Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 103Citation - Scopus: 113Preparation and Characterizations of Tio2/Zno Nanohybrid and Its Application in Photocatalytic Degradation of Tetracycline in Wastewater(Elsevier, 2023) Zeinali Heris, Saeed; Etemadi, Martin; Mousavi, Seyed Borhan; Mohammadpourfard, Mousa; Ramavandi, BahmanThe photodegradation of tetracycline antibiotics (TC) in an aqueous solution, using the TiO2 nanoparticles, ZnO microparticles, and TiO2/ZnO composite under the UV lamp in a continuous reactor, was performed. The effects of different parameters, such as the initial TC concentration, medium pH, ratio of each photocatalyst, and the flow rate were comprehensively studied. SEM, EDX, and XRD characterization techniques were employed to study the morphology and structure features of the prepared composite. The results revealed that a more significant amount of TC is not easily removed from wastewater. Furthermore, by increasing the pH of the medium to 11, the efficiency of TC degradation was increased, while the amount of removal remained stable at higher pH values. As the flow rate increased up to 190 mL/min, the removal efficiency increased; however, at higher flow rates, lower efficiency was obtained. Moreover, using multivariate analysis and response surface methodology (RSM), a model for removing TC and the effect of experimental parameters on removal efficiency was proposed. The optimal conditions using the RSM method were found to be the reduction efficiency of 78.94 % in pH = 11 (flow rate of 132 mL/min, and TiO2 concentration of 323 mg) and reduction efficiency of 75.89% in pH = 9 (flow rate of 143.19 mL/min and TiO2 concentration of 312.73 mg). © 2023 Elsevier B.V.Article Citation - WoS: 40Citation - Scopus: 47Boron in Geothermal Energy: Sources, Environmental Impacts, and Management in Geothermal Fluid(Elsevier, 2022) Mott, A.; Baba, Alper; Hadi Mosleh, Mojgan; Ökten, Hatice Eser; Babaei, Masoud; Gören, Ayşegül Yağmur; Feng, C.; Recepoğlu, Yaşar Kemal; Uzelli, Taygun; Uytun, Hüseyin; Morata, Diego; Yüksel Özşen, AslıThe problem of hazardous chemicals in geothermal fluid is a critical environmental concern in geothermal energy developments. Boron is among the hazardous contaminants reported to be present at high concentrations in geothermal fluids in various countries. Poor management and inadequate treatment of geothermal fluids can release excessive boron to the environment that has toxic effects on plants, humans, and animals. Despite the importance of boron management in geothermal fluid, limited and fragmented resources exist that provide a comprehensive understanding of its sources, transport and fate, and the treatment strategies in geothermal energy context. This paper presents the first critical review from a systematic and comprehensive review on different aspects of boron in geothermal fluid including its generation, sources, toxicity, ranges and the management approaches and treatment technologies. Our research highlights the origin of boron in geothermal water to be mainly from historical water-rock interactions and magmatic intrusion. Excessive concentrations of boron in geothermal fluids have been reported (over 500 mg/L in some case studies). Our review indicated that possible boron contamination in geothermal sites are mostly due to flawed construction of production/re-injection wells and uncontrolled discharge of geothermal water to surface water. The dominancy of non-ionic H3BO3 species makes the selection of the suitable treatment method for geothermal waters limited. Combining boron selective resins and membrane technologies, hybrid systems have provided effluents suitable for irrigation. However, their high energy consumption and course structure of boron selective resins encourage further research to develop cost-effective and environmentally friendly alternatives.
