Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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  • Article
    Citation - WoS: 20
    Citation - Scopus: 22
    Fabrication and Properties of Novel Porous Ceramic Membrane Supports From the (sig) Diatomite and Alumina Mixtures
    (Elsevier, 2022) Aouadja, Faycal; Bouzerara, Ferhat; Güvenç, Çetin Meriç; Demir, Mustafa M.
    In this paper, the manufacturing of macro-porous tubular ceramic supports for membranes is described. The novel supports are fabricated from natural diatomite and alumina raw materials using the extrusion method. The structure was analyzed by X-ray diffraction (XRD) and mercury porosimetry techniques; the presence of possible defects was investigated by scanning electron microscopy (SEM). The permeability has been measured from water flux in standard experiments. Experimental results show that the open porosity, the average pore size (APS), the pore size distribution, the strength, and the permeability of sintered supports, have been found to depend, mainly on the concentration of alumina (Al2O3) additive. Supports prepared with the addition of 10 wt.% of alumina and sintered at 1200 degrees C, can be considered as the most optimized; they have a porosity ratio of about 46%, an APS is around 7.7 mu m, a flexural strength value of about 28 MPa, and water permeability of around 15 m(3)h(-1) m(-2) bar(-1). Such materials could be of great interest in the supports fabrication for membrane application, for instance, water filtration. (C) 2021 SECV. Published by Elsevier Espana, S.L.U.
  • Article
    Citation - WoS: 43
    Citation - Scopus: 47
    Bioactive Diatomite and Poss Silica Cage Reinforced Chitosan/Na-carboxymethyl Cellulose Polyelectrolyte Scaffolds for Hard Tissue Regeneration
    (Elsevier, 2019) Tamburacı, Sedef; Kimna, Ceren; Tıhmınlıoğlu, Funda
    Recently, natural polymers are reinforced with silica particles for hard tissue engineering applications to induce bone regeneration. In this study, as two novel bioactive agents, effects of diatomite and polyhedral oligomeric silsesquioxanes (POSS) on chitosan (CS)/Na-carboxymethylcellulose (Na-CMC) polymer blend scaffolds are examined. In addition, the effect of silica reinforcements was compared with Si-substituted nano-hydroxyapatite (Si-Hap) particles. The morphology, physical and chemical structures of the scaffolds were characterized with SEM, liquid displacement, FT-IR, mechanical analysis, swelling and degradation studies. The particle size and the crystal structure of diatomite, POSS and Si-Hap particles were determined with DLS and XRD analyses. In vitro studies were performed to figure out the cytotoxicity, proliferation, ALP activity, osteocalcin production and biomineralization to demonstrate the promising use of natural silica particles in bone regeneration. Freeze-dried scaffolds showed 190-307 mu m pore size range and 61-70% porosity. Both inorganic reinforcements increased the mechanical strength, enhanced the water uptake capacity and fastened the degradation rate. The nanocomposite scaffolds did not show any cytotoxic effect and enhanced the surface mineralization in osteogenic medium. Thus, diatomite and POSS cage structures can be potential reinforcements for nanocomposite design in hard tissue engineering applications.