Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 15Citation - Scopus: 17Effect of Substrate Rotation Speed and Off-Center Deposition on the Structural, Optical, and Electrical Properties of Azo Thin Films Fabricated by Dc Magnetron Sputtering(American Institute of Physics, 2018) Aygün, Gülnur; Aygün, Gülnur; Köseoğlu, Hasan; Özdemir, Mehtap; Özdemir, Mehtap; Özyüzer, Lütfi; Özyüzer, Lütfi; Özyüzer, Gülnur Aygün; Özyüzer, Lütfi; 04.05. Department of Pyhsics; 04. Faculty of Science; 01. Izmir Institute of TechnologyIn this study, aluminum-doped zinc oxide (AZO) thin films were deposited by DC magnetron sputtering at room temperature. The distance between the substrate and target axis, and substrate rotation speed were varied to get high quality AZO thin films. The influences of these deposition parameters on the structural, optical, and electrical properties of the fabricated films were investigated by X-ray diffraction (XRD), Raman spectroscopy, spectrophotometry, and four-point probe techniques. The overall analysis revealed that both sample position and substrate rotation speed are effective in changing the optical, structural, and electrical properties of the AZO thin films. We further observed that stress in the films can be significantly reduced by off-center deposition and rotating the sample holder during the deposition. An average transmittance above 85% in the visible range and a resistivity of 2.02 × 10-3Ω cm were obtained for the AZO films.Conference Object Determination of Aluminum Rolling Oil and Machinery Oil Residues on Finished Aluminum Sheet and Foil Using Elemental Analysis and Fourier Transform Infrared Spectroscopy Coupled With Multivariate Calibration(John Wiley and Sons Inc., 2014) İnanç Uçar, Özlem; Özdemir, Durmuş; Günyüz, Mert; Dündar, Mustafa Murat; Özdemir, Durmuş; 04.01. Department of Chemistry; 04. Faculty of Science; 01. Izmir Institute of TechnologyThe surface characteristics of rolled aluminum products such as sheets and foils are strongly affected by the particular rolling process and the type of aluminum rolling oil compositions. After the rolling process, coiled aluminum sheets and foils undergoes annealing to form desired crystal structure and remove the rolling oil residues. Depending on the time and the temperature that rolled aluminum exposed for annealing, rolling oil residues are mostly removed from the coiled aluminum products but if there is any contamination in rolling oil due to hydraulic and gearing parts of the rolling systems these heavier oils are not easily evaporates from the aluminum surfaces especially inner parts of the coiled aluminum sheets and foils. These rolling oil contaminants create serious problems for the some specific applications of these aluminum products in certain industries such as automotive and coating as remaining thin oil layer prevents proper painting and coating. Therefore, it is very crucial for the rolling industry to be able to monitor the heavy oil contamination on the rolled products and determine the source of these contaminants .In this study, it was aimed to develop a nondestructive infrared spectroscopic method combined with chemometric multivariate calibration techniques for the quantitative determination of rolling oil residues and contaminants on the rolled aluminum products. To be able to generate multivariate calibration methods, an industrial elemental analysis system was adopted for the quantitative determination of heavy oil contaminants on the rolled aluminum products and these were used as reference values for infrared analysis of the same samples. In addition, apart from conventional use of elemental analysis systems for the total organic analysis, the raw data (raw chromatogram) obtained from elemental analysis was used to directly generate multivariate calibration models for each contaminant by using synthetically contaminated surfaces as the calibration samples. The results promised that elemental analysis can be used not just for the total organic content but also specifically to determine amount of each contaminant on the aluminum surfaces, it is also, expected that infrared spectroscopy with grazing angle spectra collection accessories can be used for nondestructive analysis of these contaminants.s.
