Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Subject: search.filters.subject.Metal-Organic Frameworks

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  • Article
    Silver-Loaded Titania-Based Metal-Organic Frameworks as a Platform for Silver Ion Release for Antibacterial Applications
    (American Chemical Society, 2025) Mazare, Anca; Goldmann, Wolfgang Heinrich; Kocak, Esra; Osuagwu, Benedict; Qin, Shanshan; Cao, Ran; Schmuki, Patrik; 01. Izmir Institute of Technology
    Conventional Ag-decorated TiO<inf>2</inf>coatings suffer from low adsorption capacity and burst release kinetics, limiting long-term antibacterial efficacy and risking cytotoxicity. An entirely different payload release approach can be based on metal–organic frameworks (MOFs), which offer tunable porosity, high surface area, and internal diffusion channels. Here, we report a thermally stabilized Ti-based MOF [NH<inf>2</inf>-MIL-125(Ti)] functionalized with Ag+via reactive deposition, enabling high Ag loading (∼14.7 wt %) and sustained release. Annealing at 250 °C enhances aqueous stability, allowing diffusion-governed Ag+delivery over >48 h, with 77% of the Ag still present in the MOF after a 24 h release. The system exhibits dose-dependent antibacterial activity in powders and comparable efficacy in coatings, with a more gradual release profile. This scalable platform is promising for long-acting coatings, wound interfaces, and implantable materials. © 2025 Elsevier B.V., All rights reserved.
  • Article
    Citation - WoS: 10
    Citation - Scopus: 12
    Bimetallic Mof@cds Nanorod Composite for Highly Efficient Piezo-Photocatalytic Co2 Methanation Under Visible Light
    (Elsevier Sci Ltd, 2024) Mohammadpourfard, Mousa; Asgharizadeh, Kimia; Jalili, Hadi; Nejatbakhsh, Siyamak; Azimi, Babak; Aghdasinia, Hassan; Mohammadpourfard, Mousa; 03.06. Department of Energy Systems Engineering; 03. Faculty of Engineering; 01. Izmir Institute of Technology
    CO2 methanation is leading progress in both dwindling the emitted greenhouse gas and taking advantage of CO2 conversion to a worthwhile fuel. Various types of catalysts have gained researchers' attention. On the other hand, those catalysts chiefly suffer from being uneconomical, owning laborious processes, and having low efficiency. Particularly in the photocatalytic process, electron-hole recombination, charge separation efficiency, and the photocorrosion are the most remarkable obstacles in the path of gaining high efficiency. To conquer the aforementioned hindrances, Cu/Zr-MOF@CdS had been designed in order to not only do elevate CH4 selectivity but also increase CO2 conversion by altering the electron transfer mechanism. Doping Cu in Zr-MOF structure restrains C-C coupling and ameliorates the viability of protonation of *CO to *HCO during methane production. CdS and Zr-MOF both grant piezoelectricity trait to the catalyst in a way that by merging it with the photocatalytic process the mechanism of process converted from type (II) scheme to Z-scheme, culminating in thwarting recombination and increase of charge separation efficiency. The photocatalytic process achieved 23.6 mu mol. g- 1. h- 1 CH4 reaction rate and 80 % CO2 conversion, hereafter applying the piezo-photocatalytic process, these two factors reached 52.2 mu mol. g- 1. h- 1 and 99 %, respectively. This work unveils the viable reaction routes along with their several quotas in piezo-photocatalytic CO2 methanation process by scrutinizing the intricate mechanisms via in-situ analyses.