Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 5Citation - Scopus: 7Bleach-Containing Automatic Toilet-Bowl Cleaners as Sources of Vocs, Associated Indoor Air Concentrations and Carcinogenic Risk(Turkish National Committee for Air Pollution Research (TUNCAP), 2020) Ayrı, İlknur; Genişoğlu, Mesut; Gaygısız, Handan; Sofuoğlu, Aysun; Sofuoğlu, Sait CemilHousehold cleaning products are sources of volatile organic compounds (VOCs). Bleach containing products are a special case because reactions occur between chloride and their organic content such as surfactants, perfumes, etc., generating VOCs. This study aimed to determine concentration of 13 VOCs in bleach-containing automatic toilet cleaners, to estimate their indoor air concentrations and associated exposure and health risk levels. Experiments with products purchased from supermarkets were conducted in 20-mL headspace vials by placing 1 g of sample with and without water. Solid-phase micro extraction with a DVB/CAR/PDMS fiber assembly was used for adsorption of VOCs from the headspace, and analyzed using a GC-MS. The median carbon tetrachloride and chloroform concentrations of the studied products ranged from 5.03 × 10?3 to 2.37 × 10?2 ?g/g and 2.53 × 10?2 to 2.37 ?g/g, respectively. The modeled 95th percentile indoor air concentrations in a 1.6 m3 bathroom with no ventilation were estimated to be 1 and 20 ?g/m3 for carbon tetrachloride and chloroform, respectively. The 95th percentile carcinogenic risk associated even with the use of the highest content product, 3.72 × 10?7 and 8.62 × 10?7 for carbon tetrachloride and chloroform respectively, were below the acceptable risk. In conclusion, automatic toilet-bowl cleaners were found to be sources of VOCs, but their emission potentials are not high to cause considerable indoor air concentrations over their suggested product lifetime. In turn, carcinogenic risks associated with inhalation exposure are below the de Minimis risk level of 10?6. © 2020Article Citation - WoS: 21Citation - Scopus: 26Indoor Environmental Quality in Chemistry and Chemical Engineering Laboratories at Izmir Institute of Technology(Turkish National Committee for Air Pollution Research (TUNCAP), 2015) Ugranlı, Tuğba; Toprak, Melis; Gürsoy, Gül; Çimrin, Arif H.; Sofuoğlu, Sait CemilIndoor air pollution in university research laboratories may be important to building occupants, especially for those who work in the laboratories. In this study, indoor air quality (IAQ) and indoor environmental comfort were investigated in research laboratories of two departments at a university. PM2.5, PM10, TVOC (total volatile organic compounds), and CO concentrations, and three comfort variables which are temperature, relative humidity, and CO2 were measured. PM2.5 concentration was determined gravimetrically by collecting particles on glass fiber filters, whereas the remaining pollutants and comfort variables were measured using a monitoring device. IAQ measurements showed that levels of all pollutants were under the limits in both of the departments except for TVOC in one laboratory which had a mean concentration of 182 ppb. The comfort variables were in the comfort ranges for laboratories in both of the departments except for temperature in one laboratory with a mean value of 30 °C. In conclusion, measures are needed for extensive uses of organic solvents because ventilation may not be sufficient to keep VOC concentrations within the limits, and to provide thermal comfort.
