Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 34Citation - Scopus: 37Steam Gasification of Safflower Seed Cake and Catalytic Tar Decomposition Over Ceria Modified Iron Oxide Catalysts(Elsevier Ltd., 2014) Duman, Gözde; Watanabe, Taichi; Uddin, Md Azhar; Yanık, JaleCatalytic steam gasification of safflower seed cake was carried out using a double-bed microreactor in a two-stage process in the presence of ceria oxide (CeO2) modified iron oxide (Fe2O3) catalysts with different CeO2-Fe2O3 ratios. The effects of both catalyst and the temperature of catalytic bed on the tar decomposition and the overall gaseous product yield were investigated comparatively. It was found that ceria modified iron oxide catalysts had higher reactivity than that of the individual Fe2O3 and CeO2 for the catalytic tar decomposition in safflower seed cake steam gasification. The CeO2-Fe2O3 catalyst with 50 wt.% of Fe 2O3 exhibited the excellent performance for tar conversion at 700 °C. A comparison of tar decomposition from thermal run and catalytic run showed that in thermal run tar decomposition was progressed via steam reforming only. However, in the presence of catalyst, tar decomposition occurred via both steam reforming and water gas shift reaction. As a conclusion, ceria promoted iron catalysts were found to be active for both hydrogen production and tar decomposition in steam gasification of lignocellulosic biomass.Article Citation - WoS: 61Citation - Scopus: 75Optimization of Biomass, Pellet Size and Polygalacturonase Production by Aspergillus Sojae Atcc 20235 Using Response Surface Methodology(Elsevier Ltd., 2007) Tarı, Canan; Göğüş, Nihan; Tokatlı, FigenA two-step optimization procedure using central composite design with four factors (concentrations of maltrin and corn steep liquor (CSL), agitation speed and inoculation ratio) was used in order to investigate the effect of these parameters on the polygalacturonase (PG) enzyme activity, mycelia growth (biomass) and morphology (pellet size) of Aspergillus sojae ATCC 20235. According to the results of response surface methodology (RSM), initial concentrations of maltrin and CSL and agitation speed were significant (p < 0.05) on both PG enzyme production and biomass formation. As a result of this optimization, maximum PG activity (13.5 U/ml) was achievable at high maltrin (120 g/l), at low CSL (0 g/l), high agitation speed (350 rpm) and high inoculation ratio (2 × 107 total spore). Similarly, maximum biomass (26 g/l) could be obtained under the same conditions with only the difference for higher level of CSL requirement. The diameter of pellets in all optimization experiments ranged between 0.05 and 0.76 cm. The second optimization step improved the PG activity by 74% and the biomass by 40%.
