Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 45Citation - Scopus: 55Incorporation of Iron Nanoparticles Into Clinoptilolite and Its Application for the Removal of Cationic and Anionic Dyes(Korean Society of Industrial Engineering Chemistry, 2015) Nairat, Muath; Shahwan, Talal; Eroğlu, Ahmet Emin; Fuchs, HaraldThis study reports the preparation of composite sorbents of iron nanoparticles (nZVI) and clinoptilolite at various iron/clinoptilolite ratios. The composites were characterized using various characterization techniques. The material was used for the removal of methylene blue (MB) and methyl orange (MO) as model cationic and anionic dyes. The experiments investigated the effects of time, loading, initial pH, reusability, and temperature on the removal process. According to the results, Cl-nZVI showed fast and quantitative removal over a wide range of concentrations. The removal process was endothermic in nature, and the composite demonstrated reusability for several trials.Article Citation - WoS: 654Citation - Scopus: 786Green Synthesis of Iron Nanoparticles and Their Application as a Fenton-Like Catalyst for the Degradation of Aqueous Cationic and Anionic Dyes(Elsevier Ltd., 2011) Shahwan, Talal; Abu-Sirriah, Sadieh; Nairat, Muath; Boyacı, Ezel; Eroğlu, Ahmet Emin; Scott, Thomas B.; Hallam, Keith R.Iron nanoparticles were produced using extracts of green tea leaves (GT-Fe NPs). The materials were characterized using TEM, SEM/EDX, XPS, XRD, and FTIR techniques and were shown to contain mainly iron oxide and iron oxohydroxide. The obtained nanoparticles were then utilized as a Fenton-like catalyst for decolorization of aqueous solutions containing methylene blue (MB) and methyl orange (MO) dyes. The related experiments investigated the removal kinetics and the effect of concentration for both MB and MO. The concentrations of dyes in aqueous solution were monitored using ultraviolet–visible (UV–vis) spectroscopy. The results indicated fast removal of the dyes with the kinetic data of MB following a second order removal rate, while those of MO were closer to a first order removal rate. The loading experiments indicated almost complete removal of both dyes from water over a wide range of concentration, 10–200 mg L−1. Compared with iron nanoparticles produced by borohydride reduction, GT-Fe nanoparticles demonstrated more effective capability as a Fenton-like catalyst, both in terms of kinetics and percentage removal.
