Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Access Right: Embargoed AccessSubject: search.filters.subject.Response surface methodology

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  • Article
    Citation - WoS: 20
    Citation - Scopus: 18
    Optimization of the Integrated Orc and Carbon Capture Units Coupled To the Refinery Furnace With the Rsm-Bbd Method
    (Elsevier, 2022) Nazerifard, Reza; Mohammadpourfard, Mousa; Heris, Saeed Zeinali
    To recover waste heat and reduce the CO2 emissions into the atmosphere, an integrated system of organic Rankine cycle and post-combustion carbon capture unit coupled with furnaces of a refinery located in Tabriz, East Azerbaijan, Iran has been presented. To assess the performances of the proposed system, thermodynamic and economic analyses are performed. The organic Rankine cycle was optimized by selecting the suitable working fluid with optimal operating conditions among the primary considered ones through multi-objective optimization. Then, the response surface methodology combined with the Box-Behnken design was employed to evaluate the effects of decision variables and their interaction on the CO2 capture cost and attain the optimal conditions. The results indicate that the R-245fa is the best working fluids among the selected ones. According to the results, the flue gas inlet temperature into the absorber and lean loading are the terms of the model that have a significant impact on the output response. In the optimum setting of the decision variables, the CO2 capture cost equals 81.60 $/tCO2 and 81.90 $/tCO2 for ORC+CC and DCC+CC processes, respectively. Furthermore, due to the absence of a turbine in the DCC+CC system, its equivalent work is 28 % higher than the ORC+CC system. Also, the amine regeneration energy is responsible for 91.47 % and 86.15 % of the variable operating cost of the optimal ORC+CC and optimal DCC+CC, respectively.
  • Article
    Citation - WoS: 7
    Citation - Scopus: 11
    Hydrophobic Deep Eutectic Solvent Effect on Acrylic Acid Separation From Aqueous Media by Using Reactive Extraction and Modeling With Response Surface Methodology
    (Taylor & Francis, 2022) Lalikoğlu, Melisa; Aşçı, Yavuz Selim; Sırma Tarım, Burcu; Yıldız, Mahmut; Arat, Refik
    Hydrophobic deep eutectic solvents (HDES) are new-generation green solvents that have emerged in recent years. In this study, the efficiency of using HDES as a solvent in separating acrylic acid from its aqueous solution by reactive extraction method was investigated. As a solvent, HDES prepared with a mixture of TOPO and menthol has been used for the recovery of acrylic acid for the first time. Physical properties of HDES mixtures such as density, viscosity, and refractive index were determined. In reactive extraction experiments, TOPO, one of the two basic components in the solvent, was also employed as an extractant. With the help of response surface methodology based on Box-Behnken design, the effect of the parameters of amount of extractant (0.1–0.9 g), Menthol/TOPO molar ratio (2–4), and initial acid concentration (3–9%) on the distribution coefficient was investigated and the model equation was formed. The highest distribution coefficient (D = 7.8) was achieved with the molar ratio of Menthol/TOPO is 2. Upon examining all the results obtained, it was seen that more than 90% of acrylic acid could be extracted from the aqueous phase to the organic phase.