Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection

Permanent URI for this collectionhttps://hdl.handle.net/11147/7148

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Author: search.filters.author.Mohammadpourfard, MousaPublisher: search.filters.publisher.Elsevier Sci Ltd

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  • Article
    Comprehensive 4E Analysis, Multi-Objective Optimization, and Feasibility Study of Five Natural Gas Liquefaction Processes With a Case Study for Iran
    (Elsevier Sci Ltd, 2026) Basmenj, Farhad Rahmdel; Tabriz, Zahra Hajimohammadi; Aghdasinia, Hassan; Mohammadpourfard, Mousa
    Natural gas (NG) is increasingly vital as a cleaner energy source due to its lower carbon emissions compared to other fossil fuels. Liquefaction facilitates efficient long-distance transportation. While numerous studies address NG liquefaction's technical aspects, holistic research remains limited. This study presents a comprehensive evaluation of five conventional natural gas (NG) liquefaction processes (including SMR-Linde, SMR-APCI, C3MRLinde, DMR-APCI, and MFC-Linde) through a 4E framework: energy, exergy, exergoeconomic, and exergoenvironmental analyses. Addressing limitations in prior research, it incorporates environmental considerations and introduces production volume-independent metrics to ensure equitable comparisons. Multi-objective optimization, based on exergoeconomic and exergoenvironmental criteria, is employed to identify Pareto-optimal operating conditions. To accelerate this complex process, neural networks are utilized. The study concludes with a feasibility assessment of large-scale LNG production in Iran, offering practical insights for optimizing process selection and enhancing the economic and environmental viability of LNG technologies. Simulations show that the MFC-Linde cycle as the most efficient regarding specific energy consumption (0.2563 kWh/kgLNG), coefficient of performance (3.184), and exergy efficiency (52.32 %). It also demonstrates the lowest unit exergy cost (3.67$/GJ) and exergy unit environmental impact (5271.86mPts/GJ). Multi-objective optimization, considering both exergetic-economic and exergetic-environmental criteria, using neural networks and genetic algorithms in MATLAB identifies Pareto-optimal conditions for all processes. For the MFCLinde, as the most efficient process, optimal operating conditions in the exergetic-economic trade off scenario are: Exergy efficiency of process = 51.45% and Exergy cost rate of LNG = 82, 162.15$/h; at Pressure of NG feed = 5, 925.32kPa, Pressure drop in valve = 5, 831.99kPa, and NG side temperature in heat exchanger = -168.34 degrees C. Finally, a feasibility study for large-scale LNG (Liquefied Natural Gas) production in Iran shows promising results, with a return on investment of 32.24 %/year and a payback period of 2.34 years, indicating the project's potential success in regions with abundant NG reserves.
  • Article
    Citation - WoS: 10
    Citation - Scopus: 12
    Bimetallic Mof@cds Nanorod Composite for Highly Efficient Piezo-Photocatalytic Co2 Methanation Under Visible Light
    (Elsevier Sci Ltd, 2024) Farshchi, Mahdi Ebrahimi; Asgharizadeh, Kimia; Jalili, Hadi; Nejatbakhsh, Siyamak; Azimi, Babak; Aghdasinia, Hassan; Mohammadpourfard, Mousa
    CO2 methanation is leading progress in both dwindling the emitted greenhouse gas and taking advantage of CO2 conversion to a worthwhile fuel. Various types of catalysts have gained researchers' attention. On the other hand, those catalysts chiefly suffer from being uneconomical, owning laborious processes, and having low efficiency. Particularly in the photocatalytic process, electron-hole recombination, charge separation efficiency, and the photocorrosion are the most remarkable obstacles in the path of gaining high efficiency. To conquer the aforementioned hindrances, Cu/Zr-MOF@CdS had been designed in order to not only do elevate CH4 selectivity but also increase CO2 conversion by altering the electron transfer mechanism. Doping Cu in Zr-MOF structure restrains C-C coupling and ameliorates the viability of protonation of *CO to *HCO during methane production. CdS and Zr-MOF both grant piezoelectricity trait to the catalyst in a way that by merging it with the photocatalytic process the mechanism of process converted from type (II) scheme to Z-scheme, culminating in thwarting recombination and increase of charge separation efficiency. The photocatalytic process achieved 23.6 mu mol. g- 1. h- 1 CH4 reaction rate and 80 % CO2 conversion, hereafter applying the piezo-photocatalytic process, these two factors reached 52.2 mu mol. g- 1. h- 1 and 99 %, respectively. This work unveils the viable reaction routes along with their several quotas in piezo-photocatalytic CO2 methanation process by scrutinizing the intricate mechanisms via in-situ analyses.