Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 13Citation - Scopus: 13Application of Work Function Measurements in the Study of Surface Catalyzed Reactions on Rh(1 0 0)(Taylor & Francis, 2018) Çağlar, Başar; Kızılkaya, Ali Can; Niemantsverdriet, J. W. (Hans); Weststrated, C. J. (Kees-Jan)The present article aims to show how work function measurements (WF) can be applied in the study of elementary surface reaction steps on metallic single crystal surfaces. The work function itself can in many cases not be interpreted directly, as it lacks direct information on structural and chemical nature of the surface and adsorbates, but it can be a powerful tool when used together with other surface science techniques which provide information on the chemical nature of the adsorbed species. We here, illustrate the usefulness of work function measurements using Rh(100) as our model catalyst. The examples presented include work function measurements during adsorption, surface reaction, and desorption of a variety of molecules relevant for heterogeneous catalysis. Surface coverage of adsorbates, isosteric heat of adsorption, and kinetic parameters for desorption, desorption/decomposition temperatures of surface species, different reaction regimes were determined by WF with the aid of other surface science techniques.Article Citation - WoS: 3Citation - Scopus: 3Growth and Characterization of Cdte Absorbers on Gaas by Mbe for High Concentration Pv Solar Cells(John Wiley and Sons Inc., 2015) Arı, Ozan; Polat, Mustafa; Karakaya, Merve; Selamet, YusufCdTe based II-VI absorbers are promising candidates for high concentration PV solar cells with an ideal band gap for AM1.5 solar radiation. In this study, we propose single crystal CdTe absorbers grown on GaAs substrates with a molecular beam epitaxy (MBE) which is a clean deposition technology. We show that high quality CdTe absorber layers can be grown with full width half maximum of X-ray diffraction rocking curves (XRD RC) as low as 227 arc-seconds with 0.5% thickness uniformity that a 2 μm layer is capable of absorbing 99% of AM1.5 solar radiation. Bandgap of the CdTe absorber is found as 1.483 eV from spetroscopic ellipsometry (SE) measurements. Also, high absorption coefficient is calculated from the results, which is ∼5 x 105cm-1 in solar radiation spectrum.Conference Object Citation - WoS: 1Citation - Scopus: 1Self-Heating Effect in Intrinsic Tunneling Spectroscopy of Hgbr2 Intercalated Bi2.1sr1.4ca1.5cu 2o8+? Single Crystals(IEEE, 2007) Kurter, Cihan; Özyüzer, Lütfi; Zasadzinski, John F.; Hinks, David G.; Gray, Kenneth E.We report tunneling results in intrinsic Josephson junction (IJJ) stacks fabricated in the form of square micromesas on HgBr2 intercalated Bi2.1Sr1.4Ca1.5Cu2O 8+δ (Bi2212) single crystals using photolithography and Ar ion milling techniques. Self-heating is the most common problem encountered in interlayer tunneling and it is likely to reduce the reliability of IJJ data. Although intercalation reduces heating a hundredfold, it still needs to be minimized substantially in order to approach the authentic superconducting energy gap observed by tunneling using more conventional junctions. We report tunneling characteristics of two mesas with the same height but different sizes (5 × 5 μm2 and 10 × 10 μm2) to show that heating effects are strongly related to IJJ stack size. For the smaller mesa, we observed an energy gap close to that seen in single SIN (S: superconductor, I: insulator, N: normal metal) and SIS break junctions as well as the dip and hump structures at high bias. The subgap data of 5 × 5 μm2 mesa were successfully fit with a momentum averaged d-wave model using convenient parameters. Thus our data is consistent with the predominant pairing symmetry suggested by point contact tunneling, break junction, scanning tunneling microscopy/spectroscopy and angle resolved photoemission measurements in Bi2Sr2CaCu2O8+δ.