Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Permanent URI for this collectionhttps://hdl.handle.net/11147/7148
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Article Citation - WoS: 17Citation - Scopus: 26Thixoforming of A356/Sic and A356/Tib2 Nanocomposites Fabricated by a Combination of Green Compact Nanoparticle Incorporation and Ultrasonic Treatment of the Melted Compact(Springer Verlag, 2014) Kandemir, Sinan; Atkinson, Helen V.; Weston, David P.; Hainsworth, Sarah V.Thixoforming is a type of semi-solid processing which is based on forming metals in the semi-solid state rather than fully liquid or solid state. There have been no reports of the thixoforming of nanocomposites in the literature. The incorporation of ceramic nanoparticles into liquid metals is a challenging task for the fabrication of metal matrix nanocomposites due to their large surface-to-volume ratio and poor wettability. Previous research work by a number of workers has highlighted the challenges with the incorporation of nanoparticles into liquid aluminum alloy. In the present study, SiC and TiB2 nanoparticles with an average diameter between 20 and 30 nm were firstly incorporated into green compacts by a powder forming route, and then the compacts were melted and treated ultrasonically. The microstructural studies reveal that the engulfment and relatively effective distribution of the nanoparticles into the melt were achieved. The hardness was considerably improved with only 0.8 wt pct addition of the nanoparticles. The nanocomposites were successfully thixoformed at a solid fraction between 0.65 and 0.70. The microstructures, hardness, and tensile mechanical properties of the thixoformed nanocomposites were investigated and compared with those of the as-received A356 and thixoformed A356 alloys. The tensile properties of the thixoformed nanocomposites were significantly enhanced compared to thixoformed A356 alloy without reinforcement, indicating the strengthening effects of the nanoparticles.Article Citation - WoS: 19Citation - Scopus: 23Silicon Oxycarbide-Based Composites Produced From Pyrolysis of Polysiloxanes With Active Ti Filler(Elsevier Ltd., 2006) Akkaş, Hatice Deniz; Öveçoğlu, M. Lütfi; Tanoğlu, MetinPhenyl (PPS) and methyl (PMS) containing polysiloxanes were pyrolyzed at elevated temperatures (900-1500 °C) under argon atmosphere to investigate the phase developments within the polymers. It was found that pyrolysis of the polymers under inert atmosphere up to 1300 °C leads to amorphous silicon oxycarbide (SiOxCy) ceramics. Conversions at higher temperatures results in the transformations into the crystalline β-SiC phases. Ceramic matrix composites (CMCs) were developed based on the active filler controlled pyrolysis (AFCOP) of polysiloxanes with active Ti filler additions. CMC monoliths were prepared with 60-80 wt.% of active Ti particulates blended into polymer precursors. Green bodies of the composites were made by warm pressing under 15 MPa pressure and ceramics were obtained by pyrolysis at elevated temperatures between 900 and 1500 °C under argon atmosphere. The results showed that due to the incorporation of active Ti fillers, formation of crystalline phases such as TiC, TiSi, and TiO occured within the amorphous matrix due to the reactions between the Ti and the polymer decomposition products. The microstructural and mechanical characterization results of the composites are presented within the paper.
