Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Subject: search.filters.subject.PermeabilityWoS Q: search.filters.wosQuartile.Q2

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  • Article
    Citation - WoS: 8
    Citation - Scopus: 7
    Cvd-Deposited Oxygen-Selective Fluorinated Siloxane Copolymers as Gas Diffusion Layers
    (American Chemical Society, 2022) Cihanoğlu, Gizem; Ebil, Özgenç
    Copolymer thin films of 2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane (V4D4), 2-(perfluorohexylethylacrylate) (PFHEA), and 2-(perfluoroalkylethylmethacrylate) (PFEMA) were synthesized via initiated chemical vapor deposition (iCVD) as potential candidates for gas diffusion layers (GDLs) in gas diffusion electrodes (GDEs) for aqueous metal–air batteries. Thin-film GDLs exhibited an average water vapor transmission rate of 7.5 g m–2 day–1 and enhanced oxygen diffusion with oxygen permeabilities as high as 3.53 × 10–15 mol m m–2 s–1 Pa–1 (10.5 Barrer). The electrochemical performance of GDEs fabricated using commercial catalysts, current collectors, and synthesized GDLs was investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and potentiodynamic polarization measurements. The fabricated GDEs exhibited higher oxygen reduction current densities (228.2 mA cm–2) compared to commercial GDEs (132.7 mA cm–2). Copolymer GLDs exhibited an order of magnitude higher oxygen diffusion (39.5 × 10–8 cm2 s–1) in GDEs compared to commercial counterparts (1.84 × 10–8 cm2 s–1). Due to the high oxygen solubility of V4D4 and excellent hydrophobic behavior of PFHEA and PFEMA, their copolymers can effectively promote the diffusion of oxygen and restrict moisture intake, making them ideal materials for GDLs. Combining well-balanced properties of siloxane and fluorinated polymer chemistries, the iCVD process is an excellent low-cost method for the fabrication of GDLs for metal–air battery applications.
  • Article
    Citation - WoS: 6
    Citation - Scopus: 6
    A Study on Numerical Determination of Permeability and Inetia Coefficient of Aluminum Foam Using X-Ray Microtomography Techniques: Focus on Inspection Methods for Reliability (permeability and Inertia Coefficient by Tomography)
    (Begell House, 2019) Mobedi, Moghtada; Nakayama, Akira; Özkol, Ünver; Çelik, Hasan
    The volume-averaged (i.e., macroscopic) transport properties such as permeability and inertia coefficient of two aluminum foams with 10 and 20 pores per inch (PPI) pore density are found using microtomography images. It is shown that a comparison between the numerical values and the experimental results may not be sufficient to prove the correctness of the obtained results. Hence, in addition to traditional validation methods such as grid independency and comparison with reported results in literature, further inspections such as (a) checking the development of flow, (b) inspection of Darcy and non-Darcy regions, (c) conservation of flow rate through the porous media, (d) sufficiency of number of voxels in the narrow throats, and (e) observation of transverse velocity gradients in pores for high and low Reynolds numbers can be performed to further validate the achieved results. These techniques have been discussed and explained in detail for the performed study. Moreover, the obtained permeability and inertia coefficient values are compared with 19 reported theoretical, numerical, and experimental studies. The maximum deviation between the present results and the reported studies for 10 PPI is below 25%, while for 20 PPI it is below 28%.
  • Article
    Citation - WoS: 5
    Citation - Scopus: 9
    Consolidation of Elastic Porous Media Saturated by Two Immiscible Fluids
    (American Society of Civil Engineers (ASCE), 1996) Tuncay, Kağan; Çorapçıoğlu, M. Yavuz
    A theory is presented to simulate the consolidation of elastic porous media saturated by two immiscible Newtonian fluids. The macroscopic equations, including mass and momentum balance equations and constitutive relations, are obtained by volume averaging the microscale equations. The theory is based on the small deformation assumption. In the microscale, the grains are assumed to be linearly elastic and the fluids are Newtonian. The bulk and shear moduli of the solid matrix are introduced to obtain the macroscopic constitutive equations. Momentum transfer terms are expressed in terms of intrinsic and relative permeabilities assuming the validity of Darcy's law. In one dimension, the governing equations reduce to two coupled diffusion equations in terms of the pore pressures of the fluid phases. An analytical solution is obtained for a column with a fixed impervious base and a free drainage surface. Results are presented for cases of practical interest, i.e., columns saturated by oil-water and air-water phases. Results indicate that the presence of a second fluid phase affects pore water pressure and total settlement.