Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 1Citation - Scopus: 2Lacoo3 Is a Promising Catalyst for the Dry Reforming of Benzene Used as a Surrogate of Biomass Tar(Tubitak Scientific & Technological Research Council Turkey, 2024) Çağlar, Başar; Üner, DenizTar build-up is one of the bottlenecks of biomass gasification processes. Dry reforming of tar is an alternative solution if the oxygen chemical potential on the catalyst surface is at a sufficient level. For this purpose, an oxygen-donor perovskite, $LaCoO_3$, was used as a catalyst for the dry reforming of tar. To circumvent the complexity of the tar and its constituents, the benzene molecule was chosen as a model compound. Dry reforming of benzene vapor on the $LaCoO_3$ catalyst was investigated at temperatures of 600, 700, and 800 °C; at $CO_2/C_6H_6$ ratios of 3, 6, and 12; and at space velocities of 14,000 and 28,000 h–1. The conventional Ni(15 wt.%)/$Al_2O_3$ catalyst was also used as a reference material to determine the relative activity of the $LaCoO_3$ catalyst. Different characterization techniques such as X-ray diffraction, $N_2$ adsorption-desorption, temperature-programmed reduction, and oxidation were used to determine the physicochemical characteristics of the catalysts. The findings demonstrated that the $LaCoO_3$ catalyst has higher $CO_2$ conversion, higher $H_2$ and CO yields, and better stability than the Ni(15 wt.%)/γ-$Al_2O_3$ catalyst. The improvement in activity was attributed to the strong capacity of $LaCoO_3$ for oxygen exchange. The transfer of lattice oxygen from the surface of the $LaCoO_3$ catalyst facilitates the oxidation of carbon and other surface species and leads to higher conversion and yields.Article Citation - WoS: 22Citation - Scopus: 22Multiparameter-Based Product, Energy and Exergy Optimizations for Biomass Gasification(Elsevier, 2021) Çağlar, Başar; Tavşancı, Duygu; Bıyık, EmrahThe thermodynamic modelling of biomass gasification was studied by using Gibbs free energy minimization approach. Different from the studies using the same approach, the simultaneous presence of all gasifying agents (air, H2O and CO2) was considered and a multiparameter optimization was applied to determine the synergetic effect of gasifying agents for hydrogen, syngas with a specific H2/CO ratio and methane production. The performance of gasification was assessed by using technical and environmental performance indicators such as product yields, cold gas efficiency, exergy efficiency, CO2 emission and the heat requirement of the gasifier. The results show that the simultaneous presence of gasifying agents does not create considerable changes in syngas yield, H2 yield, methane yield, CGE and exergy efficiency while it allows to tune the H2/CO ratio and the heat requirement of the gasifier. The highest syngas yield is observed at T > 1100 K and 1 bar and when SBR > 0.5 and/or CBR > 0.8 with the absence of air, at which CGE changes between 114% and 122% while exergy efficiency is between 77% and 86%. The results prove that CO2 offers several advantages as a gasifying agent and suggests that CO2 recycling from gasifier outlet is a useful option for the biomass gasification.