Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 2Citation - Scopus: 2Incorporation of CuWO4 With Hollow Tubular g-C3N4: Harnessing the Potential in Photocatalytic Degradation, Hydrogen Production, and Supercapacitor Applications(Pergamon-Elsevier Science Ltd, 2026) Erdem, Nurseli Gorener; Caglar, Basar; Inan, Ece; Tuna, Ozlem; Ertis, Irem Firtina; Simsek, Esra BilginDriven by the urgent need for sustainable energy conversion and environmental remediation technologies, the development of multifunctional materials has gained growing interest. Herein, a bifunctional heterostructure was fabricated by depositing copper tungstate (CuWO4) spherical particles over hollow tubular graphitic carbon nitride (HTCN) using an ultrasonic-assisted thermal impregnation method. The photocatalytic activities were evaluated through tetracycline degradation and hydrogen evolution tests, while electrochemical measurements were conducted to assess the supercapacitor performance. CuWO4@HTCN composite achieved up to 83% degradation efficiency, a hydrogen evolution rate of 2538 mu mol g1 h-1, and a specific capacitance of 212 F g1, demonstrating its strong potential as a multifunctional material for solar-driven environmental and energy storage applications. The enhanced photocatalytic performance was attributed to extended visible light absorption ability, efficient charge separation, and suppressed electron-hole recombination resulting from the formation of a Z-scheme heterojunction. Furthermore, the superior capacitance behavior was ascribed to enhanced electrical conductivity and ion transport, enabled by the porous, nitrogen-rich HTCN structure. The increased HTCN content in the composite improved pore accessibility and active site availability while an excessive amount of CuWO4 reduced electrochemical performance. These results highlight the multifunctional applicability of CuWO4@HTCN composite in photocatalytic hydrogen production and supercapacitor systems, emphasizing their relevance for renewable energy technologies.Article Citation - WoS: 1Citation - Scopus: 1Design and Comprehensive Analysis of a Solar-Biomass Hybrid System With Hydrogen Production and Storage: Towards Self-Sufficient Wastewater Treatment Plants(Pergamon-Elsevier Science Ltd, 2025) Tabriz, Zahra Hajimohammadi; Kasaeian, Alibakhsh; Mohammadpourfard, Mousa; Shariaty-Niassar, MojtabaThis paper comprehensively investigates a novel solar-biomass hybrid system designed to produce power, heating, hydrogen, methane, and digestate. The system's design is grounded in regional weather patterns and site-specific resource availability. A comprehensive thermodynamic and exergoeconomic analysis, based on the first and second laws of thermodynamics, is performed alongside parametric studies to evaluate the influence of key parameters on system performance. Multi-objective optimization employs a genetic algorithm facilitated by an artificial neural network to reduce computational time and balance exergy efficiency and total cost. The Pareto front is generated, and the TOPSIS method is employed to identify the optimal trade-off point. The system integrates an auxiliary boiler powered by stored hydrogen and methane to maintain consistent operation during periods of low solar irradiance. Key findings include a base-case overall energy efficiency of 78.67 % and exergy efficiency of 60.41 %. The base-case unit cost of hydrogen is determined to be $3.174/kg, demonstrating competitive viability. Integrating the biomass subsystem with the solar plant resulted in a 40 % increase in exergy efficiency and a 35 % improvement in the total unit cost of products compared to a stand-alone solar system. Optimized system parameters yielded an exergy efficiency of 55.52 % and a total cost rate of 14.98 M $/year. These results confirm the potential of this hybrid system as a promising sustainable solution for developing self-sufficient wastewater treatment plants.Article Citation - WoS: 6Citation - Scopus: 6A New Electro-Biomembrane Integrated Renewable-Based System To Produce Power, Fresh Water and Hydrogen for Sustainable Communities(Elsevier, 2025) Goren, A. Yagmur; Dincer, Ibrahim; Khalvati, AliAs the consequences of global warming become more severe, it is more crucial than ever to capitalize on all locally accessible potential renewable energy sources and produce sufficient useable energy outputs to meet community demands while causing the least damage to the ecosystem. Therefore, this paper focuses on a unique parabolic trough collector solar system-powered electro-biomembrane unit that combines a heat and power system with fresh water, electricity and hydrogen production. The proposed integrated system contains the following subsystems: a combining parabolic trough collector solar system, an organic Rankine cycle, a steam Rankine cycle, a multi-stage flash desalination system, and an electro-biomembrane H2 and freshwater production system. A thorough analysis and parametric research are performed on the multigeneration system to determine how important characteristics affect system performance and evaluate the energy and exergy efficiencies, and exergy destruction levels for particular system elements. The study results show that solar irradiation is the most critical parameter for improving system performance. The highest freshwater production of 1,303,333.3 L/day is observed at the solar irradiation of 935,768 kWh/day. Furthermore, the combined output of three electricity production technologies exceeds 2,000,000 kWh/day, highlighting the ability of the system to harness solar thermal energy effectively. The study findings indicate that using solar power and biomass as renewable energy sources, the proposed integrated system provided 328.56 kg of biohydrogen per day. Overall, the energy and exergy efficiencies of the integrated system are obtained as 34.3 and 29.5 %, respectively.Article Citation - WoS: 3Citation - Scopus: 4Towards Renewable Energy Islands in Türkiye: Potential and Challenges(Pergamon-elsevier Science Ltd, 2025) Karipoglu, Fatih; Denizli, OsmancanThe necessity of renewables is increasing day by day due to increasing energy demand. Therefore, novel approaches and methods for producing electricity in an environmentally friendly manner are valuable and critical. The seas have enormous potential in terms of wind, waves, solar, and hydrogen systems. The study presents the investigation of the potential dynamics for energy island formation on T & uuml;rkiye borders. Also, targets, legislation, and environmental and social concerns are discussed comprehensively. Results show that offshore wind and hydrogen are promising systems shortly while solar and wave energy needs more research for T & uuml;rkiye. The Marmara and Aegean Seas are considered technically feasible for offshore wind installations, while the Mediterranean and Aegean Seas have the highest technical solar potential. In addition, the highest wave power is detected along the line from I(center dot)zmir to Antalya Coast while hydrogen energy systems receive great interest with academic and industrial projects in the Marmara Coastline. Profiting from marine energy, marine spatial planning, and grid availability are detected as the shortcoming issues in T & uuml;rkiye. The study could give critical information to energy planners, and decision makers for potential projects.Article Citation - WoS: 16Citation - Scopus: 17Integrating Experimental and Machine Learning Approaches for Predictive Analysis of Photocatalytic Hydrogen Evolution Using Cu/G-c3n4(Pergamon-elsevier Science Ltd, 2024) Arabaci, Bahriyenur; Bakir, Rezan; Orak, Ceren; Yuksel, AsliThis study addresses environmental issues like global warming and wastewater generation by exploring waste-toenergy strategies that produce renewable hydrogen and treat wastewater simultaneously. Cu/g-C3N4 is used to evolve hydrogen from sucrose solution and the impact of reaction parameters such as pH (3, 5, and 7), Cu loading (5, 10, and 15 wt%), catalyst amount (0.1, 0.2, and 0.3 g/L), and oxidant (H2O2) concentration (0, 10, and 20 mM) on the evolved hydrogen amount is examined. Characterization study confirmed successful incorporation of Cu without significantly altering g-C3N4 properties. The highest hydrogen production (1979.25 mu mol g- 1 & sdot;h- 1) is achieved with 0.3 g/L catalyst, 20 mM H2O2, 5 % Cu loading, and pH 3. The experimental study concludes that Cu/g-C3N4 is an effective photocatalyst for renewable hydrogen production. In addition to the experimental investigations, various machine learning (ML) models, including Random Forest, Decision Tree, XGBoost, among others, are employed to analyze the impact of reaction parameters and forecast the quantities of produced hydrogen. Alongside these individual models, an ensemble approach is proposed and utilized. The R2 values of these ML models ranged from 0.9454 to 0.9955, indicating strong predictive performance across the board. Additionally, these models exhibited low error rates, further confirming their reliability in predicting hydrogen evolution.Article Citation - WoS: 52Citation - Scopus: 57Optimizing Hydrogen Evolution Prediction: a Unified Approach Using Random Forests, Lightgbm, and Bagging Regressor Ensemble Model(Elsevier Ltd, 2024) Bakır,R.; Orak,C.; Yüksel,A.Hydrogen, as a clean and versatile energy carrier, plays a pivotal role in addressing global energy challenges and transitioning towards sustainable energy systems. This study explores the convergence of machine learning (ML) for photocatalytic hydrogen evolution from sucrose solution using perovskite-type catalysts, namely LaFeO3 (LFO) and graphene-supported LaFeO3 (GLFO). This study pioneers the practical application of ML techniques, including Random Forests, LightGBM, and Bagging Regressor, to predict hydrogen yields in the presence of these photocatalysts. LFO and GLFO underwent a thorough characterization study to validate their successful preparation. Noteworthy, the highest hydrogen yield from the sucrose model solution was achieved using GLFO as 3.52 mmol/gcat. The optimum reaction conditions were experimentally found to be pH = 5.25, 0.15 g/L of catalyst amount, and 7.5 mM of HPC (hydrogen peroxide concentration). A pivotal contribution of this research lies in the practical application of ML models, culminating in the development of an ensemble model. This collaborative approach not only achieved an overall R2 of 0.92 but also demonstrated exceptional precision, as reflected in remarkably low error metrics. The mean squared logarithmic error (MSLE) was 0.0032, and the mean absolute error (MAE) was 0.049, underscoring the effectiveness of integrating diverse ML algorithms. This study advances both the understanding of photocatalytic hydrogen evolution and the practical implementation of ML in predicting intricate chemical reactions. © 2024 Hydrogen Energy Publications LLCArticle Citation - WoS: 14Citation - Scopus: 17Cleaner Production of Biohydrogen Using Poplar Leaves: Experimental and Optimization Studies(Elsevier Sci Ltd, 2024) Goren, A. Yagmur; Kenez, Muratcan; Dincer, Ibrahim; Khalvati, AliBiohydrogen (bioH2) is recognized as a potential carbon-neutral energy vector, and developing novel methods has received increasing attention with a prime goal of producing H2 more efficient and cost effective manner. This study aimed to develop a unique reactor to investigate dark fermentative H2 production from poplar biomass using commercially available and inexpensive microorganism cultures. Therefore, six factors of the Box-Behnken design (BBD) were performed to evaluate the individual and combined effects of operational param-eters: acid concentration (2-10%), biomass concentration (2-10 g), initial pH (5-8), temperature (30-40 degrees C), mixing ratio (150-350 rpm), and microorganism concentration (2-6 g) on bioH2 production. Among the oper-ational parameters, the acid concentration was the most effective parameter on bioH2 production. The bioH2 production increased from 11.33 to 18.15 mg/g biomass with increasing acid concentration from 6 to 10%. Moreover, the optimum levels of operational variables were as follows: acid concentration of 9.9%, biomass amount of 2 g, pH of 6.56, temperature of 35 degrees C, mixing ratio of 345 rpm, and microorganism amount of 4.5 g for the highest bioH2 production of 20 mg/g-biomass according to the experimental design. Consequently, the bioH2 production performance of the dark fermentation process showed that bioH2 production from poplar biomass using commercially available microorganisms had a competitive advantage.Article Citation - WoS: 49Citation - Scopus: 51Energy, Exergy, Exergoeconomic, and Exergoenvironmental (4e) Analysis of a New Bio-Waste Driven Multigeneration System for Power, Heating, Hydrogen, and Freshwater Production: Modeling and a Case Study in Izmir(Elsevier, 2023) Tabriz, Zahra Hajimohammadi; Mohammadpourfard, Mousa; Gökçen Akkurt, Gülden; Heris, Saeed ZeinaliToday, the world is facing numerous challenges such as the increasing demand for energy, fossil fuels reduction, the growth of atmospheric pollutants, and the water crisis. In the present research, a new multigeneration system based on urban sewage bio-waste has been designed and evaluated for power, hydrogen, freshwater, and heating production. This system, which consists of biomass conversion subsystem, hydrogen production unit, Brayton cycle, atmospheric water harvesting unit, steam Rankine cycle, and organic Rankine cycles, has been evaluated from a thermodynamic point of view, and the energy, exergy, exergoeconomic, and exergoenvironmental analyses have been carried out on it. In the current study, the atmospheric water harvesting unit, as an attractive and environmentally friendly technology, is integrated with this Biomass-based multigeneration. A case study has been conducted on this system using the information collected from cigli wastewater treatment plant located In Izmir province, Turkey, and the results indicate that such a system, in addition to receiving sewage sludge from the treatment plant unit as a polluting waste, can produce added value products. The modeling results show that in the base conditions and with a feed rate of 7.52 kg/s, the total power generated by this system is 17750 kW, the hydrogen production rate is 3180 kg/h, the freshwater production rate is more than 18 l/h, and the energy and exergy efficiencies are 35.48% and 40.18%, respectively. According to the exergoeconomic and exergoenvironmental evaluations, the unit cost of total products and the unit emission of carbon dioxide are calculated as 13.05 $/GJ and 0.2327 t/MWh, respectively. Also, the results of parametric studies show that increasing the rate of Biomass improves the overall energy efficiency and production rates and also reduces the unit emission of carbon dioxide, but on the other hand, it causes a decrease in exergy efficiency and an increase in the unit cost of total products.Article Citation - WoS: 11Citation - Scopus: 12Box-Behnken Design for Hydrogen Evolution From Sugar Industry Wastewater Using Solar-Driven Hybrid Catalysts(American Chemical Society, 2022) Orak, Ceren; Yüksel, AslıHydrogen is a clean and green fuel and can be produced from renewable sources via photocatalysis. Solar-driven hybrid catalysts were synthesized and characterized (scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), photoluminescence (PL) spectroscopy, and UV-vis diffuse reflectance spectroscopy (DSR)), and the results implied that graphene-supported LaRuO3is a more promising photocatalyst to produce hydrogen and was used to produce hydrogen from sugar industry wastewater. To investigate the main and interaction effects of reaction parameters (pH, catalyst amount, and [H2O2]0) on the evolved hydrogen amount, the Box-Behnken experimental design model was used. The highest hydrogen evolution obtained was 6773 μmol/gcatfrom sugar industry wastewater at pH 3, 0.15 g/L GLRO, and 15 mM H2O2. Based on the Pareto chart for the evolved hydrogen amount using GLRO, among the main effects, the only effective parameter was the catalyst amount for the photocatalytic hydrogen evolution from sugar industry wastewater. In addition, the squares of pH and two-way interaction of pH and [H2O2]0were also statistically efficient over the evolved hydrogen amount.Article Citation - WoS: 13Citation - Scopus: 12Comparison of Photocatalytic Performances of Solar-Driven Hybrid Catalysts for Hydrogen Energy Evolution From 1,8–diazabicyclo[5.4.0]undec-7 (dbu) Solution(Elsevier, 2022) Orak, Ceren; Yüksel, AslıHydrogen is evolved from 1,8–Diazabicyclo [5.4.0]undec-7-ene (DBU) model solution which is a nitrogen-containing heterocyclic organic compound using different solar-driven hybrid photocatalysts. A characterization study is performed and the results of PL analysis show that the most promising solar-driven hybrid catalyst is graphene supported LaFeO3. Then, an experimental design matrix is built using the Box Behnken model to main and interaction effects of reaction parameters (pH, catalyst loading, and [H2O2]0). Based on the experimental results relatively higher hydrogen amounts are achieved using GLFO and this finding is supported by PL analysis. The highest hydrogen amount and DBU removal are determined as 3058.31 μmol/gcat and 90.3%, respectively. Statistical analysis shows that the square of catalyst loading is the only effective parameter over the produced hydrogen amount from the DBU model solution using GLFO and the R2 of model is 92.47%. Thus, hydrogen production and wastewater treatment could be achieved via photocatalytic oxidation as concomitant.