Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 10Citation - Scopus: 10Influence of Calcium Acetate Concentration in Electrolyte on Tribocorrosion Behaviour of Mao Treated Titanium(MDPI Multidisciplinary Digital Publishing Institute, 2021) Sousa, Luis; Mendes, Ana Rita; Pinto, Ana Maria Pires; Toptan, Fatih; Alves, Alexandra CruzTi-based materials are widely used for dental and orthopaedic implant applications due to their adequate mechanical properties, corrosion behaviour and biocompatibility. However, these materials are biologically inert and display poor wear resistance. In one of the most studied processes that aims to overcome these drawbacks, Ti surfaces are often covered by anodic oxide films with the incorporation of bioactive agents such as Ca and P. Although there are several works on the tribocorrosion behaviour of MAO-treated Ti surfaces, the influence of electrolyte composition on the corrosion kinetics under sliding is yet to be fully understood. In the present work, anodic oxide films were produced on cp-Ti surfaces with different calcium acetate concentrations in the electrolyte. Tribocorrosion behaviour was investigated by reciprocating sliding tests performed in 8 g/L NaCl solution at body temperature, under potentiostatic conditions. The results showed that higher concentrations of calcium acetate had a detrimental effect on tribocorrosion kinetics, however, they resulted in less mechanical damage due to alterations in the topography and structure of the MAO layer.Article Citation - WoS: 18Citation - Scopus: 23On the Effect of Modified Carbohydrates on the Size and Shape of Gold and Silver Nanostructures(MDPI Multidisciplinary Digital Publishing Institute, 2020) Yazgan, İdris; Gümüş, Abdurrahman; Gökkuş, Kutalmış; Demir, Mehmet Ali; Evecen, Senanur; Sönmez, Hamide Ayçin; Toprak, Muhammet S.Gold (Au) and silver (Ag) nanostructures have widespread utilization from biomedicine to materials science. Therefore, their synthesis with control of their morphology and surface chemistry have been among the hot topics over the last decades. Here, we introduce a new approach relying on sugar derivatives that work as reducing, stabilizing, and capping agents in the synthesis of Au and Ag nanostructures. These sugar derivatives are utilized alone and as mixture, resulting in spherical, spheroid, trigonal, polygonic, and star-like morphologies. The synthesis approach was further tested in the presence of acetate and dimethylamine as size- and shape-directing agents. With the use of transmission electron microscopy (TEM), selected area electron diffraction (SAED), x-ray diffraction (XRD), scanning electron microscopy (SEM), and ultraviolet-visible (UV-vis) absorption spectroscopy techniques, the particle size, shape, assembly, aggregation, and film formation characteristics were evaluated. NPs' attributes were shown to be tunable by manipulating the sugar ligand selection and sugar ligand/metal-ion ratio. For instance, with an imine side group and changing the sugar moiety from cellobiose to lactose, the morphology of the Ag nanoparticles (NPs) transformed from well dispersed cubic to rough and aggregated. The introduction of acetate and dimethylamine further extended the growth pattern and morphological properties of these NPs. As examples, L5 AS, G5AS, and S5AS ligands formed spherical or sheet-like structures when used alone, which upon the use of these additives transformed into larger multicore and rough NPs, revealing their significant effect on the NP morphology. Selected samples were tested for their stability against protein corona formation and ionic strength, where a high chemical stability and resistance to protein coating were observed. The findings show a promising, benign approach for the synthesis of shape- and size-directed Au and Ag nanostructures, along with a selection of the chemistry of carbohydrate-derivatives that can open new windows for their applications.Article Citation - WoS: 30Citation - Scopus: 44A Review on Computational Modeling Tools for Mof-Based Mixed Matrix Membranes(MDPI Multidisciplinary Digital Publishing Institute, 2019) Keskin, Seda; Alsoy Altınkaya, SacideComputational modeling of membrane materials is a rapidly growing field to investigate the properties of membrane materials beyond the limits of experimental techniques and to complement the experimental membrane studies by providing insights at the atomic-level. In this study, we first reviewed the fundamental approaches employed to describe the gas permeability/selectivity trade-off of polymer membranes and then addressed the great promise of mixed matrix membranes (MMMs) to overcome this trade-off. We then reviewed the current approaches for predicting the gas permeation through MMMs and specifically focused on MMMs composed of metal organic frameworks (MOFs). Computational tools such as atomically-detailed molecular simulations that can predict the gas separation performances of MOF-based MMMs prior to experimental investigation have been reviewed and the new computational methods that can provide information about the compatibility between the MOF and the polymer of the MMM have been discussed. We finally addressed the opportunities and challenges of using computational studies to analyze the barriers that must be overcome to advance the application of MOF-based membranes.Article The Sustainability of an Urban Ritual in the Collective Memory: Bergama Kermesi(MDPI Multidisciplinary Digital Publishing Institute, 2019) İnceköse, ÜlküBergama Festival, locally known as Bergama Kermesi, is an annual festival which dates back to 22 May 1937 in the city. It came into existence as a result of Ataturk's intention to introduce this, an extraordinary town with its historical and cultural properties, and promote it internationally. The Festival is an important element in the collective memory of the city. Initially, it was a civic event, a device in the formation process of the Turkish Republic. However, now, it is a civil event for national and international representatives, and a festival that allows locals and guests from different social, economic, and cultural backgrounds to mix freely and equally for a certain period. In the course of the Festival, the public buildings and the open spaces of the town become places of activity and entertainment. Parks, stadiums, the town square, and streets function as spaces for a variety of activities. Looking back at its 81-year history, one can notice some important changes in the Festival's cultural and social practices, from an earlier state-dominated character into the current more publicly oriented one. This article studies the change of Bergama Festival as an invented tradition' into an element of the collective memory in town from the perspective of different public affairs that it introduces. In this regard, the article will also show how an urban ritual can maintain its sustainability by keeping itself fresh in the social life.Article Citation - WoS: 64Citation - Scopus: 109Irrigation of World Agricultural Lands: Evolution Through the Millennia(MDPI Multidisciplinary Digital Publishing Institute, 2020) Angelakis, Andreas N.; Zaccaria, Daniele; Krasilnikoff, Jens; Salgot, Miquel; Bazza, Mohamed; Roccaro, Paolo; Fereres, Elias; Baba, AlperMany agricultural production areas worldwide are characterized by high variability of water supply conditions, or simply lack of water, creating a dependence on irrigation since Neolithic times. The aim of this paper is to provide an overview of the evolution of irrigation of agricultural lands worldwide, based on bibliographical research focusing on ancient water management techniques and ingenious irrigation practices and their associated land management practices. In ancient Egypt, regular flooding by the Nile River meant that early agriculture probably consisted of planting seeds in soils that had been recently covered and fertilized with floodwater and silt deposits. On the other hand, in arid and semi-arid regions farmers made use of perennial springs and seasonal runoff under circumstances altogether different from the river civilizations of Mesopotamia, Egypt, India, and early dynasties in China. We review irrigation practices in all major irrigation regions through the centuries. Emphasis is given to the Bronze Age civilizations (Minoans, Egyptians, and Indus valley), pre-Columbian, civilizations from the historic times (e.g., Chinese, Hellenic, and Roman), late-Columbians (e.g., Aztecs and Incas) and Byzantines, as well as to Ottomans and Arabs. The implications and impacts of irrigation techniques on modern management of water resources, as well as on irrigated agriculture, are also considered and discussed. Finally, some current major agricultural water management challenges are outlined, concluding that ancient practices could be adapted to cope with present challenges in irrigated agriculture for increasing productivity and sustainability. © 2020 by the authors.Article Citation - WoS: 2Citation - Scopus: 3Can Tube Tunnel Crossings Relieve Urban Congestion Problems? Izmir Tube Tunnel Project Proposal Under Scrutiny(MDPI Multidisciplinary Digital Publishing Institute, 2019) Duvarcı, Yavuz; Yiğitcanlar, TanBuilding underwater tube tunnel crossings to ease the urban congestion problems has become a popular approach for many cities across the globe. London, New York, Istanbul, Hamburg, Sydney and Brisbane are among these cities. However, the effectiveness and externalities of these expensive mega urban infrastructures have also been questioned widely among urban, transport and environmental planning scholars. Given the international popularity of the topic, this study places a new tube tunnel crossings project from Izmir, Turkey under the microscope. In this heuristic simulation study, policy-on scenarios were tested to determine possible impacts of the underwater tube tunnel-crossing project. The traffic impacts are discussed using simulations assigning the initial origin-destination data. The results of the study revealed that, given the two locations, outer and inner locations over the dagger-shape bay, the capacity increments on the bridge links and the links around the periphery highway did not bring any effective solutions beyond some minor improvements. The findings disclosed that the ineffectiveness of the tube tunnel crossing might be due to the excessive congestion happening all over the downtown area, which clogs the passageways to the bridge. The paper highlights the limitations of the tube tunnel-crossing project, emphasises the need for comprehensive investigations before committing to the project and advocates the emphasis to be actually given for sustainable mobility.Article Citation - WoS: 54Citation - Scopus: 65Flood Hydrograph Prediction Using Machine Learning Methods(MDPI Multidisciplinary Digital Publishing Institute, 2018) Tayfur, Gökmen; Singh, Vijay P.; Moramarco, Tommaso; Barbetta, SilviaMachine learning (soft) methods have a wide range of applications in many disciplines, including hydrology. The first application of these methods in hydrology started in the 1990s and have since been extensively employed. Flood hydrograph prediction is important in hydrology and is generally done using linear or nonlinear Muskingum (NLM) methods or the numerical solutions of St. Venant (SV) flow equations or their simplified forms. However, soft computing methods are also utilized. This study discusses the application of the artificial neural network (ANN), the genetic algorithm (GA), the ant colony optimization (ACO), and the particle swarm optimization (PSO) methods for flood hydrograph predictions. Flow field data recorded on an equipped reach of Tiber River, central Italy, are used for training the ANN and to find the optimal values of the parameters of the rating curve method (RCM) by the GA, ACO, and PSO methods. Real hydrographs are satisfactorily predicted by the methods with an error in peak discharge and time to peak not exceeding, on average, 4% and 1%, respectively. In addition, the parameters of the Nonlinear Muskingum Model (NMM) are optimized by the same methods for flood routing in an artificial channel. Flood hydrographs generated by the NMM are compared against those obtained by the numerical solutions of the St. Venant equations. Results reveal that the machine learning models (ANN, GA, ACO, and PSO) are powerful tools and can be gainfully employed for flood hydrograph prediction. They use less and easily measurable data and have no significant parameter estimation problem.Article Citation - WoS: 5Citation - Scopus: 7Re-Arrangements in the Cytoplasmic Distribution of Small Rnas Following the Maternal-To Transition in Drosophila Embryos(MDPI Multidisciplinary Digital Publishing Institute, 2018) Coşacak, Mehmet İlyas; Yiğit, Hatice; Kızıl, Çağhan; Akgül, BünyaminSmall ribonucleic acids (RNAs) are known to regulate gene expression during early development. However, the dynamics of interaction between small RNAs and polysomes during this process is largely unknown. To investigate this phenomenon, 0-1 h and 7-8 h Drosophila melanogaster embryos were fractionated on sucrose density gradients into four fractions based on A254 reading (1) translationally inactive messenger ribonucleoprotein (mRNP), (2) 60S, (3) monosome, and (4) polysome. Comparative analysis of deep-sequencing reads from fractionated and un-fractionated 0-1 h and 7-8 h embryos revealed development-specific co-sedimentation pattern of small RNAs with the cellular translation machinery. Although most micro RNAs (miRNAs) did not have a specific preference for any state of the translational machinery, we detected fraction-specific enrichment of a few miRNAs such as dme-miR-1-3p, -184-3p, 5-5p and 263-5p. More interestingly, we observed changes in the subcellular location of a subset of miRNAs in fractionated embryos despite no measurable difference in their amount in unfractionated embryos. Transposon-derived endo small interfering RNAs (siRNAs) were over-expressed in 7-8 h embryos and associated mainly with the mRNP fraction. In contrast, transposon-derived PIWI-interacting RNAs (piRNA), which were more abundant in 0-1 h embryos, co-sedimented primarily with the polysome fractions. These results suggest that there appears to be a complex interplay among the small RNAs with respect to their polysome-cosedimentation pattern during early development in Drosophila melanogaster.Article Citation - WoS: 13Citation - Scopus: 13Differentially Expressed Trna-Derived Small Rnas Co-Sediment Primarily With Non-Polysomal Fractions in Drosophila(MDPI Multidisciplinary Digital Publishing Institute, 2017) Göktaş, Çağdaş; Yiğit, Hatice; Coşacak, Mehmet İlyas; Akgül, BünyaminRecent studies point to the existence of poorly characterized small regulatory RNAs generated from mRNAs, rRNAs and tRNAs. To explore the subcellular location of tRNA-derived small RNAs, 0–1 and 7–8 h Drosophila embryos were fractionated on sucrose density gradients. Analysis of 12,553,921 deep-sequencing reads from unfractionated and fractionated Drosophila embryos has revealed that tRFs, which are detected mainly from the 5’ends of tRNAs, co-sediment with the non-polysomal fractions. Interestingly, the expression levels of a subset of tRFs change temporally following thematernal-to-zygotic transition in embryos. We detected non-polysomal association of tRFs in S2 cells as well. Differential tRF expression pattern points to developmental significance at the organismal level. These results suggest that tRFs are associated primarily with the non-polysomal complexes in Drosophila embryos and S2 cells.Article Citation - WoS: 19Citation - Scopus: 20Transparent Pullulan/Mica Nanocomposite Coatings With Outstanding Oxygen Barrier Properties(MDPI Multidisciplinary Digital Publishing Institute, 2017) Uysal Ünalan, İlke; Boyacı, Derya; Trabattoni, Silvia; Tavazzi, Silvia; Farris, StefanoThis study presents a new bionanocomposite coating on poly(ethylene terephthalate) (PET) made of pullulan and synthetic mica. Mica nanolayers have a very high aspect ratio (α), at levels much greater than that of conventional exfoliated clay layers (e.g., montmorillonite). A very small amount of mica (0.02 wt %, which is φ ≈ 0.00008) in pullulan coatings dramatically improved the oxygen barrier performance of the nanocomposite films under dry conditions, however, this performance was partly lost as the environmental relative humidity (RH) increased. This outcome was explained in terms of the perturbation of the spatial ordering of mica sheets within the main pullulan phase, because of RH fluctuations. This was confirmed by modelling of the experimental oxygen transmission rate (OTR) data according to Cussler’s model. The presence of the synthetic nanobuilding block (NBB) led to a decrease in both static and kinetic coefficients of friction, compared with neat PET (≈12% and 23%, respectively) and PET coated with unloaded pullulan (≈26% reduction in both coefficients). In spite of the presence of the filler, all of the coating formulations did not significantly impair the overall optical properties of the final material, which exhibited haze values below 3% and transmittance above 85%. The only exception to this was represented by the formulation with the highest loading of mica (1.5 wt %, which is φ ≈ 0.01). These findings revealed, for the first time, the potential of the NBB mica to produce nanocomposite coatings in combination with biopolymers for the generation of new functional features, such as transparent high oxygen barrier materials.