Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 4Citation - Scopus: 4A Cyclopalladated Bodipy Construct as a Fluorescent Probe for Carbon Monoxide(Wiley, 2022) Çevik Eren, Merve; Eren, Ahmet; Dartar, Suay; Tütüncü, Büşra Buse; Emrullahoğlu, MustafaBy introducing a palladium ion into the backbone of BODIPY, we devised a cyclopalladated BODIPY construct that was almost non-emissive in the absence of any analyte but became highly fluorescent upon interacting with carbon monoxide (CO) in solution and in living cells. A process of ortho-carbonylation and depalladation mediated by the specific binding of CO to palladium, promoted the release of the heavy atom from the fluorophore and consequently generated a fluorescence signal with an exceptionally high (60-fold) enhancement ratio.Article Citation - WoS: 22Citation - Scopus: 25A Bodipy/Pyridine Conjugate for Reversible Fluorescence Detection of Gold(iii) Ions(Royal Society of Chemistry, 2015) Üçüncü, Muhammed; Karakuş, Erman; Emrullahoğlu, MustafaWe designed a "turn-on" type fluorescent probe based on a BODIPY-pyridine conjugate which exhibits high selectivity towards Au(iii) ions and, also responds to changes in the pH within the acidic pH range. The probe offers features such as a rapid response time, a low detection limit, and high sensitivity and selectivity. The detection of Au(iii) is recognized by a distinct change in the emission intensity which relies on a reversible "ligand to ion" binding mechanism. We also document the utility of the probe for the quantification of gold ion residues in synthetic end products prepared via gold catalysis. © 2015 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.