Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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  • Article
    Performance of Sheet Pile Walls With Rubber-Modified Backfill
    (Springer, 2025) Ecemis, Nurhan; Kadekeshova, Kuralay; Khlaif, Ali Hamid
    This study investigates the behavior of clean sand and sand-rubber mixtures used as backfill materials behind sheet pile walls under vertical loads. Physical model experiments were conducted to assess lateral displacement and pressure for backfills containing 10% granulated rubber (2.5-5 mm) under both dry and saturated conditions, and across varying backfill inclination angles. To complement the experiments, discrete element method (DEM) simulations were performed to capture the micromechanical behavior of sand-rubber mixtures, enabling analysis of particle-scale interactions. Material stiffness and friction parameters were calibrated through direct shear tests to ensure computational efficiency and accurate representation. Comparative analyses were conducted between the DEM simulations and the physical sheet pile tests across various sand-rubber backfill configurations. The results suggest that sand-rubber mixtures offer a practical and sustainable alternative for backfill applications, improving both mechanical performance and pressure mitigation. Furthermore, force chain development and deformation patterns were thoroughly examined to understand the role of micro parameters; such as particle contact behavior, porosity, internal friction, and stiffness of the rubber-sand composite backfill in reducing active earth pressure against sheet pile walls.
  • Article
    Silver-Loaded Titania-Based Metal-Organic Frameworks as a Platform for Silver Ion Release for Antibacterial Applications
    (American Chemical Society, 2025) Mazare, Anca; Goldmann, Wolfgang Heinrich; Kocak, Esra; Osuagwu, Benedict; Qin, Shanshan; Cao, Ran; Schmuki, Patrik
    Conventional Ag-decorated TiO<inf>2</inf>coatings suffer from low adsorption capacity and burst release kinetics, limiting long-term antibacterial efficacy and risking cytotoxicity. An entirely different payload release approach can be based on metal–organic frameworks (MOFs), which offer tunable porosity, high surface area, and internal diffusion channels. Here, we report a thermally stabilized Ti-based MOF [NH<inf>2</inf>-MIL-125(Ti)] functionalized with Ag+via reactive deposition, enabling high Ag loading (∼14.7 wt %) and sustained release. Annealing at 250 °C enhances aqueous stability, allowing diffusion-governed Ag+delivery over >48 h, with 77% of the Ag still present in the MOF after a 24 h release. The system exhibits dose-dependent antibacterial activity in powders and comparable efficacy in coatings, with a more gradual release profile. This scalable platform is promising for long-acting coatings, wound interfaces, and implantable materials. © 2025 Elsevier B.V., All rights reserved.
  • Article
    Citation - WoS: 14
    Citation - Scopus: 17
    Biocompatibility of Silicon Nitride Produced Via Partial Sintering & Tape Casting
    (Elsevier Ltd., 2021) Çeçen, Berivan; Topateş, Gülsüm; Kara, Aylin; Akbulut, Serdar Onat; Havıtçıoğlu, Hasan; Kozacı, Leyla Didem
    The biocompatibility of silicon nitride ceramics was proven by several studies however this study is apart from the literature in the manner of production routes that are tape casting and partial sintering. We report the tape casting route was chosen and a porous structure was obtained by partial sintering technique. Tape casting brought a smooth surface to the samples. Density and pore size distribution analysis showed that the scaffolds have low density because of the porous structure. XRD and SEM analyses were carried out to reveal the phase and microstructural characteristics of porous ceramic samples. Static contact angle measurement was done for the characterization of the wettability of the scaffolds. It revealed that the surface of the scaffolds was highly hydrophilic which is a desirable characteristic for the protein and cell adhesion. The mechanical characteristics of the scaffolds were analyzed by compression tests. Human osteosarcoma cells were used for in vitro studies. Cell-proliferation and cytotoxicity were analyzed by WST-1 and LDH, respectively. The osteoblastic behavior of the cells on the surface of the scaffolds was identified by alkaline phosphatase activity. BCA analysis was used for total protein content. The BCA and ALP results showed an increasing trend which is directly correlated with cell proliferation. Cells on the surface of the silicon nitride scaffolds were visualized by SEM and fluorescence microscopy where the images supported the in vitro analysis. Therefore, porous silicon nitride scaffolds fabricated via tape casting and partial sintering were biocompatible and they are possible candidates as bone substitute elements. © 2020 Elsevier Ltd and Techna Group S.r.l.