Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - Scopus: 7Modification of Grape Pulp With Citric Acid for the Production of Natural Ion Exchanger Resin and Removal of Pb (ii) and Cd (ii) From Aqueous Solutions: Kinetic, Thermodynamics, and Mechanism(Springer Science and Business Media Deutschland GmbH, 2023) Eren, Muhammet Şakir Abdullah; Eren, M.Ş.A.; Arslanoğlu, H.; Çiftçi, H.; 01. Izmir Institute of Technology; 04.03. Department of Molecular Biology and Genetics; 04. Faculty of ScienceIn this study, grape pulp (MGP) modified with NaOH and citric acid was used in the production of natural ion exchangers. The effects of parameters such as initial pH, MGP dosage, temperature, initial metal ion concentration, and contact time on the removal of Pb (II) and Cd (II) ions from aqueous solutions using modified materials were investigated by batch experiments. It was found that the experimental kinetic data fit the second-order model, and the activation energy for Pb (II) and Cd (II) adsorption processes were 20.68 and 38.61 kj mol−1, respectively. Although the initial adsorption rate increases with increasing temperature, the adsorption efficiency slightly decreases. It was calculated that the equilibrium data fit the Langmuir isotherm better, and the maximum adsorption capacities for Pb (II) and Cd (II) adsorption processes were approximately 1.496 and 1.022 mmol g−1 at 25 °C, respectively. Thermodynamic analysis has shown that the adsorption processes of Pb (II) and Cd (II) are exothermic (ΔH°Pb = −35.68 kj mol−1, ΔH°Cd = −21.19 kj mol−1) and have a self-developing character. Graphical abstract: [Figure not available: see fulltext.]. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.Article Citation - WoS: 1Citation - Scopus: 1Investigating Triple Superphosphate for Lead Removal From Aqueous Solutions(Taylor & Francis, 2022) Souley Garba, Mahamane Chapiou; Gökelma, Mertol; Gökelma, Mertol; Seyrankaya, Abdullah; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyThe aim of this research is to investigate monocalcium phosphate monohydrate [Ca(H2PO4)2. H2O] also called triple superphosphate (TSP) for the removal of lead (Pb) from aqueous solutions. In this study, TSP was selected amongst various phosphate-based materials and fertilizers to act as the source of orthophosphate (PO43-) which is a powerful tool for metal fixation in soil and water. Thermodynamic equilibrium dissolution-precipitation relationships for the systems of Pb-H2O and Pb-PO43--H2O were drawn with the aid of Eh-pH stability diagrams to determine the predominance areas of different species. The lead phosphate compounds, identified through the stability area diagrams, were verified with the batch precipitation tests performed with standard solutions of lead and TSP at different conditions. It was observed that, depending upon solution conditions, TSP can precipitate 99.9% of the lead from the solution. Lead precipitates, analyzed by x-ray diffraction, showed the formation of lead phosphate compounds. The mechanism of TSP for the removal of lead from aqueous solutions is discussed.Article Citation - WoS: 37Citation - Scopus: 39Polymer-Derived Ceramic Adsorbent for Pollutant Removal From Water(John Wiley and Sons Inc., 2018) Zeydanlı, Damla; Ahmetoğlu, Çekdar Vakıf; Ahmetoğlu, Çekdar Vakıf; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 01. Izmir Institute of TechnologyPolymer-derived ceramic components (SiOC, sample W) were produced from preceramic polymer mixture and a catalyst. After curing and pyrolysis, some of the samples etched by hydrofluoric acid to obtain carbonaceous SiOC (C-rich SiOC, sample W-HF). W and W-HF were tested as an adsorbent material to remove both heavy-metal ions (Cr (III), Pb (III), and Cd (II)) and cationic dyes (Methylene Blue (MB), Rhodamine B (RB), and Crystal Violet (CV)) from aqueous solutions. HF-treated high surface area SiOC samples had quite high adsorption affinity for cationic dyes. According the Langmuir isotherm model the maximum dye uptake values were found to be around to 50 mg/g for sample W, whereas those for sample W-HF ranged from 104 to 186 mg/g. Regeneration studies were conducted both by heat treatment and leaching, high recovery yields (always above 97%) of MB adsorption were obtained.Article Citation - WoS: 70Citation - Scopus: 82Sorption Efficiency of Chitosan Nanofibers Toward Metal Ions at Low Concentrations(American Chemical Society, 2010) Horzum Polat, Nesrin; Boyacı, Ezel; Shahwan, Talal; Shahwan, Talal; Demir, Mustafa Muammer; Demir, Mustafa Muammer; Eroğlu, Ahmet Emin; 04.01. Department of Chemistry; 03.09. Department of Materials Science and Engineering; 03. Faculty of Engineering; 04. Faculty of Science; 01. Izmir Institute of TechnologyChitosan fibers showing narrow diameter distribution with a mean of 42 nm were produced by electrospinning and utilized for the sorption of Fe(III), Cu(II), Ag(I), and Cd(II) ions from aqueous solutions. The ion concentrations in the supernatant solutions were determined using inductively coupled plasma-mass spectrometry (ICP-MS). The filtration efficiency of the fibers toward these ions was studied by both batch and microcolumn methods. High efficiency in sorption of the metal ions was obtained in the both methods. The effects of sorbent amount (0.10−0.50 mg), shaking time (15−120 min), initial metal ion concentration (10.0−1000.0 μg·L−1), and temperature (25 and 50 °C) on the extent of sorption were examined. The sorbent amount did not significantly alter the efficiency of sorption; however, shaking time, temperature, and metal ion concentration were found to have a strong influence on sorption. By virtue of its mechanical integrity, the applicability of the chitosan mat in solid phase extraction under continuous flow looks promising.