adaptive Actuator Failure Compensation for Concurrently Actuated Manipulators(Elsevier, 2003) Keçeci, Emin Faruk; Tang, Xidong; Tao, GangThis paper presents an adaptive actuator failure compensation method, which compensates for uncertainties due to unknown actuator failures and system dynamics, for a class of redundant manipulators where some joints concurrently actuated. Physical realization of concurrently actuated manipulators and their advantageous of use have been understood before, but adaptive failure compensation is still an open issue. In this research, failure formulation, controller structure and adaptive update rules for handling uncertainties from both the system dynamics and the failures are studied. The system stability is shown by a modified Lyapunov. Simulation results show the effectiveness of the proposed adaptive failure compensation control design.Conference Object Adaptive Actuator Failure Compensation for Cooperating Multiple Manipulator Systems(Elsevier, 2003) Keçeci, Emin Faruk; Tang, Xidong; Tao, GangThis paper presents adaptive actuator failure compensation for a cooperating multiple manipulator system with uncertain actuator failures in the task space. Advantages of designing control schemes in task spaces are emphasized, applications of task space control in robotics are discussed and a short review on control algorithms for cooperating multiple manipulator systems is given. Dynamic equations of motion of the multiple manipulator system in the task space are derived, and the adaptive actuator failure compensation problem is formulated. A compensation controller structure is proposed, for which adaptive parameter update laws are developed. The adaptive control scheme is able to compensate for the uncertainties arising from both the system parameters and the actuator failures. Based on Lyapunov stability analysis, the closed-loop signal boundedness and the convergence of the tracking error to zero are ensured. © 2003 International Federation of Automatic Control.Article Citation - WoS: 20Citation - Scopus: 21Long Term Stability of Biodegradable Polymers on Building Limestone(Elsevier Ltd., 2019) Kaplan, Zişan; Böke, Hasan; Sofuoğlu, Aysun; İpekoğlu, BaşakSynthetic polymers can be replaced by biodegradable ones as adhesives, water repellents and consolidants on the stone surfaces and facades of the historic buildings in their conservation to minimize future deterioration. In this study, the long-term stability of two biodegradable polymers, polyhydroxybutyrate (PHB) and poly-L-lactide (PLA), and an acrylic polymer (Paraloid B72) which is commonly used in conservation works of artefacts, were evaluated on limestone using a UV lamp-weathering chamber (up to 104 days) for future protection studies. Chemical and morphological changes induced by an accelerated weathering test were examined by Fourier Transform Infrared spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM) analyses. Protection efficiency of the polymers was determined by the changes in color, capillary water absorption, static contact angle on limestone. Paraloid B72, PHB, and PLA coatings significantly increased hydrophobicity while decreasing capillarity water absorption and caused negligible change in the color of the limestone. Protection efficiencies of PLA and PHB polymers were almost the same as that of Paraloid B72, a widely used acrylic polymer. However, PLA and PHB seemed to be favorable polymers as protective agents due to their reversibility and biodegradability, low chromatic changes, good hydrophobic behavior and good stability to weathering in reducing the effects of outdoor exposure on limestone surfaces.Conference Object Physical Model Experiments of Ordu-Giresun Airport, Turkey(American Society of Civil Engineers (ASCE), 2016) Arıkan, S. E.; Gültekin, N.; Küçükosmanoğlu, A.; Özbahçeci, Bergüzar; Sağ, M.; Kılıç, Y.; Koca, F.Ordu-Giresun Airport, which has been constructed recently, being an example of the aviation sector of Turkish transportation network, is a project having marine structural aspects due to the construction at the sea by filling and in this workout physical model experiments of the project are evaluated. 3000-meters-long runway and the other superstructures of the airport, the first example of construction of such a structure by filling in the sea in Turkey, is to be protected by a breakwater of 7435 meters long. 'First Cross Section' has been prepared by using experimental formulas and artificial neural network and 'Second Cross Section', being the alternative of the first one has been planned. Yet, both cross sections have similar characteristics, they have berm heights in such a manner that 'First Cross Section' enables the structure to be constructed from the sea, whereas 'Second Cross Section' makes it possible from the land. Both cross sections are aimed to be evaluated in terms of stability, wave overtopping and economy through the hydraulic model studies performed at the Hydraulics Laboratory of Turkish Ministry of Transportation, Maritime Affairs and Communication. Starting from design stage (computation of design wave characteristics, physical model experiment under different wave conditions on different structure alternatives) to construction stage the engineering studies is presented with comparisons and discussions.Conference Object Citation - Scopus: 1A New Approach To Breakwater Design-2b Block(American Society of Civil Engineers (ASCE), 2016) Bilyay, Engin; Özbahçeci, Bergüzar; Bacanlı, Selahattin; Kızıroğlu, GülşenBreakwaters are one of the oldest and important marine structures. Rubble mound breakwater is a very common type in all around the world. If the heavier rock is necessary for the design, concrete armor units are used. Each unit has its own advantages and disadvantages. For example cube and antifer blocks are massive units and their interlocking is weak. Dolos and tribar units have good interlocking but rocking stresses in these units are extraordinarily high. The placement method is very important and requires special equipment and experienced staff for the later developed single-layered units like accropod and core-loc. Moreover, continuous touching of blocks to each other and fatigue of the material may cause the breakdown of legs and serious damage of armor layer. And in case of damage, it is necessary to remove the units in a wide area on the breakwater and then relocate them, so it is very difficult to repair. A new type concrete armor unit is developed considering all these problems. It is called 2B Blocks.Article Effect of Temperature on Stability of Lipid Microbubbles(Turkish Chemical Society, 2019) Kılıç, SevgiThe effect of temperature on stability of lipid microbubble shell containing polyethyleneoxide-40-stearate (PEG40St) as emulsifier was investigated. Microbubbles at 4 °C were subjected to different temperatures up to 48 ºC (down-to-up) and it was found that both the number and the size of microbubbles remained unchanged in the population up to a certain time, so called “onset time”. The onset time was about 6 hours at 10 °C, 2 hours at 20 °C and shorter at elevated temperatures, exhibiting an exponential decrease with increasing temperature. Once the onset time was reached, the number of microbubbles started to decrease and the average size of the population started to increase. Observation of single microbubbles on a constant temperature heating stage exhibited that each microbubble had its own onset time, with the smaller microbubbles vanishing earlier than the larger ones. The Langmuir monolayer studies showed that hydration degree of the emulsifier PEG chains decreased with temperature, causing them go through conformational changes and subsequently destabilization of the shell. By subjecting the freshly produced microbubbles directly to the desired temperatures in up-to-down fashion, more stable microbubbles were able to be produced, with their onset time increased 40% at 10 °C to 500% at 38 °C. Overall, the results suggest that the new strategies need to be developed to control the collapse process in the microbubble shell resulting from the conformational changes in the PEG chains of the emulsifier for the design of more stable microbubbles. © 2019, Turkish Chemical Society. All rights reserved.Article Citation - WoS: 13Citation - Scopus: 15Analysis of Dilution Induced Disintegration of Micellar Drug Carriers in the Presence of Inter and Intra Micellar Species(Elsevier, 2020) Polat, Hürriyet; Kutluay, Gülistan; Polat, MehmetMicelles of self-assembling polymeric surfactant molecules are promising nanoscopic carriers for lipophilic and toxic drugs, genes, and imaging molecules. Though it is a must for successful transport, ensuring micelle integrity is a challenge during intravenous injection where micelles must endure abrupt dilutional effects and encounters with native molecules. Therefore, direct observational evidence of how micelles behave during dilution is valuable in manipulating the designs of these carriers for a succesful drug delivery. Morphology and stability of the barren and a drug-loaded (lipophilic probucol) micelles of a polymeric surfactant (Pluronic® P123) were monitored during systematic re-dilution in distilled water and simulated body fluid in the presence of a model protein (bovine serum albumin). It was observed through surface tension, dynamic light scattering, laser velocimetry, transmission scanning and transmission electron microscopy, and atomic force microscopy analyses that the micelles disintegrated to various degrees in all cases upon dilution. The results indicate that dilution effects must be taken into account in designing micellar drug carriers. The assistance of some other means of protection such as encapsulation should be considered for ensuring micelle integrity within the bloodstream. © 2020 Elsevier B.V.Article Citation - WoS: 8Citation - Scopus: 7Commercially Suitable Pectin Methylesterase From Valencia Orange Peels(Türkiye Klinikleri Journal of Medical Sciences, 2010) Şimşek, Şebnem; Yemenicioğlu, AhmetA simple and effective procedure was developed to extract pectin methylesterase (PME) from Valencia orange peels. Orange peels contain 25-34 μmol of COOH min-1 g-1 of peel PME activity. The enzyme was ionically bound to cell walls and could not be extracted with water. This enables removal of water soluble pectic substances and oils from peels via homogenization and washing with water before enzyme extraction. Enzyme extraction can be conducted simply by addition of suitable amounts of NaCl (optimum: 10 g of NaCl 100 g-1 of extraction mixture) to peel homogenate and stirring (optimum: 30 min at 200 rpm). The PME extracted from orange peels contains almost the same amount of heat-stable and heat-labile fraction, and the enzymes cannot be activated by mild heating. A slight activation of enzyme (almost 20%) was achieved by adding 1 mM CaCl2 to enzyme extracts, but this agent was inhibitory at higher concentrations. The extracts stabilized by Na-benzoate and K-sorbate maintained more than 90% of their PME activity at 4 °C for at least 5 months. The obtained PME was successfully used to prepare low-methoxyl citrus pectin used in edible film formation in the presence of CaCl2. This study shows the potential of using Valencia orange peels as a source of commercial PME. © TÜBİTAK.