Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Subject: search.filters.subject.ThermoanalysisWoS Q: search.filters.wosQuartile.Q2

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  • Article
    Citation - Scopus: 7
    Modification of Grape Pulp With Citric Acid for the Production of Natural Ion Exchanger Resin and Removal of Pb (ii) and Cd (ii) From Aqueous Solutions: Kinetic, Thermodynamics, and Mechanism
    (Springer Science and Business Media Deutschland GmbH, 2023) Arslanoğlu, E.; Eren, M.Ş.A.; Arslanoğlu, H.; Çiftçi, H.
    In this study, grape pulp (MGP) modified with NaOH and citric acid was used in the production of natural ion exchangers. The effects of parameters such as initial pH, MGP dosage, temperature, initial metal ion concentration, and contact time on the removal of Pb (II) and Cd (II) ions from aqueous solutions using modified materials were investigated by batch experiments. It was found that the experimental kinetic data fit the second-order model, and the activation energy for Pb (II) and Cd (II) adsorption processes were 20.68 and 38.61 kj mol−1, respectively. Although the initial adsorption rate increases with increasing temperature, the adsorption efficiency slightly decreases. It was calculated that the equilibrium data fit the Langmuir isotherm better, and the maximum adsorption capacities for Pb (II) and Cd (II) adsorption processes were approximately 1.496 and 1.022 mmol g−1 at 25 °C, respectively. Thermodynamic analysis has shown that the adsorption processes of Pb (II) and Cd (II) are exothermic (ΔH°Pb = −35.68 kj mol−1, ΔH°Cd = −21.19 kj mol−1) and have a self-developing character. Graphical abstract: [Figure not available: see fulltext.]. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
  • Article
    Citation - WoS: 27
    Citation - Scopus: 28
    Effects of Wall-Located Heat Barrier on Conjugate Conduction/Natural- Convection Heat Transfer and Fluid Flow in Enclosures
    (Taylor and Francis Ltd., 2008) Hakyemez, Erinç; Mobedi, Moghtada; Öztop, Hakan Fehmi
    The effects of a heat barrier, located in the ceiling wall of an enclosure, on conjugate conduction/natural convection are investigated numerically. The vertical walls of the enclosure are differentially heated and the horizontal walls are adiabatic. Heatline technique is used to visualize heat transport. The variations of average Nusselt number, dimensionless heat transfer rate through the ceiling wall, and dimensionless overall heat transfer rate are studied. Calculations are performed for different Rayleigh numbers (10 3≤ Ra ≤ 10 6), thermal conductivity ratios (1 ≤ K ≤ 100), dimensionless locations of the heat barrier (0 < X h < 1),and two dimensionless ceiling wall thicknesses (D = 0.05 and D = 0.20). For high thermal conductivity ratio (K = 100), the heat barrier considerably reduces the dimensionless overall heat transfer rate. The effect of the heat barrier on dimensionless heat transfer rate through the enclosure increases as the Rayleigh number decreases. For low Rayleigh number (i.e., Ra = 10 3), a location exists in the ceiling wall for which the dimensionless overall heat transfer rate is minimum.