Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Interventions in Historic Urban Sites After Earthquake Disasters(MDPI, 2025) Demir, Hatice Aysegul; Turan, Mine HamamciogluEarthquakes, fires, and climate change-related hazards increasingly threaten cultural heritage. Documenting and identifying the significance of heritage sites before disasters is essential for archival purposes and for guiding post-disaster interventions such as consolidation, reconstruction, or redesign. Although various post-disaster strategies exist in the literature, they often lack consideration of pre-disaster values and authentic qualities, limiting their effectiveness in value-based regeneration. This study proposes a framework for managing post-disaster interventions grounded in pre-disaster documentation of heritage values, authenticity, and integrity. The methodology includes seven phases: case selection; site survey and documentation; thematic analysis and mapping; quantification of qualitative data; synthesis of pre-disaster analysis results to define values, problems, and potentials; post-disaster assessment using aerial and terrestrial imagery; and development of targeted intervention strategies. This study focuses on two areas in Antakya, T & uuml;rkiye: Kurtulu & scedil; Street and Kuyulu Neighborhood, affected by the 2023 earthquake (M 7.7). These areas represent different historical layers: a Hellenistic grid plan with French-style buildings, and an organic Ottoman settlement morphology, respectively. Conservation data collected in 2019 inform the analysis. Mapping techniques evaluate attributes such as spatial characteristics, typologies, and structural systems. The study concludes that traces of pre-disaster spatial patterns and building features should inform post-disaster designs, ensuring sustainable, earthquake-resistant, and value-based interventions.Article A First Process-Oriented Characterization of Eriolobus Trilobatus (Labill. Ex Poiret) Bark From Turkey: Chemical, Morphological and Energy Properties(MDPI, 2025) Sen, Umut; Yucedag, Cengiz; Balci, Busra; Arici, Sefik; Kocar, Gunnur; Sat, Beyza; Pereira, HelenaFor the first time, Eriolobus trilobatus bark from Turkey has been characterized in terms of its chemical, extractive, fuel, and ash characteristics using SEM-EDS, wet chemical analysis, phenolic analysis, FT-IR, TGA, XRF, XRD, BET surface area measurement, proximate analysis, and ash fusion temperature (AFT) determination. The results showed that the bark contains 13% ash, dominated by calcium oxalate, and 15% extractives, largely composed of polar phenolic compounds with moderate radical-scavenging potential. Thermal decomposition of bark proceeds in four distinct stages, associated with the sequential degradation of extractives/hemicelluloses, cellulose, lignin/suberin, and inorganic fractions. The higher calorific value of 14.9 MJ/kg indicates moderate fuel quality compared with conventional woody biomass. Ash is mesoporous with a CaO-rich structure highly suitable for catalytic applications in biodiesel production and biomass gasification. Ash fusion analysis revealed a high flow temperature (1452 degrees C), indicating a very low slagging risk during thermochemical conversion. Overall, E. trilobatus bark is a promising material for value-added biorefinery pathways, enabling processes for the production of biochars, CaO-based catalysts, phenolic extracts, and sustainable energy. The valorization of E. trilobatus bark not only enhances the economic potential of forestry residues but also provides environmental co-benefits through carbon soil amendment and landscape applications.Article Chemical Composition and Reactivity of Quercus Pubescens Bark and Bark Fractions for Thermochemical Biorefinery Applications(MDPI, 2025) Sen, Umut; Balci, Busra; Arici, Sefik; Sat, Beyza; Miranda, Isabel; Pereira, HelenaAdvancing circular bioeconomy in thermochemical biorefineries requires species-specific data that link biomass composition and thermochemical performance. Here, we provide the first integrated thermochemical dataset for Quercus pubescens bark combining FT-IR, XRD, XRF, TGA, and measured ash fusion temperatures (AFT). The results reveal that bark is enriched in phenolic extractives (21.2%) and inorganics (15%), with calcium oxalate monohydrate (COM) dominating the inorganic fraction, as confirmed by FT-IR and XRD. Thermal decomposition occurs between 150 degrees C and 690 degrees C. Pyrolysis follows diffusion-controlled kinetics, with apparent activation energies for bark and its fractions ranging between 70 and 103 kJ mol-1. Extraction increases the activation energy of bark. The ash exhibits a high AFT (softening: 1421 degrees C, flow: 1467 degrees C), placing this feedstock within the low-slagging, moderate-fouling range compared to other lignocellulosics. The observed COM-to-CaCO3/CaO transformation upon heating contributes to the elevated AFT. Reactivity analyses of bark fractions support thermochemical biorefinery routing of fractions: extracted bark (EB) and desuberinised bark (DB) are highly reactive and well-suited to combustion/gasification, whereas raw bark (B) and Klason lignin (KL) exhibit higher thermal stability and yield more persistent char, favoring slow pyrolysis for biochar production. Such routing strategies optimize energy recovery and also enable co-products with environmental co-benefits.Article Iron-Promoted 1,5-Substitution Reaction of Endocyclic Enyne Oxiranes With Memgbr: a Stereoselective Method for the Synthesis of Exocyclic 2,4,5-Trienol Derivatives(MDPI, 2023) Kuş, Melih; Omur, Cenk; Karaca, Sila; Artok, LeventThe iron-promoted 1,5-substitution reaction of endocyclic oxiranes with MeMgBr yields exocyclic 2,4,5-trienols with high diastereomeric ratios of up to 100:0. However, for the method's success, the oxirane ring must have a trans-configuration. The reactions exhibit strong stereoselectivity concerning the methylation mode and the configuration of the resulting exocyclic double bond. Enantiomerically pure enyne oxiranes can be synthesized through Sharpless asymmetric dihydroxylation and subsequent manipulations. With these reagents, it has been possible to produce exocyclic 2,4,5-trienols in enantiopure forms. Importantly, this process maintains chirality without degradation during the center-to-axis transfer of chirality.Article Citation - WoS: 1Citation - Scopus: 1Light-Dark and Activity Rhythm Therapy (l-Dart) To Improve Sleep in People With Schizophrenia Spectrum Disorders: a Single-Group Mixed Methods Study of Feasibility, Acceptability and Adherence(MDPI, 2023) Faulkner, Sophie; Didikoğlu, Altuğ; Byrne, Rory; Drake, Richard; Bee, PennyPeople with a diagnosis of schizophrenia often have poor sleep, even when their psychotic symptoms are relatively well managed. This includes insomnia, sleep apnoea, hypersomnia, and irregular or non-24 h sleep-wake timing. Improving sleep would better support recovery, yet few evidence-based sleep treatments are offered to this group. This paper presents a mixed methods feasibility and acceptability study of Light-Dark and Activity Rhythm Therapy (L-DART). L-DART is delivered by an occupational therapist over 12 weeks. It is highly personalisable to sleep phenotypes and circumstances. Ten participants with schizophrenia spectrum diagnoses and sleep problems received L-DART; their sleep problems and therapy goals were diverse. We measured recruitment, attrition, session attendance, and adverse effects, and qualitatively explored acceptability, engagement, component delivery, adherence, activity patterns, dynamic light exposure, self-reported sleep, wellbeing, and functioning. Recruitment was ahead of target, there was no attrition, and all participants received the minimum 'dose' of sessions. Acceptability assessed via qualitative reports and satisfaction ratings was good. Adherence to individual intervention components varied, despite high participant motivation. All made some potentially helpful behaviour changes. Positive sleep and functioning outcomes were reported qualitatively as well as in outcome measures. The findings above support testing the intervention in a larger randomised trial ISRCTN11998005.Review Citation - WoS: 7Citation - Scopus: 7Ultrasonication Effects on Quality of Tea-Based Beverages(MDPI, 2023) Uzuner, SibelTea is the most popular consumed drink after water. Teas and tea-based beverages have grown in popularity due to bioactive compounds. Tea-based beverages have started to take their place in the market. Extraction is a crucial step for the production of functional tea-based beverages. Compared to conventional methods, ultrasound is attractive due to its lower energy requirements, and shorter extraction time. This review aimed to discuss recent marketing aspects of tea-based beverages as well as the potential and challenges of a novel infusion technique. This review describes the health benefits and technological aspects of tea-based beverages in relation to how to best solve nutritional and microbial concerns. Current and future challenges and opportunities of the novel infusion technique and its scaling-up for the extraction of bioactive compounds are also covered in the present review.Article Citation - WoS: 23Citation - Scopus: 27The Influence of Meteorological Parameters on Pm10: a Statistical Analysis of an Urban and Rural Environment in İzmir/Turkiye(MDPI, 2023) Birim, Necmiye Gulin; Turhan, Cihan; Atalay, Ali Serdar; Gökçen Akkurt, GüldenAir pollution is a substantial menace, especially in industrialized urban zones, which affects the balance of the environment, life of vital organisms and human health. Besides the main causes of air pollution such as dense urbanization, poor quality fuels and vehicle emissions, physical environment characteristics play an important role on air quality. Therefore, it is vital to understand the relationship between the characteristics of the natural environment and air quality. This study examines the correlations between the PM10 pollutant data and meteorological parameters such as temperature (T-air), relative humidity (RH), and wind speed (WS) and direction (WD) under the European Union's Horizon 2020 project. Two different zones (Vilayetler Evi as an urban zone and Sasali Natural Life Park as a rural zone) of Izmir Province in Turkiye are used as a case study and the PM10 data is evaluated between 1 January 2017 and 31 December 2021. A one-tailed t-test is used in order to statistically determine the relationships between the PM10 pollutant data and meteorological parameters. As a further study, practical significance of the parameters is investigated via the effect size method and the results show that the RH is found to be the most influencing parameter on the PM10 for both zones, while T-air is found to be statistically non-significant.Article Citation - WoS: 3Citation - Scopus: 3Numerical Study of Electrostatic Desalting: a Detailed Parametric Study(MDPI, 2022) Ramirez-Argaez, Marco A.; Abreú-López, Diego; Gracia-Fadrique, Jesús; Dutta, AbhishekA systematic process analysis was conducted to study the effect of the main variables in an industrial electrostatic desalter, such as electric field intensity, wash water content, droplet size, and oil viscosity, on the efficiency of the separation of water from oil. The analysis was assessed through an already published and validated CFD multiphase numerical model that considers the expression of the frequency of collisions as a function of the mentioned process variables. Additionally, the study allowed the formal optimization exercise of the operation to maximize the separation efficiency. The most significant variables were the initial water content and the electric field intensity, while the temperature (oil viscosity) had an effect to a lower extent. An increase in the electric field and temperature and a decrease in the water content improved the water separation from oil. Optimum values suggested from the factorial experimental design and the optimization implemented in this work indicated the use of an electric field of 3 kV/cm, water content of 3%, and an oil viscosity of 0.017 kg/ms. At the same time, the droplet size showed no significant effect under the conditions explored in this work.Article Citation - WoS: 13Citation - Scopus: 13A Theoretical Investigation on the Physical Properties of Zirconium Trichalcogenides, Zrs3, Zrse3 and Zrte3 Monolayers(MDPI, 2022) Mortazavi, Bohayra; Shojaei, Fazel; Yağmurcukardeş, Mehmet; Makaremi, Meysam; Zhuang, XiaoyingIn a recent advance, zirconium triselenide (ZrSe3) nanosheets with anisotropic and strain-tunable excitonic response were experimentally fabricated. Motivated by the aforementioned progress, we conduct first-principle calculations to explore the structural, dynamic, Raman response, electronic, single-layer exfoliation energies, and mechanical features of the ZrX3 (X = S, Se, Te) monolayers. Acquired phonon dispersion relations reveal the dynamical stability of the ZrX3 (X = S, Se, Te) monolayers. In order to isolate single-layer crystals from bulk counterparts, exfoliation energies of 0.32, 0.37, and 0.4 J/m2 are predicted for the isolation of ZrS3, ZrSe3, and ZrTe3 monolayers, which are comparable to those of graphene. ZrS3 and ZrSe3 monolayers are found to be indirect gap semiconductors, with HSE06 band gaps of 1.93 and 1.01 eV, whereas the ZrTe3 monolayer yields a metallic character. It is shown that the ZrX3 nanosheets are relatively strong, but with highly anisotropic mechanical responses. This work provides a useful vision concerning the critical physical properties of ZrX3 (X = S, Se, Te) nanosheets.Editorial Citation - WoS: 1Citation - Scopus: 1Special Issue on “process Modeling in Pyrometallurgical Engineering”(MDPI, 2021) Saxen, Henrik; Ramirez-Argaez, Marco A.; Conejo, Alberto N.; Dutta, AbhishekThis Special Issue on “Process Modeling in Pyrometallurgical Engineering” consists of 39 articles, including two review papers, and covers a wide range of topics related to process development and analysis based on modeling in ironmaking, steelmaking, flash smelting, casting, rolling operations, etc. The approaches include small-scale experiments and experimental design, first-principles modeling, detailed modeling based on CFD or DEM, and statistical and machine-learning-based methods. In the following paragraphs the issue is briefly scanned, presenting the papers in the order roughly following the route from raw materials processing to rolling and heat treatment.